R. Sundararajan
Government Arts College, Coimbatore
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Featured researches published by R. Sundararajan.
Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy | 2013
R. Suresh; D. Kamalakkannan; K. Ranganathan; R. Arulkumaran; R. Sundararajan; S.P. Sakthinathan; S. Vijayakumar; K. Sathiyamoorthi; V. Mala; Ganesan Vanangamudi; Kannan Thirumurthy; P. Mayavel; Ganesamoorthy Thirunarayanan
A series of aryl imines have been synthesized by Fly-ash: H2SO4 catalyzed microwave assisted process under solvent-free conditions. The yields of the imines have been found to be more than 87%. The purity of all imines has been checked using their physical constants and spectral data as published earlier in literature. The UV λmaxCN(nm), infrared νCN(cm(-1)), NMR δ(ppm) of CH and CN spectral data have been correlated with Hammett substituent constants and F and R parameters using single and multi-linear regression analysis. From the results of statistical analysis, the effect of substituents on the above spectral data has been studied. The antimicrobial activities of All synthesised imines have been studied using Bauer-Kirby method.
Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy | 2009
C. Ramachandraraja; A. Antony Joseph; R. Sundararajan; V. Siva Shankar; P. Murugakoothan
The novel nonlinear optical single crystal of bisthiourea nickel chloride (BTNC) was grown successfully by slow evaporation technique using water as solvent. The lattice parameters of the grown crystal have been determined by X-ray diffraction studies. Vibrational spectra were recorded to determine the symmetries of molecular vibrations. Presence of various functional groups of BTNC was identified through FTIR and Raman spectroscopic analyses. Optical absorbance spectrum recorded in the wavelength range of UV-vis-NIR revealed that this crystal has good optical transparency in the range 200-2000 nm. The second harmonic generation test of BTNC revealed the nonlinear nature of the crystal. The BTNC crystal was analyzed by differential thermal and thermo gravimetric analysis (DTA-TGA) to obtain its thermal stability.
Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy | 2015
S. Anand; R. Sundararajan; C. Ramachandraraja; S. Ramalingam; R. Durga
In the present research work, the FT-IR, FT-Raman spectra of the Bis(thiourea) Nickel chloride (BTNC) were recorded and analyzed. The observed fundamental frequencies in finger print and functional group regions were assigned according to their uniqueness region. The computational calculations were carried out by HF and DFT (B3LYP and B3PW91) methods with 6-31++G(d,p) and 6-311++G(d,p) basis sets and the corresponding results were tabulated. The present organo-metallic compound was made up of covalent and coordination covalent bonds. The modified vibrational pattern of the complex molecule associated with ligand group was analyzed. Furthermore, the (13)C NMR and (1)H NMR spectral data were calculated by using the gauge independent atomic orbital (GIAO) method with B3LYP/6-311++G(d,p) basis set and their spectra were simulated and the chemical shifts linked to TMS were compared. A investigation on the electronic and optical properties; absorption wavelengths, excitation energy, dipole moment and frontier molecular orbital energies were carried out. The kubo gap of the present compound was calculated related to HOMO and LUMO energies which confirm the occurring of charge transformation between the base and ligand. Besides frontier molecular orbitals (FMO), molecular electrostatic potential (MEP) was performed. The NLO properties related to Polarizability and hyperpolarizability based on the finite-field approach were also discussed.
Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy | 2009
C. Ramachandraraja; R. Sundararajan; V. Krishnakumar
The organometallic crystal bisthiourea manganese chloride (BTMC) was grown by slow evaporation technique using water as solvent. The lattice parameters of the grown crystal have been determined by X-ray diffraction studies. Vibrational spectra were recorded to determine the symmetries of molecular vibrations. The observed Raman and infrared bands were also assigned and discussed. The optical transmission spectral study revealed the transmitting ability of the crystal in the entire visible region. The TGA/DTA analysis explains the thermal stability of the investigated crystal.
Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy | 2008
C. Ramachandraraja; R. Sundararajan
Single crystals of bisthiourea cadmium bromide (BTCB), a new metallorganic material crystallizing in orthorhombic system were grown from slow evaporation solution growth. The grown crystals were characterized by X-ray diffraction, FTIR and FT-Raman spectral studies. The crystals were also subjected to TGA/DTA analysis and second harmonic generation test. The transmission characteristics of the crystal was also studied.
Journal of The Chilean Chemical Society | 2013
Ranganathan Arulkumaran; Sambandhamoorthy Vijayakumar; S Pazhanivel Sakthinathan; Dakshnamoorthy Kamalakkannan; K. Ranganathan; R. Suresh; R. Sundararajan; Ganesan Vanangamudi; Ganesamoorthy Thirunarayanan
In the present study we have prepared a series of some chalcones using solvent - free Aldol - condensation by microwave irradiation. The yields of the ketones are more than 60%. The synthesised chalcones were characterized by their analytical, physical and spectral data. The antimicrobial activities of substituted styryl 3-thienyl ketones have been studied using Bauer-Kirby method.
Materials Science and Applied Chemistry | 2017
Santhanam John Joseph; K. Ranganathan; R. Suresh; Ranganathan Arulkumaran; R. Sundararajan; Dakshnamoorthy Kamalakkannan; Sakthivel Pazhanivel Sakthinathan; Ganesan Vanangamudi; Selvakumar Dineshkumar; Kannan Thirumurthy; Inabasekaran Muthuvel; Ganesamoorthy Thirunarayanan; Kunasekaran Viveksarathi
Abstract The solid acidic nanocatalyst fly-ash:H3PO4 was prepared and characterized by FT-IR, SEM, EDS and TEM analysis. This catalyst was utilized for aldol condensation, coupling and cyclization reaction. The effect of catalytic activity of this fly-ash:H3PO4 nanocatalyst was studied with the obtained yield of products under solvent-free conditions. In this synthetic reaction the obtained yields were more than 95 %.
Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy | 2007
V. Krishnakumar; C. Ramachandraraja; R. Sundararajan
International Letters of Chemistry, Physics and Astronomy | 2013
S. Vijayakumar; R. Arulkumaran; R. Sundararajan; S.P. Sakthinathan; R. Suresh; D. Kamalakkannan; K. Ranganathan; K. Sathiyamoorthy; V. Mala; Ganesan Vanangamudi; Ganesamoorthy Thirunarayanan
International Letters of Chemistry, Physics and Astronomy | 2013
K. Ranganathan; R. Suresh; D. Kamalakkannan; R. Arulkumaran; R. Sundararajan; S.P. Sakthinathan; S. Vijayakumar; Ganesan Vanangamudi; Kannan Thirumurthy; P. Mayavel; Ganesamoorthy Thirunarayanan