Qing N. Chan

Development of temperature imaging using two-line atomic fluorescence

This work aims to advance understanding of the coupling between temperature and soot. The ability to image temperature using the two-line atomic fluorescence (TLAF) technique is demonstrated. Previous TLAF theory is extended from linear excitation into the nonlinear fluence regime. Nonlinear regime two-line atomic fluorescence (NTLAF) provides superior signal and reduces single-shot uncertainty from 250 K for conventional TLAF down to 100 K. NTLAF is shown to resolve the temperature profile across the stoichiometric envelope for hydrogen, ethylene, and natural gas flames, with deviation from thermocouple measurements not exceeding 100 K, and typically ≲30 K. Measurements in flames containing soot demonstrate good capacity of NTLAF to exclude interferences that hamper most two-dimensional thermometry techniques.

Solvent effects on two-line atomic fluorescence of indium

We aim to investigate the potential of four different organic solvents, namely, acetone, ethanol, methanol, and isopropanol, and the organic-solvent-water mixtures as a seeding medium for the two-line atomic fluorescence technique. Water is used as the reference case. Indium, which has been previously shown to have suitable spectroscopic attributes, is chosen as the thermometry species in the present study. Acetone and methanol are shown to enhance the fluorescence signal intensity the most (approximately threefold to fivefold at stoichiometric conditions) when used. Acetone and methanol are shown to improve the fluorescence emission over the entire stoichiometric envelope of flame, most significantly in the rich combustion region, as well as a twofold enhancement in the signal-to-noise ratio.

Instantaneous Temperature Imaging of Diffusion Flames Using Two-Line Atomic Fluorescence

This work investigates the first demonstration of nonlinear regime two-line atomic fluorescence (NTLAF) thermometry in laminar non-premixed flames. The results show the expediency of the technique in the study of the reaction zone and reveals interesting findings about the indium atomization process. Indium fluorescence is observed to be strongest at the flame-front, where the temperature exceeds 1000 K. The uncertainty in the deduced temperature measurement is ∼6%. The temperature profile across the reaction zone shows good agreement with laminar flame calculations. The advantages and inherent limitations of the technique are discussed.

New Seeding Methodology for Gas Concentration Measurements

This paper presents the first demonstration of the pulsed laser ablation technique to seed a laminar non-reacting gaseous jet at atmospheric pressure. The focused, second harmonic from a pulsed Nd:YAG laser is used to ablate a neutral indium rod at atmospheric pressure and temperature. The ablation products generated with the new seeding method are used to seed the jet, as a marker of the scalar field. The neutral indium atoms so generated are found to be stable and survive a convection time of the order of tens of seconds before entering the interrogation region. The measurements of planar laser-induced fluorescence (PLIF) with indium and laser nephelometry measurements with the ablation products are both reported. The resulting average and root mean square (RMS) of the measurements are found to agree reasonably well although some differences are found. The results show that the pulsed laser ablation method has potential to provide scalar measurement for mixing studies.

Numerical study of fire spread using the level-set method with large eddy simulation incorporating detailed chemical kinetics gas-phase combustion model

Abstract A fire code has been developed for the purpose of modelling wildland fires via Large Eddy Simulation (LES) and the use of the level-set approach to track the flame front. Detailed chemical kinetics have been considered via the strained laminar flamelet approach for the combustion process which included the consideration of the yields of toxic volatiles such as CO, CO2 and soot production. Numerical simulations have been validated against an experimental study on the fire spread on a pine needle board under different slope angles. Peak temperatures and occurrence times during the propagation process were predicted with an overall average error of 11% and 3% respectively. This demonstrates that the flaming behaviour could be well predicted under different slope conditions. By incorporating the level set with the gas phase models, information including temperature field, toxic volatiles and soot particle concentrations can be realised in comparison to empirical fire spread models.

On the influences of key modelling constants of large eddy simulations for large-scale compartment fires predictions

ABSTRACT An in-house large eddy simulation (LES) based fire field model has been developed for large-scale compartment fire simulations. The model incorporates four major components, including subgrid-scale turbulence, combustion, soot and radiation models which are fully coupled. It is designed to simulate the temporal and fluid dynamical effects of turbulent reaction flow for non-premixed diffusion flame. Parametric studies were performed based on a large-scale fire experiment carried out in a 39-m long test hall facility. Several turbulent Prandtl and Schmidt numbers ranging from 0.2 to 0.5, and Smagorinsky constants ranging from 0.18 to 0.23 were investigated. It was found that the temperature and flow field predictions were most accurate with turbulent Prandtl and Schmidt numbers of 0.3, respectively, and a Smagorinsky constant of 0.2 applied. In addition, by utilising a set of numerically verified key modelling parameters, the smoke filling process was successfully captured by the present LES model.

Establishing pyrolysis kinetics for the modelling of the flammability and burning characteristics of solid combustible materials

In this article, a generic framework was proposed to effectively characterise the pyrolysis kinetics of any household furniture materials. To examine the validity of this method, two wooden polymeric samples, (1) furniture plywood and (2) particle board, were experimented through thermogravimetric and differential thermal analyses, as well as cone calorimetry. The framework comprises of three major parameterisation procedures including (1) using the Kissinger method for the initial approximation, (2) modification of modelling constants and (3) optimisation by comparisons with the experimental results. The finalised pyrolysis kinetics was numerically investigated through computational fluid dynamics simulation of the cone calorimeter. Numerical predictions were validated against the experimental data for three different cone radiation intensities. Good agreement was achieved between the computational and experimental results in terms of heat release rate, ignition time and burn duration. The proposed framework was capable of establishing quality pyrolysis kinetics that fully replicates the complex thermal decomposition of solid combustible materials.

Numerical study of the development and angular speed of a small-scale fire whirl

Abstract The development stages of a small-scale fire whirl including the ignition, flame-rising and fully-developed whirling were successfully captured by a fire field model. Good agreements between simulation and experimental results for vertical temperature profiles and flame height were achieved. With the consideration of the interaction between the liquid and gas phases of the fuel, the radiation heat feedback towards the liquid fuel was aptly predicted. Angular velocities that govern the rotational motion of the fire whirl were evaluated based on computed data. Furthermore, the circulate motion and buoyancy force promoting the extension of flame height were characterised in numerical simulations.

Recent advances in measurement of turbulent reacting flows in which heat transfer is dominated by radiation

Recent advances in diagnostic methods are providing new capacity for detailed measurement of turbulent, reacting flows in which heat transfer is dominant. Radiation typically becomes dominant in flames containing soot and/or with sufficient physical size, so is important in many flames of practical significance. The presence of particles, including soot, increases the coupling between the turbulence, chemistry and radiative heat transfer processes. Particles also increase the difficulties of laser-based measurements by increasing the interferences to the signal and the attenuation of the beam. The paper reviews recent advances in techniques to measure temperature, mixture fraction, soot volume fraction, velocity, particle number density and the scattered, absorbed and transmitted components of radiation propagation through particle laden systems.Copyright