Qiongqiong He

A comparison of desorption process of Chinese and Australian lignites by dynamic vapour sorption

ABSTRACT Modified BET model and Do and Do (D.D.) model were chosen to interpret the desorption process of water on hard and soft lignites. The organic and inorganic hydrophilic sites were determined by X-ray photoelectron spectroscopy and X-Ray fluorescence spectroscopy. From the modified BET model, only a small part of hydrophilic sites (HSs) acted as effective primary sites due to space restraint, intramolecular hydrogen bond and maybe more than one hydrophilic site connecting with one water molecule. From the D.D. model, the total adsorption sites (St) of Loy Yang lignite (LY) is 18.7 mmol/g, which is higher than that of Shengli (SL) 17.0 mmol/g in spite of lower primary sites, and the saturation concentration of water (qus) in the micropore of LY is 33.7 mmol/g, which is much higher than that of SL (12.5 mmol/g). So the high moisture-holding capacity of LY is mainly determined by the high St and qus, and not the primary sites. The size of water clusters entering the micropores is 7 for SL and 6 for LY, which is related to relative location of HS. When dewatered, the higher total sites density and smaller water cluster size of LY both implied higher dewatering energy.

Multiphysics modeling of water transport in high-intensity lignite drying process on pore scale

ABSTRACT The understanding of the moisture transfer process in the pore network is quite important to improve the lignite drying efficiency. Scanning electronic microscopy image was used for construction of pore topology closely approximating the true topology of the real lignite for the heat and mass transfer processes on pore scale by COMSOL simulation. Considering the gas‒liquid phase coexistence of water, “Laminar Two-Phase Flow, Phase Field” module and “Liquid Heat Transfer” module were used. The pore size had significant effects on the flow velocity and the larger pores acted as the main pathway for the moisture transport, therefore affected the maximum drying rate. On the other hand, the connection of pores and the throats distribution in the pathway also had a significant effect on the flow velocity, and the moisture between the throats was hard to transfer as a flow, maybe by vapor diffusion. In high-intensity lignite drying process, the moisture vaporization quickly when heated up and vapor pressure was beneficial to keep the pore size and ensure the smooth of moisture flow pathway, thus improving the efficiency of the drying process.

Thermal fragmentation and pulverization properties of lignite in drying process and its mechanism

ABSTRACT The fragmentation and pulverization properties of lignite in the different drying processes were investigated in this study. Lignite particles were dried at different temperatures (100, 140, and 180°C), particle sizes (6–25 mm) and drying time (0–60 min), and the parameters of fragmentation index (Sf) and pulverization ratio (β) were used to describe the fragmentation and pulverization properties of lignite. The results indicated the fragmentation index increased from 3.10 to 30.41 with the increase in temperature and particle size. Pulverization ratio increased slightly from 0.39 to 0.63% with temperature, and it decreased from 0.58 to 0.36% with particle size. Fragmentation index and pulverization ratio increased rapidly from 1.20 to 5.50 and 0.05 to 0.47%, respectively, and then tended to grow slowly with drying time. Fragmentation index was linearly related to the loss of moisture content. Different kinds of fragmentation and pulverization occurred at the same time: fine particles exfoliated from the surface, and there were also fragmentation at the outer zone or the core of the particles to produce the smaller particles. The evolutions of macropores might be the main reason of thermal fragmentation.

Effect of moisture distribution in pore structure on fragmentation characteristics of lignite

ABSTRACT The experiments were performed to explore the effect of moisture on fragmentation properties of Mengdong (MD) lignite, Xiao Longtan (XLT) lignite, and Zhaotong (ZT) lignite with temperature of 200°C and particle size of 13–10 mm using the fixed bed reactor. It showed fragmentation ratio and pulverization ratio increased, and particle size variation ratio decreased with an increase in initial moisture of lignite. The distribution of moisture in pores under different initial moisture contents was analyzed by nuclear magnetic resonance. The distribution of moisture in pores between raw and dried lignite was different. The water content in macropores rapidly decreased, but water content in mesopores remained constant in prior period and then slightly decreased with the residence time increasing. There was a good connectivity between macropores and mesopores. The water in micropores, which hardly influenced fragmentation, was generally closed and not favored for the mobility of water. The water in macropores had a significant effect on fragmentation of lignite. However, when the moisture content in macropores was less than 0.10 g/g coal, the degree of fragmentation became little.

Enhancing lignite flotation performance by mechanical thermal expression treatment

ABSTRACT The developed pore distribution and large amount of oxygen functional groups have a detrimental effect on lignite flotation. The effect of mechanical thermal expression treatment (MTET) on lignite flotation performance was investigated in this study. The pore distribution and functional groups of the lignite before and after MTET were analyzed using static nitrogen adsorption method, mercury intrusion porosimetry, and Fourier transform infrared (FTIR) spectroscopy. The results showed that the clean coal yield after MTET at the 9 MPa and 200°C condition was 21.11% higher than that of untreated coal under the same flotation conditions. Both hydrophilic oxygen functional groups and porosity of the lignite decreased after MTET, increasing the absorption efficiency of oil collector on the lignite surface and the probability of bubble–particle attachment. The results of this study are expected to provide a basic understanding of the effect of MTET on lignite flotation.