Rahul Chhibber

Investigation on flux design for submerged arc welding of high-strength low-alloy steel

Fluxes in submerged arc welding of high-strength low-alloy steels are not readily available, flux compositions are not clear and compositions are patented. This study aims at the design, development and optimization of flux for submerged arc welding of high-strength low-alloy steel. Extreme vertices design suggested by McLean and Anderson is used to formulate twenty-one fluxes to study the effect of flux constituents on tensile strength, percentage elongation, impact strength, diffusible hydrogen content and microstructure of the weld metal. Mathematical models for ultimate tensile strength, percentage elongation, impact strength and diffusible hydrogen content for welded specimens versus flux constituents have been developed. From the experiments, it is found that tensile strength and elongation are affected the most with Al2O3 content, whereas CaO and CaF2 contents have significant effect on impact strength. Synergic binary effect of CaO·CaF2, CaO·MgO and Al2O3·CaF2 mixtures is more than other binary mixtures on the mechanical properties. Developed regression models have been checked for adequacy using t-test for regression coefficients and analysis of variance (F-test) for whole regression equation. Finally, optimum flux composition giving optimum mechanical and microstructural characteristics is suggested.

Effect of welding parameters on bead profile, microhardness and H2 content in submerged arc welding of high-strength low-alloy steel

In oil and gas industries, submerged arc welding is the only primarily used process to weld high thickness, large distance structural oil pipes. Welding process parameters play a significant role in determining the quality of a weld joint in submerged arc welding. In the present work, an attempt has been made to optimize the weld bead parameters: weld bead form factor, dilution, microhardness and diffusible hydrogen content for welding of structural pipe steel (API 5L X65 grade) by desirability function approach used by Derringer and Harrington. For design of experiments, response surface methodology had been used. Mathematical models for output responses had been developed in terms of welding parameters and checked for adequacy using t-test and analysis of variance (F-test). It was found that welding current was the most significant parameter controlling all the responses, and arc voltage had increasing effect on all the responses except microhardness.

Effect of surface treatment of nanoclay on the mechanical properties of epoxy/glass fiber/clay nanocomposites

Abstract A new method of silane treatment of nanoclays is reported where in the clay is nanodispersed in hydrolyzed silanes. The surface functionalization of Cloisite® 15A nanoclay has been carried out using two different silane coupling agents: 3-aminopropyltriethoxy silane and 3-glycidyloxypropyltrimethoxy silane using varied amounts of silane coupling agents, e.g. 10, 50, 200, and 400 wt% of clay. The surface modification of Cloisite® 15A has been confirmed by Fourier transform infrared spectroscopy. The modified clays were then dispersed in epoxy resin, and glass fiber-reinforced epoxy clay laminates were manufactured using vacuum bagging technique. The fiber-reinforced epoxy clay nanocomposites containing silane modified clays have been characterized using small angle X-ray scattering, transmission electron spectroscopy and differential scanning calorimetry. The results indicate that the silane treatment of nanoclay aided the exfoliation of nanoclay and also led to an increase in mechanical properties. The optimized amount of silane coupling agents was 200 wt%. The nanocomposites containing clay modified in 200 wt% of silanes exhibited an exfoliated morphology, improved tensile strength, flexural modulus, and flexural strength. The improved interfacial bonding between silane modified nanoclays and epoxy matrix was also evident from significant increase in elongation at break.

Application of Ball Indentation Technique for Mechanical Properties Estimation of Bi-Metallic Weld

This work studied the ball indentation test at room temperature to characterize the local tensile properties of bi-metallic weld joints. The weld specimens used were fabricated by joining between SA 508 Gr. 3 ferritic steel and Type 304LN stainless steel with Alloy 82 buttering on the ferritic steel side and Alloy 82/182 weld metal. The test results showed that yield stress (YS) of weld metal was slightly higher than that of Type 304 and smaller than that of SA508 Gr.3, and ultimate tensile stress (UTS) of weld metal was similar as those of Type 304 and SA508 Gr.3 base metals. Also, the values of YS and UTS of buttering layer (Alloy 82) were nearly same as those of weld metal. Heat-affected-zones (HAZs) showed higher YS and UTS values compared to their base metals.

Estimation of Gurson material parameters in bimetallic weldments for the nuclear reactor heat transport piping system

Bimetallic welds (BMWs) play a critical and indispensable role in the primary heat transport piping system of nuclear reactors. The primary heat transport system itself is the critical part of a nuclear reactor. Any failure of this system can lead to very grave consequences, not only speaking of huge monetary losses resulting from non-utilization of the reactor setup, but also immensely valuable and irreparable loss of human life. This paper describes the experimental efforts towards estimation of Gurson material parameters of base metal and weld metal regions of a BMW so as to use the micromechanical modelling approach for addressing the structural integrity issues in BMWs.

Investigations on Design and Formulation of Buttering Layer Electrode Coatings for Bimetallic Welds

The bimetallic welds (BMWs) between ferritic low alloy steels and austenitic stainless steel are used widely in steam generators of the power plants. The adoption of these welds in wide industrial applications provides feasible solutions for the flexible design of the products by using each material efficiently and economically. The present paper is an effort towards studying the development of austenitic stainless steel buttering filler material for bimetallic weld joint. The work aims at the design and development of buttering layer electrode coatings for shielded metal arc welding process using extreme vertices design methodology suggested by McLean and Anderson to study the effect of electrode coating ingredients on the buttering layer metal composition and delta ferrite content to prevent solidification cracking.

Modeling flux chemistry for submerged arc weldments of high-strength low-alloy steel

Chemical and mechanical properties of the welded joint are greatly affected by flux composition. The resulting chemical compositions of C, Si, Mn, P and S in the weld metal have been studied using formulated fluxes. The constrained mixture design, extreme vertices design, has been used to formulate fluxes to study the effect of flux constituents. Regression models were developed for weld metal content in terms of individual flux constituents and their binary mixtures for submerged arc welding of high-strength low-alloy steel. From the results, it is found that CaF2 is the most significant flux constituent and Al2O3 is the second most significant constituent among individual mixtures. CaO–MgO and CaO–Al2O3 binary mixtures are the most effective to change weld metal content. Regression mathematical models have been checked for adequacy using t-test and analysis of variance (F-test). Flux mixtures’ composition has been provided for optimum chemical composition of weld metal.

On the Microstructure and Wear Behavior of Fe–xCr–4Mn–3C Hardfacing Alloys

The present paper describes an investigation aimed at evaluating the microstructural and dry sliding adhesive wear characteristics of Fe–xCr–4Mn–3C hardfacing alloys applied through shielded metal arc welding. The effect of chromium addition on the microstructure of hardfacings was carried out by using optical microscope, field emission scanning electron microscope and X-ray mapping. Dry sliding wear tests were performed on a pin-on-disc wear tribometer. From the experimental results, it was observed that the primary carbides were refined and increased with the increase of chromium content. The morphology of carbides revealed that the primary carbides were rod shaped. The increased chromium content was also found to be beneficial to enhance hardness and wear resistance of hardfacings. The correlation between hardness and wear resistance exhibited the reliability of hardness as an indicator of the wear performance of hardfacings.

Investigations on weld metal chemistry and mechanical behaviour of bimetallic welds using CaO–CaF2–SiO2–Ni based electrode coatings

The bimetallic welds between ferritic low alloy steels and austenitic stainless steels are widely used in the heat piping transport systems of nuclear power plants for connecting the heavy section low alloy steel components with those of high temperature stainless steel pipes. The operating experience of major nuclear power plant components has recently shown that bimetallic joints can jeopardize the plant availability and safety because of increased incidences of failure. In shielded metal arc welding process, the occurrence and severity of weld defects mainly depend upon the type of electrode filler wire and the electrode coating ingredients used. The use of nickel based filler metals is no longer considered as the final solution for unexpected failures of bimetallic welds due to incidences of hot cracking. In the present paper, an attempt has been made to design and develop an intermediate electrode based on CaO–CaF2–SiO2 ternary phase diagram system and nickel as an additional electrode coating ingredient using mild steel as a filler wire for the bimetallic weld joint. The extreme vertices methodology has been used to design 21 electrode coating formulations. The quadratic regression models for weld metal chemistry, ultimate tensile strength, impact toughness, macrohardness, diffusible hydrogen content, and corrosion rate in terms of electrode coating ingredients, have been developed and checked for adequacy using analysis of variance. The work aims at studying the individual as well as combined effect of electrode coating ingredients on the measured weld responses and microstructures of the weld. Also, the electrode coating formulations suggesting multiobjective optimized solutions have been proposed.

Prediction of element transfer due to flux and optimization of chemical composition and mechanical properties in high-strength low-alloy steel weld

The transfer of elements C, Si, Mn, P and S from slag into the weld metal or from weld metal into the slag and microhardness has been studied using formulated fluxes. The fluxes have been formulated using extreme vertices design with an aim to develop mathematical models for change in element content and mechanical properties versus flux constituents for submerged arc welding of high-strength low-alloy steel. It is found that CaO is the most significant flux constituent and Al2O3 is the second most significant constituent among individual mixtures. CaO·MgO and CaO·Al2O3 among binary mixtures have significant effect on element transfer and microhardness. Developed mathematical models have been checked for adequacy using t-test and analysis of variance (F-test). Flux mixtures’ composition has been provided for optimum chemical composition and mechanical properties. One of the optimum flux mixture with composition, CaO 11.61, Al2O3 12.33, CaF2 15.00 and MgO 39.06, would be providing desirable chemical composition and mechanical properties.