R. I. Aminov

Synthesis of N-alkylanilines and substituted quinolines by reaction of aniline with alcohols and CCl4 effected with Ni-containing catalysts

Syntheses of N-alkylanilines and 2,3-disubstituted quinolines by the reaction of aniline with CCl4 and aliphatic alcohols under the action of nickel-containing catalysts, in particular, Ni(OAc)2·4H2O-Et3N.

Synthesis of N-benzylidenebenzylamine from benzylamine under the action of iron-containing catalysts in CCl4

A direct synthesis of N-benzylidenebenzylamine from benzylamine in the presence of iron-containing catalysts was performed with the 92–96% yield. The reaction proceeds in tetrachloromethane at 80–85°C over 8 h.

Synthesis of substituted quinolines by the reaction of anilines with alcohols and CCl4 in the presence of Fe-containing catalysts

Substituted quinolines were synthesized by the reaction of aniline derivatives with aliphatic alcohols and CCl4 upon the action of the FeCl3·6H2O catalyst.

Synthesis of quinolines by iron-catalyzed reaction of anilines with propane-1,3-diol

Quinoline and its derivatives were synthesized by cyclocondensation of anilines with propane-1,3-diol in 57–96% yield in the presence of iron-containing catalysts in carbon tetrachloride.

Quinolines synthesis by reacting 1,3-butanediol with anilines in the presence of iron catalysts

Abstract2-, 4-, 6-, 7-, and 8-substituted quinolines were synthesized in 78–95% yield by the reaction of 1,3- butanediol with anilines in the presence of iron catalysts in carbon tetrachloride.

Alkylation of aniline with methanol in the presence of FeCl3 · 6H2O in carbon tetrachloride

The reaction of aniline with methanol in the presence of FeCl3 · 6 H2O in carbon tetrachloride leads to the formation of N-methyl- and N,N-dimethylanilines and 4,4′-methylenebis(N,N-dimethylaniline).

Synthesis of diamantane via skeletal isomerization of hydrogenated cyclohepta-1,3,5-triene dimers in ionic liquid [Et 3 NH] + [Al 2 Cl 7 ] –

Diamantane was synthesized in 91–97% yield by skeletal isomerization of a mixture of hydrogenated cyclohepta-1,3,5-triene dimers, pentacyclo[8.4.0.03,7.04,14.06,11]tetradecane and pentacyclo-[7.5.0.02,8.05,14.07,11]tetradecane, at a ratio of 3: 2 in the presence of ionic liquid [Et3NH]+ [Al2Cl7]–.