R. Pedrós

Chlorophyll fluorescence emission spectrum inside a leaf

Chlorophyll a fluorescence can be used as an early stress indicator. Fluorescence is also connected to photosynthesis so it can be proposed for global monitoring of vegetation status from a satellite platform. Nevertheless, the correct interpretation of fluorescence requires accurate physical models. The spectral shape of the leaf fluorescence free of any re-absorption effect plays a key role in the models and is difficult to measure. We present a vegetation fluorescence emission spectrum free of re-absorption based on a combination of measurements and modelling. The suggested spectrum takes into account the photosystem I and II spectra and their relative contribution to fluorescence. This emission spectrum is applicable to describe vegetation fluorescence in biospectroscopy and remote sensing.

Column‐integrated aerosol optical properties from ground‐based spectroradiometer measurements at Barrax (Spain) during the Digital Airborne Imaging Spectrometer Experiment (DAISEX) campaigns

[1] The Digital Airborne Imaging Spectrometer Experiment (DAISEX) was carried out for the European Space Agency (ESA) in order to develop the potential of spaceborne imaging spectroscopy for a range of different scientific applications. DAISEX involved simultaneous data acquisitions using different airborne imaging spectrometers over test sites in southeast Spain (Barrax) and the Upper Rhine valley (Colmar, France, and Hartheim, Germany). This paper presents the results corresponding to the columnintegrated aerosol optical properties from ground-based spectroradiometer measurements over the Barrax area during the DAISEX campaign days in the years 1998, 1999, and 2000. The instruments used for spectral irradiance measurements were two Licor 1800 and one Optronic OL-754 spectroradiometers. The analysis of the spectral aerosol optical depth in the visible range shows in all cases the predominance of the coarse-particle mode over the fine-particle mode. The analysis of the back trajectories of the air masses indicates a predominance of marine-type aerosols in the lower atmospheric layers in all cases. Overall, the results obtained show that during the DAISEX there was a combination of maritime aerosols with smaller continental aerosols. INDEX TERMS: 0305 Atmospheric Composition and Structure: Aerosols and particles (0345, 4801); 0345 Atmospheric Composition and Structure: Pollution—urban and regional (0305); 0394 Atmospheric Composition and Structure: Instruments and techniques; 3360 Meteorology and Atmospheric Dynamics: Remote sensing; 4801 Oceanography: Biological and Chemical: Aerosols (0305); KEYWORDS: atmospheric composition and structure, instruments and techniques, remote sensing

Values of broad band turbidity coefficients in a mediterranean coastal site

Abstract The Angstrom turbidity coefficient, the Linke turbidity factor, and the Unsworth–Monteith coefficient have been determined and analysed based on measurements of normal direct irradiance and global horizontal irradiance taken in Valencia, Spain, between January 1990 and December 1996. The data, which were acquired automatically and continuously, have been filtered to select only those values corresponding to clear sky conditions. To determine the Angstrom turbidity coefficient the method proposed by Louche et al. has been used whilst the expression for δCDA proposed by Kasten was used to obtain the Linke turbidity coefficient. The Angstrom turbidity coefficient showed a minimum in winter with values between 0.06 and 0.12. It tended to increase in the spring and reach a maximum between 0.22 and 0.29 in summer before falling again in the autumn. The daily and annual evolution of all three coefficients were very similar with correlation coefficients between pairs of them close to 1.

The optimisation of the angle of inclination of a solar collector to maximise the incident solar radiation

Irradiation data, recorded on vertical surfaces facing north, south, east and west and on a horizontal surface every ten minutes during daylight hours from January–December 1992 in Valencia, Spain, have been compared with estimated solar irradiation from inclined-surface models. Results show that Hays model most accurately reproduces the variation in irradiation on all vertical surfaces.

Aerosol closure study by lidar, Sun photometry, and airborne optical counters during DAMOCLES field campaign at El Arenosillo sounding station, Spain

We present a comparison of aerosol properties derived from in situ and remote sensing instruments during DAMOCLES campaign, aimed at investigating the equivalence between the instrumentation and methodologies employed by several Spanish groups to study atmospheric aerosols at a regional background site. The complete set of instruments available during this closure experiment allowed collecting a valuable high-resolution aerosol measurement data set. The data set was augmented with airborne in situ measurements carried out in order to characterize aerosol particles during the midday of 29 June 2006. This work is focused on aerosol measurements using different techniques of high-quality instruments (ground-based remote sensing and aircraft in situ) and their comparisons to characterize the aerosol vertical profiles. Our results indicate that the variability between the detected aerosol layers was negligible in terms of aerosol optical properties and size distributions. Relative differences in aerosol extinction coefficient profiles were less than 20% at 355 and 532 nm and less than 30% at 1064 nm, in the region with high aerosol concentration. Absolute differences in aerosol optical depth (AOD) were below 0.01 at 532 and 1064 nm and less than 0.02 at 355 nm, less than the uncertainties assumed in the AOD obtained from elastic lidar. Columnar values of the lidar ratio revealed some discrepancies with respect to the in situ aircraft measurements, caused fundamentally by the lack of information in the lowest part of the boundary layer.

Aerosol optical characteristics from a summer campaign in an urban coastal Mediterranean area

The authors present a preliminary study of some optical properties of atmospheric aerosols over the area of Valencia, Spain, a coastal Mediterranean city. Measurements of spectral direct irradiance in the 300-1100 nm range were taken simultaneously at three sites: rural-continental, rural-coastal, and urban-coastal, all located within a 50 km radius of the city of Valencia. The irradiance measurements were obtained using three Li-cor 1800 spectroradiometers provided with radiance limiting tubes with field of views (FOVs) of 4.7/spl deg/. The measurements were made under clear sky conditions during a field campaign carried out in the summer of 1998. In order to avoid the uncertainties associated with the determination of the water vapor content and the other atmospheric constituents, the analysis of the spectral aerosol optical thickness (AOT) values was limited to the 400-670 mm spectral band. From the values of the spectral AOT, both the Angstrom coefficients and the aerosol size distributions were obtained. The results show the great dependence of the optical aerosol characteristic on the direction of the prevailing winds (maritime or continental) in this area.

Aerosol Lidar Intercomparison in the Framework of SPALINET—The Spanish Lidar Network: Methodology and Results

A group of eight Spanish lidars was formed in order to extend the European Aerosol Research Lidar Network-Advanced Sustainable Observation System (EARLINET-ASOS) project. This study presents intercomparisons at the hardware and software levels. Results of the system intercomparisons are based on range-square-corrected signals in cases where the lidars viewed the same atmospheres. Comparisons were also made for aerosol backscatter coefficients at 1064 nm (2 systems) and 532 nm (all systems), and for extinction coefficients at 532 nm (2 systems). In total, three field campaigns were carried out between 2006 and 2007. Comparisons were limited to the highest layer found before the free troposphere, i.e., either the atmospheric boundary layer or the aerosol layer just above it. Some groups did not pass the quality assurance criterion on the first attempt. Following modification and improvement to these systems, all systems met the quality criterion. The backscatter algorithm intercomparison consisted of processing lidar signal profiles simulated for two types of atmospheric conditions. Three stages with increasing knowledge of the input parameters were considered. The results showed that all algorithms work well when all inputs are known. They also showed the necessity to perform, when possible, additional measurements to attain better estimation of the lidar ratio, which is the most critical unknown in the elastic lidar inversion.

A New Method for Determining the Ångström Turbidity Coefficient from Broadband Filter Measurements

Abstract In this work, a new method for determining Angstrom turbidity coefficients is presented. This method is based on broadband filter irradiance measurements. By combining measurements obtained with different filters it is possible to obtain a single value of the turbidity coefficient representative of the whole measurement range of the pyrheliometer. The results provided by this new method are compared with the original Angstrom method and turbidity coefficient values derived by spectroradiometric measurements. The results reproduce the actual values, as measured by a spectroradiometer, better than the previous best correlation did, thus demonstrating the advantage of analyzing the optical thickness from bands covering the whole spectral range.

Climatology of the Aerosol Extinction-to-Backscatter Ratio from Sun-Photometric Measurements

The elastic lidar equation contains two unknown atmospheric parameters, namely, the particulate optical extinction and backscatter coefficients, which are related through the lidar ratio (i.e., the particulate-extinction-to-backscatter ratio). So far, independent inversion of the lidar signal has been carried out by means of Raman lidars (usually limited to nighttime measurements), high-spectral-resolution lidars, or scanning elastic lidars under the assumption of a homogeneously vertically stratified atmosphere. In this paper, we present a procedure to obtain the lidar ratio at 532 nm by a combined Sun-photometer-aerosol-model inversion, where the viability of the solution is largely reinforced by assimilating categorized air-mass back-trajectory information. Thus, iterative lidar-ratio tuning to reconstruct the Sun-photometric aerosol optical depth (AOD) is additionally constrained by the air-mass back trajectories provided by the hybrid single-particle Lagrangian integrated-trajectory model. The retrieved lidar ratios are validated with inversions of lidar data based on the Klett-Fernald-Sasano algorithm and with the Aerosol Robotic Network (AERONET)-retrieved lidar ratios. The estimated lidar ratios concur with the AERONET-retrieved lidar ratios and with those of the well-known KFS inversion constrained with Sun-photometric AOD values and embedded single-scattering models. The proposed method can be applied to routinely extract climatological values of the lidar ratio using measurements of direct solar irradiance (more numerous than those of sky radiance).

Aerosol size distributions and air mass back trajectories over a Mediterranean coastal site

In this paper we present the results obtained from ground-based measurements using a CIMEL sunphotometer during selected clear days corresponding to the winter and summer periods of 2002 in Valencia, an urban coastal Mediterranean site. From the direct solar extinction data the spectral aerosol optical depth (AOD) has been retrieved. This spectral AOD has been used to obtain the size distribution function from the King inversion algorithm. The results show the great dependence of the optical aerosol characteristics on the dominant winds in this area. This location is subject to winds which have either a land or Mediterranean origin which frequently mask the aerosols coming from the Atlantic or north Africa, respectively.