Quinten Knijnenburg | Researchain

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Dalton Transactions | 2006

Ligand-centred reactivity in diiminepyridine complexes

Quinten Knijnenburg; Sandro Gambarotta; Peter H. M. Budzelaar

The diiminepyridine ligand, made famous by Brookhart and Gibson a decade ago through its use in the first iron-containing olefin polymerization catalyst, also displays an amazing variety of ligand-centred reactions, including electron transfer, alkylation, dimerization and deprotonation. The present Perspective summarizes these reactions and also speculates on the links between ligand- and metal-centred reactivity.

Journal of the American Chemical Society | 2005

Formation of a paramagnetic Al complex and extrusion of Fe during the reaction of (Diiminepyridine)Fe with AIR3 (R = Me, et)

J. Scott; S. Gambarotta; I. Korobkov; Quinten Knijnenburg; B. de Bruin; Peter H. M. Budzelaar

European Journal of Inorganic Chemistry | 2004

The Electronic Structure of (Diiminopyridine)cobalt(I) Complexes

Quinten Knijnenburg; T. Martijn Kooistra; Peter H. M. Budzelaar

Angewandte Chemie | 2001

Olefin Polymerization with [{bis(imino)pyridyl}CoIICl2]: Generation of the Active Species Involves CoI

T. Martijn Kooistra; Quinten Knijnenburg; J. M. M. Smits; Andrew D. Horton; Peter H. M. Budzelaar; Anton W. Gal

Journal of Molecular Catalysis A-chemical | 2005

Olefin hydrogenation using diimine pyridine complexes of Co and Rh

Quinten Knijnenburg; Andrew D. Horton; Harry van der Heijden; T. Martijn Kooistra; J. M. M. Smits; Bas de Bruin; Peter H. M. Budzelaar; Anton W. Gal

Organometallics | 2006

Reaction of the diimine pyridine ligand with aluminum alkyls : An unexpectedly complex reaction

Quinten Knijnenburg; J. M. M. Smits; Peter H. M. Budzelaar

European Journal of Inorganic Chemistry | 2003

Cobalt Chloride Complexes of N3 and N4 Donor Ligands

T. Martijn Kooistra; Koen F. W. Hekking; Quinten Knijnenburg; Bas de Bruin; Peter H. M. Budzelaar; René de Gelder; J. M. M. Smits; Anton W. Gal

Inorganica Chimica Acta | 2004

Chemical ligand non-innocence in pyridine diimine Rh complexes

T. Martijn Kooistra; Erik Schwartz; Quinten Knijnenburg; Peter H. M. Budzelaar; Anton W. Gal

Comptes Rendus Chimie | 2004

Reaction of AlEt2Cl with the diiminepyridine ligand: an unexpected product

Quinten Knijnenburg; J. M. M. Smits; Peter H. M. Budzelaar

Archive | 2002

Hydrogenation catalyst and catalysed hydrogenation process

Quinten Knijnenburg; Andrew D. Horton; Der Heijden Harry Van; Antonius Wilhelmus Gal; Petrus Henricus Maria Budzelaar

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