R. Macatangay

Atmospheric carbon dioxide retrieved from the Greenhouse gases Observing SATellite (GOSAT): Comparison with ground-based TCCON observations and GEOS-Chem model calculations

We retrieved column-averaged dry air mole fractions of atmospheric carbon dioxide (X_CO_2) from backscattered short-wave infrared (SWIR) sunlight measured by the Japanese Greenhouse gases Observing SATellite (GOSAT). Over two years of X_CO_2 retrieved from GOSAT is compared with X_CO_2 inferred from collocated SWIR measurements by seven ground-based Total Carbon Column Observing Network (TCCON) stations. The average difference between GOSAT and TCCON X_CO_2 for individual TCCON sites ranges from −0.87 ppm to 0.77 ppm with a mean value of 0.1 ppm and standard deviation of 0.56 ppm. We find an average bias between all GOSAT and TCCON X_CO_2 retrievals of −0.20 ppm with a standard deviation of 2.26 ppm and a correlation coefficient of 0.75. One year of XCO2 was retrieved from GOSAT globally, which was compared to global 3-D GEOS-Chem chemistry transport model calculations. We find that the latitudinal gradient, seasonal cycles, and spatial variability of GOSAT and GEOS-Chem agree well in general with a correlation coefficient of 0.61. Regional differences between GEOS-Chem model calculations and GOSAT observations are typically less than 1 ppm except for the Sahara and central Asia where a mean difference between 2 to 3 ppm is observed, indicating regional biases in the GOSAT X_CO_2 retrievals unobserved by the current TCCON network. Using a bias correction scheme based on linear regression these regional biases are significantly reduced, approaching the required accuracy for surface flux inversions.

The CarboEurope Regional Experiment Strategy

Quantification of sources and sinks of carbon at global and regional scales requires not only a good description of the land sources and sinks of carbon, but also of the synoptic and mesoscale meteorology. An experiment was performed in Les Landes, southwest France, during May?June 2005, to determine the variability in concentration gradients and fluxes of CO2. The CarboEurope Regional Experiment Strategy (CERES; see also http://carboregional.mediasfrance.org/index) aimed to produce aggregated estimates of the carbon balance of a region that can be meaningfully compared to those obtained from the smallest downscaled information of atmospheric measurements and continental-scale inversions. We deployed several aircraft to concentration sample the CO2 and fluxes over the whole area, while fixed stations observed the fluxes and concentrations at high accuracy. Several (mesoscale) meteorological modeling tools were used to plan the experiment and flight patterns. Results show that at regional scale the relation between profiles and fluxes is not obvious, and is strongly influenced by airmass history and mesoscale flow patterns. In particular, we show from an analysis of data for a single day that taking either the concentration at several locations as representative of local fluxes or taking the flux measurements at those sites as representative of larger regions would lead to incorrect conclusions about the distribution of sources and sinks of carbon. Joint consideration of the synoptic and regional flow, fluxes, and land surface is required for a correct interpretation. This calls for an experimental and modeling strategy that takes into account the large spatial gradients in concentrations and the variability in sources and sinks that arise from different land use types. We briefly describe how such an analysis can be performed and evaluate the usefulness of the data for planning of future networks or longer campaigns with reduced experimental efforts.

Side by side measurements of CO2 by ground-based Fourier transform spectrometry (FTS)

High resolution solar absorption Fourier transform spectrometry (FTS) is the most precise ground-based remote sensing technique to measure the total column of atmospheric carbon dioxide. For carbon cycle studies as well as for the calibration and validation of spaceborne sensors the instrumental comparability of FTS systems is of critical importance. Retrievals from colocated measurements by two identically constructed FTS systems have been compared for the first time. Under clear sky conditions a precision for the retrieved xCO2 better than ˜0.1% is demonstrated and the instruments agree within ˜0.07%. An important factor in achieving such good comparability of the xCO2 is an accurate sampling of the internal reference laser. A periodic laser mis-sampling leads to ghosts (artificial spectral lines), which are mirrored images from original spectral lines. These ghosts can interfere with the spectral range of interest. The influence of the laser mis-sampling on the retrieved xCO2 and xO2 in the near-IR has been quantified. For a typical misalignment, the ratio of the ghost intensity compared to the intensity of the original spectral line is about 0.18% and in this case the retrieved xCO2 is wrong by 0.26% (1 ppm) and the retrieved xO2 is wrong by 0.2%.

Determining relationships and mechanisms between tropospheric ozone column concentrations and tropical biomass burning in Thailand and its surrounding regions

This study aims to determine the variability and trends of tropical biomass burning, tropospheric ozone levels from 2005–2012 in Thailand and the ozone transport from the surrounding regions. Intense biomass burning and tropospheric ozone in this area have a seasonal variability with the maximum generally occurring during the dry season. The northern part of Thailand was observed to have high tropospheric ozone during the dry peak season in April. Forward trajectory analysis determined that ozone sources due to biomass burning in the northern and western surrounding regions (Myanmar, Laos and India) enhance the tropospheric ozone column in northern Thailand. Seasonal variations were also seen for the middle and northeastern regions of Thailand. During August, most biomass burning occurs in Indonesia and Malaysia. However, forward trajectory analysis showed that the effect in the tropospheric ozone column level in the southern part of Thailand is minimal from these regions. Eight-year trends of tropospheric ozone column were also calculated for the different regions of Thailand. However, statistical analysis showed that these trends were not significant. The interannual variability of the tropospheric ozone column concentrations due to El Nino Southern Oscillation were also investigated. It was observed that the best correlation of the tropospheric ozone column with the Oceanic Nino Index (ONI) occured when ONI was advanced 3 months for the north, northeast and south regions of Thailand and 4 months for the middle region of Thailand.

Simultaneous retrieval of atmospheric CO2 and light path modification from space-based spectroscopic observations of greenhouse gases: methodology and application to GOSAT measurements over TCCON sites

This paper presents an improved photon path length probability density function method that permits simultaneous retrievals of column-average greenhouse gas mole fractions and light path modifications through the atmosphere when processing high-resolution radiance spectra acquired from space. We primarily describe the methodology and retrieval setup and then apply them to the processing of spectra measured by the Greenhouse gases Observing SATellite (GOSAT). We have demonstrated substantial improvements of the data processing with simultaneous carbon dioxide and light path retrievals and reasonable agreement of the satellite-based retrievals against ground-based Fourier transform spectrometer measurements provided by the Total Carbon Column Observing Network (TCCON).

Factors influencing surface CO2 variations in LPRU, Thailand and IESM, Philippines

Surface carbon dioxide concentrations were measured using a non-dispersive infrared carbon dioxide sensor at Lampang Rajabhat University from April to May 2013 and at the University of the Philippines-Diliman campus starting September 2013. Factors influencing the variations in these measurements were determined using multiple linear regression and a Lagrangian transport model. Air temperature and sea level pressure were the dominant meteorological factors that affect the CO2 variations. However, these factors are not enough. Surface CO2 flux and transboundary transport needs to be considered as well.

Project MANTRA: Multi-platform ANalysis of TRace Gases and Aerosols with a Focus on Atmospheric CO 2 Measurements for Southeast Asia

This chapter gives an overview of Project MANTRA (Multi-platform Analysis of Trace gases and Aerosols) focusing on atmospheric carbon dioxide. Specifically, this chapter addresses how surface CO2 data can be measured in a cost-effective manner. Applications are shown for measurements at Lampang Rajabhat University (LPRU), Thailand, at the University of the Philippines Institute of Environmental Science and Meteorology (UP-IESM) and at Binan, Laguna, Philippines. The measured data were also compared with simulations using the Regional Emissions Inventory in Asia (REAS ver. 2.1) and the Stochastic Time-Inverted Lagrangian Transport (STILT) model. Mobile measurements taken from the Lampang-Tak route in Thailand and from Quezon City-Baguio route in the Philippines are also shown. Broadening to the regional scale, measurements from the Ship of Opportunity (SOOP), from the High-performance Instrumented Airborne Platform for Environmental Research (HIAPER) Pole-to-Pole Observation (HIPPO) and from the Greenhouse gases Observing SATellite (GOSAT) over the Southeast Asian region are presented. New initiatives such as the Total Carbon Column Observing Network (TCCON) Southeast Asia are also introduced.

Finding the Optimum Resolution, and Microphysics and Cumulus Parameterization Scheme Combinations for Numerical Weather Prediction Models in Northern Thailand: A First Step towards Aerosol and Chemical Weather Forecasting for Northern Thailand

Weather forecasts dictate our daily activities and allow us to respond properly during extreme weather events. However, weather forecasts are never perfect, but differences with model output and with observations can be minimized. Discrepancies between meteorological observations and weather model outputs are often caused by resolution differences (point vs. grid comparisons) and by the parameterizations used in the model. Atmospheric model parameterization refers to substituting small-scale and complicated atmospheric processes by simplified ones. In order to make weather forecasts more accurate, one can either increase the model resolution or improve the parameterizations used. Increasing model resolution can simulate small-scale atmospheric processes better, but takes a longer simulation time. On the other hand, improving model parameterization schemes involve in-depth measurements, analysis and research on numerous atmospheric processes. However, one can find a combination of existing parameterization schemes that would minimize observation-model differences. It is therefore essential to ask the question, “What model resolution and parameterization scheme combinations at a particular location and at particular seasons produce model output that has the smallest difference with observations simulated at a reasonable amount of time?” Northern Thailand is a meteorologically active and unstable region especially during the summer and monsoon months (e.g. intense thunderstorms, hail storms, etc). It is also where high concentrations of air pollutants occur during the dry months (e.g. haze). It is therefore essential to have model forecasts close to observations for this region to reduce risk from weather and from air quality degradation. This study aims to find the optimum model resolution and parameterization scheme combinations at particular provinces in northern Thailand with available data during the wet and dry seasons that produces minimum differences with observations. Nested model simulations were performed using the Weather Research and Forecasting (WRF) model (v. 3.6) ran in the High-Performance Computer (HPC) cluster of the National Astronomical Research Institute of Thailand (NARIT) for northern Thailand (2 km spatial resolution and hourly output), for the whole of Thailand (10 km spatial resolution and hourly output), and for the entire Southeast Asia (50 km spatial resolution and 3-hourly output). Combinations of the WRF Single-Moment 3-class, the WRF Single-Moment 5-class, the Lin et al. (Purdue), the WRF Single-Moment 6-class and the WRF Double-Moment 6-class microphysics parameterization schemes, as well as the Betts-Miller-Janjic, the Kain-Fritsch scheme, the Grell-Freitas (GF) ensemble and the Grell 3D cumulus parameterization schemes were utilized to determine the optimum resolution and parameterization of the model when compared to observations. Measured data came from the Thai Meteorological Department (TMD) weather stations in Chiang Mai, Chiang Rai and Lampang in northern Thailand from December 1-15, 2014 (cool dry season), from May 1-12 (hot dry season) and from August 1-7, 2015 (wet season). Results showed a seasonal dependence on the optimum microphysics and convective parameterization combination scheme. It was also found out that cloud resolving model grid sizes still failed to capture convective process as indicated by the derived optimum resolution for the hot-dry and wet seasons.