Rajarathinam Parthasarathy

Investigation of mass transfer intensification under power ultrasound irradiation using 3D computational simulation: A comparative analysis

This paper aims at investigating the influence of acoustic streaming induced by low-frequency (24kHz) ultrasound irradiation on mass transfer in a two-phase system. The main objective is to discuss the possible mass transfer improvements under ultrasound irradiation. Three analyses were conducted: i) experimental analysis of mass transfer under ultrasound irradiation; ii) comparative analysis between the results of the ultrasound assisted mass transfer with that obtained from mechanically stirring; and iii) computational analysis of the systems using 3D CFD simulation. In the experimental part, the interactive effects of liquid rheological properties, ultrasound power and superficial gas velocity on mass transfer were investigated in two different sonicators. The results were then compared with that of mechanical stirring. In the computational part, the results were illustrated as a function of acoustic streaming behaviour, fluid flow pattern, gas/liquid volume fraction and turbulence in the two-phase system and finally the mass transfer coefficient was specified. It was found that additional turbulence created by ultrasound played the most important role on intensifying the mass transfer phenomena compared to that in stirred vessel. Furthermore, long residence time which depends on geometrical parameters is another key for mass transfer. The results obtained in the present study would help researchers understand the role of ultrasound as an energy source and acoustic streaming as one of the most important of ultrasound waves on intensifying gas-liquid mass transfer in a two-phase system and can be a breakthrough in the design procedure as no similar studies were found in the existing literature.

Net positive energy wastewater treatment plant via thermal pre-treatment of sludge: A theoretical case study

ABSTRACT In a wastewater treatment process, energy is mainly used in sludge handling and heating, while energy is recovered by biogas production in anaerobic digestion process. Thermal pre-treatment of sludge can change the energy balance in a wastewater treatment process since it reduces the viscosity and yield stress of sludge and increases the biogas production. In this study, a calculation based on a hypothetical wastewater treatment plant is provided to show the possibility of creating a net positive energy wastewater treatment plant as a result of implementing thermal pre-treatment process before the anaerobic digester. The calculations showed a great energy saving in pumping and mixing of the sludge by thermal pre-treatment of sludge before anaerobic digestion process.

Predicting the apparent viscosity and yield stress of mixtures of primary, secondary and anaerobically digested sewage sludge: Simulating anaerobic digesters.

Predicting the flow behaviour, most notably, the apparent viscosity and yield stress of sludge mixtures inside the anaerobic digester is essential because it helps optimize the mixing system in digesters. This paper investigates the rheology of sludge mixtures as a function of digested sludge volume fraction. Sludge mixtures exhibited non-Newtonian, shear thinning, yield stress behaviour. The apparent viscosity and yield stress of sludge mixtures prepared at the same total solids concentration was influenced by the interactions within the digested sludge and increased with the volume fraction of digested sludge - highlighted using shear compliance and shear modulus of sludge mixtures. However, when a thickened primary - secondary sludge mixture was mixed with dilute digested sludge, the apparent viscosity and yield stress decreased with increasing the volume fraction of digested sludge. This was caused by the dilution effect leading to a reduction in the hydrodynamic and non-hydrodynamic interactions when dilute digested sludge was added. Correlations were developed to predict the apparent viscosity and yield stress of the mixtures as a function of the digested sludge volume fraction and total solids concentration of the mixtures. The parameters of correlations can be estimated using pH of sludge. The shear and complex modulus were also modelled and they followed an exponential relationship with increasing digested sludge volume fraction.

Mixing characteristics of sludge simulant in a model anaerobic digester

This study aims to investigate the mixing characteristics of a transparent sludge simulant in a mechanically agitated model digester using flow visualisation technique. Video images of the flow patterns were obtained by recording the progress of an acid–base reaction and analysed to determine the active and inactive volumes as a function of time. The doughnut-shaped inactive region formed above and below the impeller in low concentration simulant decreases in size with time and disappears finally. The ‘cavern’ shaped active mixing region formed around the impeller in simulant solutions with higher concentrations increases with increasing agitation time and reaches a steady state equilibrium size, which is a function of specific power input. These results indicate that the active volume is jointly determined by simulant rheology and specific power input. A mathematical correlation is proposed to estimate the active volume as a function of simulant concentration in terms of yield Reynolds number.

Mechanical and thermal properties of melt processed PLA/organoclay nanocomposites

Polylactic acid (PLA) and organically modified layered silicates (organoclay) with concentrations of 2-10 wt% were prepared by melt intercalation technique. The effects of organoclay on the mechanical and thermal properties of PLA were studied. Tensile properties were evaluated using an Instron Universal Tester. Modulated differential scanning calorimetry (MDSC) and Thermogravimetric analyses (TGA) were performed to study the thermal behaviour of the prepared composites. The nanocomposites exhibited superior improvement of practical materials properties such as Youngs modulus and thermal stability, as compared to the neat PLA. The Youngs modulus drastically increased, whereas tensile strength and elongation at break decreased. The maximum degradation temperature of the hybrid increased linearly with an increasing amount of organoclay. However, MDSC has determined that the glass transition, cold crystallisation, and melting point temperatures were not significantly influenced by the presence of organoclay.

Control of the mixing time in vessels agitated by submerged recirculating jets

Submerged recirculating jet mixing systems are an efficient and economical method of agitating large tanks with a high hydraulic residence time. Much work has been carried out in developing design correlations to aid the predictions of the mixing time in such systems, with the first such correlation being developed nearly 70 years ago. In most of these correlations, the mixing time depends directly on the volume of the vessel and inversely on the injection velocity of the submerged jet. This work demonstrates, for the first time, that the distance between the injection and suction nozzles also significantly affects the mixing time and can be used to control this time scale. The study introduces a non-dimensional quantity that can be used as an adjustable parameter in systems where such control is desired.

Influences of novel microwave drying on dissolution of new formulated naproxen sodium

Drying of a pharmaceutical composition is an important step during its processing, which can affect its quality attributes including its texture, dispersion of the drug within the formulation, drug dissolution kinetics and eventually the drugs efficacy. This study presents the influence of varying drying techniques on the textural properties of the wet granulated formulation consisting of the drug naproxen sodium (NapSod) during the drying process. A new pharmaceutical formulation consisting of the NapSod drug was prepared by wet granulation and dried by novel microwave drying (MW), freeze drying (FD), vacuum drying (VD), and convective drying (CD) techniques before being processed in the form of tablets. The dissolution rate of NapSod from the tablet was measured in gastric (pH = 1.3) and intestinal fluid (pH = 6.8) mediums. The drug release was found to be influenced by the specific surface area, size distribution and the crystalline structure of dried particles, which were found to vary with the type of drying technique used as confirmed by the results of XRD, FTIR, SEM and particle size analyses. This study shows that using microwave technique to dry pharmaceutical granules containing a polar drug, such as NapSod, is an efficient and economical process, which can maintain the drug release at an appropriate rate to realize its desired pharmaceutical effect.

Quantitative investigation of hydraulic mixing energy input during batch mode anaerobic digestion and its impact on performance

The relationship between mixing energy input and biogas production was investigated by anaerobically digesting sewage sludge in lab scale, hydraulically mixed, batch mode digesters at six different specific energy inputs. The goal was to identify how mixing energy influenced digestion performance at quantitative levels to help explain the varying results in other published works. The results showed that digester homogeneity was largely uninfluenced by energy input, whereas cumulative biogas production and solids destruction were. With similar solids distributions between conditions, the observed differences were attributed to shear forces disrupting substrate-microbe flocs rather than the formation of temperature and/or concentration gradients. Disruption of the substrate-microbe flocs produced less favourable conditions for hydrolytic bacteria, resulting in less production of biomass and more biogas. Overall, this hypothesis explains the current body of research including the inhibitory conditions reported at extreme mixing power inputs. However, further work is required to definitively prove it.

Mass Transfer Study of Newtonian Fluids with Different Viscosity under Low-Frequency, High-Power Ultrasound Irradiation

In this article, the effects of liquid properties and operating conditions on gas–liquid mass transfer under ultrasound irradiation and mechanical stirring were studied and compared. Response surface methodology (RSM) was utilized for the design of experiments and evaluation of the influence of operating parameters. The maximum value of volumetric mass transfer coefficient (kLa) was found to be 0.0714 s−1 when the ultrasonic horn was located horizontally just above the gas sparger in the tank. Ultrasonic power and the position of ultrasonic horn were found to be the most significant parameters that influence kLa. Also, three empirical correlations were developed to estimate kLa considering liquid viscosity as one of the main parameters, and their estimations were compared to those estimated using existing correlations in the literature.