Pierpaolo Minei
University of Pisa
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Publication
Featured researches published by Pierpaolo Minei.
Journal of Materials Chemistry C | 2014
Pierpaolo Minei; Matthias Koenig; Antonella Battisti; Muzaffer Ahmad; Vincenzo Barone; Tomás Torres; Dirk M. Guldi; Giuseppe Brancato; Giovanni Bottari; Andrea Pucci
We report on a new vapochromic system suitable for sensing volatile organic compounds (VOCs) based on polymer films doped with 4-(diphenylamino)phthalonitrile (DPAP), a fluorescent molecular rotor sensitive to both solvent polarity and viscosity. Poly(methyl methacrylate) (PMMA) and polycarbonate (PC) films containing small amounts of DPAP (≤0.1 wt%) were prepared and exposed to saturated atmospheres of different VOCs. DPAP/PMMA films show a good and reversible vapochromism when exposed to VOCs with high polarity index and favourable interaction with polymer matrices such as THF, CHCl3, and acetonitrile. Analogously, DPAP/PC films exposed to polar and highly polymer-interacting solvents, that is, toluene, THF, and CHCl3, show a gradual decrease and red-shift of the emission. In contrast to DPAP/PMMA films, an unexpected increase and further red-shift of fluorescence are observed at longer exposure times as a consequence of an irreversible, solvent-induced crystallization process of PC. The vapochromism of DPAP-doped films is rationalized on the basis of alterations of the rotor intramolecular motion and polarity effects stemming from the environment, which, in concert, influence the deactivation pathways of the DPAP intramolecular charge transfer state. Overall, the present results support the use of DPAP-enriched plastic films as a new chromogenic material suitable for the detection of VOCs.
RSC Advances | 2016
Pierpaolo Minei; Elisabetta Fanizza; Antonio M. Rodriguez; Ana B. Muñoz-García; Paola Cimino; Michele Pavone; Andrea Pucci
Sunlight concentration is a promising path to cost-effective photovoltaic (PV) technologies. Compared to standard concentrators based on geometrical optics, luminescent solar concentrators (LSCs) appear to be viable and convenient alternatives because sunlight concentration to PV occurs with diffuse light and there is no need for sun tracking or cooling apparatuses. In this study, we report on the optical efficiencies of luminescent solar concentrators (LSCs) based on poly(methyl methacrylate) (PMMA) thin films doped with a red-emitting zinc(II) complex of the D–A–D type ligand N,N′-bis(2-hydroxy-1-naphthylidene)-diaminomaleonitrile (ZnL). ZnL is attractive for use in LSC owing to its easy and cheap synthesis. ZnL in PMMA shows an emission band at 624 nm, a Stokes shift of 34 nm and an average QY of 23%, data comparable to those recorded in solution and efficiently predicted by DFT calculations. A study of ZnL/PMMA LSC yields optical efficiencies of 7%, which is comparable to those based on the near unity QY fluorophores such as Lumogen Red. These performances were attributed to the higher emission red-shift and larger Stokes shift of ZnL that prevent the loss of efficiencies due to self-absorption and possibly circumvent its lower QY.
Polymers for Advanced Technologies | 2016
Pierpaolo Minei; Muzaffer Ahmad; Vincenzo Barone; Giuseppe Brancato; Elisa Passaglia; Giovanni Bottari; Andrea Pucci
We report on vapochromic films suitable for detecting volatile organic compounds (VOCs), based on polycarbonate (PC) doped with 4-(triphenylamino)phthalonitrile (TPAP), a fluorescent molecular rotor sensitive to solvent polarity and viscosity. PC films of variable thickness (from 20 up to 80 µm) and containing small amounts of TPAP (0.05 wt.%) were prepared and exposed to a saturated atmosphere of different VOCs. TPAP/PC films showed a gradual decrease and red-shift of the emission during the exposure to solvents with high polarity index and favourable interaction with the polymer matrix such as THF, CHCl3, and acetonitrile. In the case of the most interacting solvents (THF and CHCl3), TPAP/PC films also showed a fluorescence increase at longer exposure times, as a consequence of an irreversible, solvent-induced crystallization process of the polymeric matrix. The vapochromism of TPAP/PC films is rationalized on the basis of alterations of the rotor intramolecular motion upon solvent uptake by PC and polarity effects of the microenvironment. Interestingly, the fluorescence response of the TPAP/PC films shows a non-trivial, tuneable dependence on film thickness during the second solvent-exposure stage. The latter effect is attributed to a variable extent of the crystallization process occurring in the PC films. This observation promptly suggests, in turn, an effective procedure to modulate the spectroscopic response in such functionalized polymeric materials through the precise control of the film thickness.
Molecules | 2017
Mirko Borelli; Giuseppe Iasilli; Pierpaolo Minei; Andrea Pucci
Thin films of styrene copolymers containing fluorescent molecular rotors were demonstrated to be strongly sensitive to volatile organic compounds (VOCs). Styrene copolymers of 2-[4-vinyl(1,1′-biphenyl)-4′-yl]-cyanovinyljulolidine (JCBF) were prepared with different P(STY-co-JCBF)(m) compositions (m% = 0.10–1.00) and molecular weights of about 12,000 g/mol. Methanol solutions of JCBF were not emissive due to the formation of the typical twisted intramolecular charge transfer (TICT) state at low viscosity regime, which formation was effectively hampered by adding progressive amounts of glycerol. The sensing performances of the spin-coated copolymer films (thickness of about 4 µm) demonstrated significant vapochromism when exposed to VOCs characterized by high vapour pressure and favourable interaction with the polymer matrix such as tetrahydrofurane (THF), CHCl3 and CH2Cl2. The vapochromic response was also reversible and reproducible after successive exposure cycles, whereas the fluorescence variation scaled linearly with VOC concentration, thus suggesting future applications as VOC optical sensors.
Faraday Discussions | 2017
Giuseppe Iasilli; Fabio Martini; Pierpaolo Minei; Giacomo Ruggeri; Andrea Pucci
Dyes and Pigments | 2016
Jonathan Lucarelli; Marco Lessi; Chiara Manzini; Pierpaolo Minei; Fabio Bellina; Andrea Pucci
ACS Macro Letters | 2013
Pierpaolo Minei; Antonella Battisti; Simone Barondi; Marco Lessi; Fabio Bellina; Giacomo Ruggeri; Andrea Pucci
Dyes and Pigments | 2016
Fabio Bellina; Chiara Manzini; Giulia Marianetti; Cristofer Pezzetta; Elisabetta Fanizza; Marco Lessi; Pierpaolo Minei; Vincenzo Barone; Andrea Pucci
Polymer International | 2016
Pierpaolo Minei; Andrea Pucci
ChemPlusChem | 2014
Marco Lessi; Chiara Manzini; Pierpaolo Minei; Luca A. Perego; Julien Bloino; Franco Egidi; Vincenzo Barone; Andrea Pucci; Fabio Bellina