R. Craig Robinson

SiC and Si3N4 Recession Due to SiO2 Scale Volatility Under Combustor Conditions

SiC and Si3N4 materials were tested under various turbine engine combustion environments, chosen to represent either conventional fuel-lean or fuel-rich mixtures proposed for high speed aircraft. Representative CVD, sintered, and composite materials were evaluated in both furnace and high pressure burner rig exposure. While protective SiO2 scales form in all cases, evidence is presented to support paralinear growth kinetics, i.e. parabolic growth moderated simultaneously by linear volatilization. The volatility rate is dependent on temperature, moisture content, system pressure, and gas velocity. The burner tests were used to map SiO2 volatility (and SiC recession) over a range of temperature, pressure, and velocity. The functional dependency of material recession (volatility) that emerged followed the form: exp(-Q/RT) * Px * vy. These empirical relations were compared to rates predicted from the thermodynamics of volatile SiO and SiOxHv reaction products and a kinetic model of diffusion through a moving ...

Ceramic Matrix Composite Vane Subelement Testing in a Gas Turbine Environment

Vane subelements were fabricated from a silicon carbide fiber reinforced silicon carbide matrix (SiC/SiC) composite and were coated with an environmental barrier coating (EBC). A test configuration for the vanes in a gas turbine environment was designed and fabricated. Prior to testing, finite element analyses were performed to predict the temperatures and stress conditions present in vane during rig testing. This paper discusses the test configuration, the finite element analysis predictions, and results of the vane testing.Copyright

Oxidation Behavior of Prospective Silicon Nitride Materials for Advanced Microturbine Applications

Various laboratory tests have shown that high-pressure water vapor environments combined with elevated temperatures and intermediate gas velocities (current facilities limited to about 50 m/s) can cause grain boundary degradation and material recession in silica formers. Recent tests include burner rig testing conducted by NASA [1], Honeywell Engines & Systems [2], Siemens Power Generation [3], CRIEPI in Japan [4, 5], “Keiser rig” testing at Oak Ridge National Laboratory (ORNL) [6], and engine testing in the Allison 501K industrial gas turbine [7]. This paper presents a summary of oxidation test data of candidate silicon nitride materials for advanced microturbine applications. These data are of interest to microturbine component designers in order to determine the limits of safe unprotected component operation with respect to the given turbine environment, as well as to understand the behavior of ceramic microturbine components once local spallation of the protective environmental barrier coating has occurred.This paper intends to give materials and engine development engineers some guidance with respect to the different test facility capabilities and the prevailing oxidation/recession mechanisms to better understand/interprete the oxidation test results when developing new ceramic material compositions and environmental barrier coating systems.Copyright