Pierre Delmelle
Université catholique de Louvain
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Geochimica et Cosmochimica Acta | 1994
Pierre Delmelle; Alain Bernard
The Kawah Ijen volcano--with a record of phreatic eruptions--has its 1000 m wide crater filled with a lake that has existed for at least one century. At present, the lake waters are hot ( T 37° C ), strongly mineralized (TDS = 105 g/L) and extremely acidic ( pH 0.4). By its volume, the Javanese lake is probably the largest accumulation in the world of such acidic waters. Mineralogy of the suspended solids within the lake waters suggests that concentrations of Si, Ca, Ti, and Ba are controlled by precipitation of silica, gypsum, anatase, and barite. Lake sediment is composed of chemical precipitates with composition similar to the suspended solids. Thermodynamic calculations predict that the lake waters have reached equilibrium with respect to -cristobalite, barite, gypsum, anglesite, celestite, and amorphous silica, in agreement with the analytical observations. Significant concentrations of ferric iron suggest that the current lake waters are fairly oxidized. Sulfides are absent in the water column but are always present in the native S spherules that form porous aggregates which float on the lake. The presence of native S provides direct evidence of more reduced conditions at the lake floor where H 2 S is probably being injected into the lake. With progressive addition of H 2 S to the acid waters, native S, pyrite, and enargite are theoretically predicted to be saturated. Reactions between upward streaming H 2 S-bearing gases discharged by subaqueous fumaroles, and metals dissolved in the acidic waters could initiate precipitation of these sulfides. A model of direct absorption of hot magmatic gases into cool water accounts for the extreme acidity of the crater lake. Results show that strongly acidic, sulfate-rich solutions are formed under oxidizing conditions at high gas/water ratios. Reactions between the acidic fluids and the Ijen andesite were modeled to account for elevated cation concentrations in lake water. Current concentrations of conservative rockforming elements are produced by dissolution of approximately 60 g of andesite per kg of acid solution. Complete neutralization of the acid lake waters by reaction with the wallrock produces a theoretical alteration assemblage equivalent to that observed in volcano-hosted, acid-sulfate epithermal ore deposits.
Journal of Volcanology and Geothermal Research | 2000
Pierre Delmelle; Alain Bernard; Minoru Kusakabe; Tobias P. Fischer; Bokuichiro Takano
Samples from Kawah Ijen crater lake, spring and fumarole discharges were collected between 1990 and 1996 for chemical and isotopic analysis. An extremely low pH (<0.3) lake contains SO 4 -Cl waters produced during absorption of magmatic volatiles into shallow ground water. The acidic waters dissolve the rock isochemically to produce immature solutions. The strong D and 18 O enrichment of the lake is mainly due to enhanced evaporation at elevated temperature, but involvement of a magmatic component with heavy isotopic ratios also modifies the lake D and 18 O content. The large Δ SO4-S D (23.8-26.4‰) measured in the lake suggest that dissolved SO 4 forms during disproportionation of magmatic SO 2 in the hydrothermal conduit at temperatures of 250∼280°C. The lake δ 18 O SO4 and δ 18 O H2O values may reflect equilibration during subsurface circulation of the water at temperatures near 150°C. Significant variations in the lakes bulk composition from 1990 to 1996 were not detected. However, we interpret a change in the distribution and concentration of polythionate species in 1996 as a result of increased SO 2 -rich gas input to the lake system. Thermal springs at Kawah Ijen consist of acidic SO 4 -Cl waters on the lakeshore and neutral pH HCO 3 -SO 4 -Cl-Na waters in Blawan village, 17 km from the crater. The cation contents of these discharges are diluted compared to the crater lake but still do not represent equilibrium with the rock. The SO 4 /Cl ratios and water and sulfur isotopic compositions support the idea that these springs are mixtures of summit acidic SO 4 -Cl water and ground water. The lakeshore fumarole discharges (T = 170∼ 245°C) have both a magmatic and a hydrothermal component and are supersaturated with respect to elemental sulfur. The apparent equilibrium temperature of the gas is ∼260°C. The proportions of the oxidized, SO 2 -dominated magmatic vapor anti of the reduced, H 2 S-dominated hydrothermal vapor in the fumaroles varied between 1979 and 1996. This may be the result of interaction of SO 2 -bearing magmatic vapors with the summit acidic hydrothermal reservoir. This idea is supported by the lower H 2 S/SO 2 ratio deduced for the gas producing the SO 4 -Cl reservoir feeding the lake compared with that observed in the subaerial gas discharges. The condensing gas may have equilibrated in a liquid-vapor zone at about 350°C. Elemental sulfur occurs in the crater lake environment as banded sediments exposed on the lakeshore and as a subaqueous molten body on the crater floor. The sediments were precipitated in the past during inorganic oxidation of H 2 S in the lake water. This process was not continuous, but was interrupted by periods of massive silica (poorly crystallized) precipitation, similar to the present-day lake conditions. We suggest that the factor controlling the type of deposition is related to whether H 2 S- or silica-rich volcanic discharges enter the lake. This could depend on the efficiency with which the lake water circulates in the hydrothermal cell beneath the crater. Quenched liquid sulfur products show δ 34 S values similar to those found in the banded deposits, suggesting that the subaqueous molten body simply consists of melted sediments previously accumulated at the lake bottom.
Bulletin of Volcanology | 2012
Paul Ayris; Pierre Delmelle
The Earth’s history is punctuated by large explosive eruptions that eject large quantities of magma and silicate rock fragments into the atmosphere. These tephra particles can sometimes be dispersed across millions of square kilometres or even entire continents. The interaction of tephra with or in receiving environments may induce an array of physical, chemical and biological effects. The consequences for affected systems and any dependent communities may be chronic and localised in the event of frequent, small eruptions, while larger and rarer events may have acute, regional-scale impacts. It is, therefore, necessary to document the range of possible impacts that tephra may induce in receiving environments and any resulting effects in interconnected systems. We collate results from many studies to offer a detailed multidisciplinary and interdisciplinary review of the immediate post-eruptive effects of tephra emission into the atmosphere, onto vegetation, soil or ice/snow surfaces and in aquatic systems. We further consider the repercussions that may be induced in the weeks to years afterwards. In the atmosphere, tephra can influence cloud properties and air chemistry by acting as ice nuclei (IN) or by offering sites for heterogeneous reactions, respectively. Tephra on vegetation causes physical damage, and sustained coverage may elicit longer-term physiological responses. Tephra deposits on soils may alter their capacity to exchange gas, water and heat with the atmosphere or may have a specific chemical effect, such as nutrient input or acidification, on sensitive soils. Tephra deposition onto snow or ice may affect ablation rates. Rivers and lakes may experience turbidity increases and changes in their morphology as a result of fallout and prolonged (months or years) erosion from the tephra-covered catchment. In the first weeks after deposition, tephra leaching may affect river chemistry. The abundance and speciation of phytoplankton populations in lakes may be altered by tephra-induced changes in water chemistry or sediment–water nutrient cycling. In the oceans, tephra deposition may fertilise Fe-limited waters, with potential impacts on the global carbon cycle. Embracing the full complexity of environmental effects caused by tephra fall demands a renewed investigative effort drawing on interdisciplinary field and laboratory studies, combined with consideration of the interconnectivity of induced impacts within and between different receiving environments.
Geophysical Research Letters | 2004
A. J. S. McGonigle; Pierre Delmelle; Clive Oppenheimer; Vitchko Tsanev; Thomas Delfosse; Glyn Williams-Jones; Keith A. Horton; Tamsin A. Mather
Ground based remote sensing techniques are used to measure volcanic SO2 fluxes in efforts to characterise volcanic activity. As these measurements are made several km from source there is the potential for in-plume chemical transformation of SO2 to sulphate aerosol (conversion rates are dependent on meteorological conditions), complicating interpretation of observed SO2 flux trends. In contrast to anthropogenic plumes, SO2 lifetimes are poorly constrained for tropospheric volcanic plumes, where the few previous loss rate estimates vary widely (from 99% per hour). We report experiments conducted on the boundary layer plume of Masaya volcano, Nicaragua during the dry season. We found that SO2 fluxes showed negligible variation with plume age or diurnal variations in temperature, relative humidity and insolation, providing confirmation that remote SO2 flux measurements (typically of approximate to500-2000 s old plumes) are reliable proxies for source emissions for ash free tropospheric plumes not emitted into cloud or fog.
Geological Society, London, Special Publications | 2003
Pierre Delmelle
Abstract Recent studies suggest that the environmental effects of volcanic gas emissions in the lower troposphere have been underestimated. This chapter first briefly summarizes the techniques available for characterizing tropospheric volcanic gas plumes, including the composition and fluxes of emitted gases and aerosols, as well as their atmospheric dispersion. The second part documents the contribution of gas emissions from degassing craters to the composition of the atmosphere, including effects from dry and wet deposition chemistry. The third section deals with the detrimental impacts on vegetation, soils, and groundwater in relation to passive degassing activity. Improved understanding of the impacts of volcanic degassing on the atmospheric and terrestrial environment will require: (1) systematic two-dimensional and three-dimensional measurements of tropospheric volcanic plumes, (2) development of general physical and chemical models to describe the fate of volcanic gases and aerosols during transport in the troposphere, and (3) investigation of the response of diverse ecosystems to volcanogenic air pollution.
Global Biogeochemical Cycles | 2011
Nazli Olgun; Svend Duggen; Peter Croot; Pierre Delmelle; Heiner Dietze; U. Schacht; Niels Oskarsson; Claus Siebe; Andreas Auer; Dieter Garbe-Schönberg
Surface ocean iron (Fe) fertilization can affect the marine primary productivity (MPP), thereby impacting on CO2 exchanges at the atmosphere-ocean interface and eventually on climate. Mineral (aeolian or desert) dust is known to be a major atmospheric source for the surface ocean biogeochemical iron cycle, but the significance of volcanic ash is poorly constrained. We present the results of geochemical experiments aimed at determining the rapid release of Fe upon contact of pristine volcanic ash with seawater, mimicking their dry deposition into the surface ocean. Our data show that volcanic ash from both subduction zone and hot spot volcanoes (n = 44 samples) rapidly mobilized significant amounts of soluble Fe into seawater (35–340 nmol/g ash), with a suggested global mean of 200 ± 50 nmol Fe/g ash. These values are comparable to the range for desert dust in experiments at seawater pH (10–125 nmol Fe/g dust) presented in the literature (Guieu et al., 1996; Spokes et al., 1996). Combining our new Fe release data with the calculated ash flux from a selected major eruption into the ocean as a case study demonstrates that single volcanic eruptions have the potential to significantly increase the surface ocean Fe concentration within an ash fallout area. We also constrain the long-term (millennial-scale) airborne volcanic ash and mineral dust Fe flux into the Pacific Ocean by merging the Fe release data with geological flux estimates. These show that the input of volcanic ash into the Pacific Ocean (128–221 × 1015 g/ka) is within the same order of magnitude as the mineral dust input (39–519 × 1015 g/ka) (Mahowald et al., 2005). From the similarity in both Fe release and particle flux follows that the flux of soluble Fe related to the dry deposition of volcanic ash (3–75 × 109 mol/ka) is comparable to that of mineral dust (1–65 × 109 mol/ka). Our study therefore suggests that airborne volcanic ash is an important but hitherto underestimated atmospheric source for the Pacific surface ocean biogeochemical iron cycle.
Environmental Pollution | 2003
Pierre Delmelle; Thomas Delfosse; Bruno Delvaux
The continuous emissions of SO(2), HCl and HF by Masaya volcano, Nicaragua, represent a substantial source of atmospheric S-, Cl- and F-containing acid inputs for local ecosystems. We report on the effects of such acid depositions on the sulfate, chloride and fluoride contents in soils (0-40 cm) from two distinct transects located downwind from the volcano. The first transect corresponds to relatively undifferentiated Vitric Andosols, and the second transect to more weathered Eutric Andosols. These soils are exposed to various rates of volcanogenic acid addition, with the Vitric sites being generally more affected. Prolonged acid inputs have led to a general pH decrease and reduced exchangeable base cation concentrations in the Andosols. The concentrations of 0.5 M NH(4)F- and 0.016 M KH(2)PO(4)-extractable sulfate (NH(4)F-S and KH(2)PO(4)-S, respectively) indicate that volcanic S addition has increased the inorganic sulfate content of the Vitric and Eutric soils at all depths. In this process, the rate of sulfate accumulation is also dependent on soil allophane contents. For all soils, NH(4)F extracted systematically more (up to 40 times) sulfate than KH(2)PO(4). This difference suggests sulfate incorporation into an aluminum hydroxy sulfate phase, whose contribution to total inorganic sulfate in the Vitric and Eutric Andosols is estimated from approximately 34 to 95% and approximately 65 to 98%, respectively. The distribution of KH(2)PO(4)-extractable chloride in the Vitric and Eutric Andosols exposed to volcanic Cl inputs reveals that added chloride readily migrates through the soil profiles. In contrast, reaction of fluoride with Al and Fe oxyhydroxides and allophanes is an important sink mechanism in the Masaya Andosols exposed to airborne volcanic F. Fluoride dominates the anion distribution in all soil horizons, although F is the least concentrated element in the volcanic emissions and depositions. The soil anion distribution reflects preferential retention of fluoride over sulfate and chloride, and of sulfate over chloride. The primary acidifying agent of the Andosols subject to the volcanic acid inputs is HCl.
Journal of Volcanology and Geothermal Research | 2000
Pierre Delmelle; Alain Bernard
Abstract The crater lake of Kawah Ijen volcano contains extremely low pH ( We discuss the downstream composition changes affecting the Banyupahit waters by using stable isotope, chemical and mineralogical data collected from sites along the stream length. The saturation of the stream waters with respect to minerals was evaluated with SOLVEQ and WATEQ4F and compared with the geochemical observations. An aluminous mineralogy (alunogen, pickeringite, tamarugite and kalinite) develops in the upper part of the Banyupahit due to concentration of the headwaters by evaporation. Downstream attenuation of dissolved element concentrations results principally from dilution and from mineral precipitation. The stream pH changes from ∼0 at the source to >4 close to the mouth. The δD and δ18O values and the relative SO4–Cl–F contents of the Banyupahit waters indicate that the tributaries are mostly meteoric. Dissolved SO4 in the acidic stream come only from the crater lake seepages and are not involved later in microbially mediated reactions, as shown by their δ34S and δ18O values. Re-equilibration of the stream SO4 oxygen-isotope composition with H2O from tributaries does not occur. Calcium, SiO2, Al, Fe, K and SO4 behave non-conservatively in the stream waters. Gypsum, silica (amorphous or poorly ordered), a basic aluminum hydroxysulfate (basaluminite?), K-jarosite and amorphous ferric hydroxide may exert a solubility control on these elements along the entire stream length, or in certain stream sections, consistent with the thermochemical model results. Downstream concentration trends and mineral saturation levels suggest that precipitation of Sr-, Pb-rich barite and celestite consume Ba, Sr and Pb, whereas dissolved Cu, Pb and Zn may adsorb onto solid particles, especially after the junctions of the acidic stream with non-acidic rivers. We calculated that significant fluxes of SO4, F, Cl, Al, SiO2, Ti, Mn and Cu may reach the irrigation system, possibly causing serious environmental impacts such as soil acidification and induration.
Geophysical Research Letters | 1998
S. R. Young; Peter Francis; J. Barclay; T. J. Casadevall; C. A. Gardner; B. Darroux; M. A. Davies; Pierre Delmelle; G. E. Norton; Adam Maciejewski; Clive Oppenheimer; John Stix; Ian M. C. Watson
Correlation spectrometer measurements of sulfur dioxide (SO2) emission rates during the current eruption of the Soufriere Hills volcano, Montserrat, have contributed towards identifying different phases of volcanic activity. SO2 emission rate has increased from 550 td−1 (>6.4 kgs−1) after July 1996, with the uncertainty associated with any individual measurement ca. 30%. Significantly enhanced SO2 emission rates have been identified in association with early phreatic eruptions (800 td−1 (9.3 kgs−1)) and episodes of vigorous dome collapse and pyroclastic flow generation (900 to 1500 td−1 (10.4 to 17.4 kgs−1)). SO2 emission rate has proved a useful proxy measurement for magma production rate. Observed SO2 emission rates are significantly higher than those inferred from analyses of glass inclusions in phenocrysts, implying the existence of a S-rich magmatic vapour phase.
Journal of Geophysical Research | 2006
Andrew G. Allen; Tamsin A. Mather; A. J. S. McGonigle; Alessandro Aiuppa; Pierre Delmelle; Brian Davison; N. Bobrowski; C. Oppenheimer; David M. Pyle; Salvatore Inguaggiato
The number concentrations and size distributions of aerosol particles >0.3 mm diameter were measured at the summit of Mount Etna and up to 10 km downwind from the degassing vents during July and August 2004. Aerosol number concentrations reached in excess of 9 106 L1 at summit vents, compared to 4–8 104 L1 in background air. Number concentrations of intermediate size particles were higher in emissions from the Northeast crater compared to other summit crater vents, and chemical composition measurements showed that Northeast crater aerosols contained a higher mineral cation content compared to those from Voragine or Bocca Nuova, attributed to Strombolian or gas puffing activity within the vent. Downwind from the summit the airborne plume was located using zenith sky ultraviolet spectroscopy. Simultaneous measurements indicated a coincidence of elevated ground level aerosol concentrations with overhead SO2, demonstrating rapid downward mixing of the plume onto the lower flanks of the volcano under certain meteorological conditions. At downwind sites the ground level particle number concentrations were elevated in all size fractions, notably in the 2.0–7.5 mm size range. These findings are relevant for assessing human health hazard and suggest that aerosol size distribution measurements may aid volcanic risk management.