Ramon Aravena

Role of the riparian zone in controlling the distribution and fate of agricultural nitrogen near a small stream in southern Ontario

Abstract Uncultivated riparian areas can play an important role in reducing nutrient loading to streams in agricultural watersheds. Groundwater flow and geochemistry were monitored in the riparian zone of a small agricultural watershed in southern Ontario. Hydraulic and geochemical measurements were taken along a transect of monitoring wells extending across the riparian area into an agricultural field. Chloride and nitrate concentrations in groundwater samples collected from the agricultural field were much higher than in samples from the riparian area. A sharp decline in both nitrate and chloride concentrations was observed near the field–riparian zone boundary. It appears that increased recharge within the riparian zone, as compared to the artificially drained field, caused nitrate-rich groundwater from the field to be diverted downward beneath the riparian zone, thus limiting the input of agrochemicals to the riparian area and consequently protecting the stream from potential contamination. Geochemical data also indicated that nitrate was attenuated in the downward moving groundwater. Patterns of dissolved oxygen concentrations and redox potential in the subsurface coincided with the pattern defined by groundwater nitrate. These patterns indicated that conditions within the riparian zone and at depth near the field–riparian zone boundary were conducive to denitrification. A linear relation between the δ 15 N and δ 18 O values of nitrate from the monitored transect also supported denitrification as the primary nitrate removal mechanism. This study provides a new conceptual model of how riparian zones may prevent nitrate contamination of streams, and highlights the need for a complete understanding of both groundwater flow and geochemistry in riparian environments.

Artificial neural network modeling of water table depth fluctuations

Three types of functionally different artificial neural network (ANN) models are calibrated using a relatively short length of groundwater level records and related hydrometeorological data to simulate water table fluctuations in the Gondo aquifer, Burkina Faso. Input delay neural network (IDNN) with static memory structure and globally recurrent neural network (RNN) with inherent dynamical memory are proposed for monthly water table fluctuations modeling. The simulation performance of the IDNN and the RNN models is compared with results obtained from two variants of radial basis function (RBF) networks, namely, a generalized RBF model (GRBF) and a probabilistic neural network (PNN). Overall, simulation results suggest that the RNN is the most efficient of the ANN models tested for a calibration period as short as 7 years. The results of the IDNN and the PNN are almost equivalent despite their basically different learning procedures. The GRBF performs very poorly as compared to the other models. Furthermore, the study shows that RNN may offer a robust framework for improving water supply planning in semiarid areas where aquifer information is not available. This study has significant implications for groundwater management in areas with inadequate groundwater monitoring network.

Export of DOC from forested catchments on the Precambrian Shield of Central Ontario: Clues from 13C and 14C

Export of dissolved organic carbon (DOC) from forested catchmentsis governed by competing processes of production, decomposition, sorptionand flushing. To examine the sources of DOC, carbon isotopes (14Cand 13C) were analyzed in DOC from surface waters, groundwatersand soils in a small forested catchment on the Canadian Shield in centralOntario. A significant fraction (greater than 50%) of DOCin major inflows to the lake is composed of carbon incorporated into organicmatter, solubilized and flushed into the stream within the last 40 years. Incontrast, 14C in groundwater DOC was old indicating extensiverecycling of forest floor derived organic carbon in the soil column beforeelution to groundwater in the lower B and C soil horizons. A small uplandbasin had a wide range in 14C from old groundwater values atbaseflow under dry basin conditions to relatively modern values during highflow or wetter antecedent conditions. Wetlands export mainly recently fixedcarbon with little seasonal range. DOC in streams entering the small lakemay be composed of two pools; an older recalcitrant pool delivered bygroundwater and a young labile pool derived from recent organic matter.The relative proportion of these two pools changes seasonally due thechanges in the water flowpaths and organic carbon dynamics. Althoughchanges in local climate (temperature and/or precipitation) may alterthe relative proportions of the old and young pools, the older pool islikely to be more refractory to sedimentation and decomposition in thelake setting. Delivery of older pool DOC from the catchment andsusceptibility of this older pool to photochemical decomposition mayconsequently be important in governing the minimum DOC concentrationlimit in lakes.

Precambrian Shield Wetlands: Hydrologic Control of the Sources and Export of Dissolved Organic Matter

Most Precambrian Shield forested catchments have some wetland component. Even small riparian wetlands are important modifiers of stream chemistry. Dissolved organic matter (DOM) is one of the most important products exported by wetlands in streams. Stratigraphic control of hydraulic conductivity generally leads to decreasing conductivity with depth. Thus important flowpaths occur in the uppermost organic rich layers and are reflected in chemical profiles of dissolved organic carbon (DOC). Accumulation of DOC in peat porewaters is the net effect of production, consumption and transport. DOC profiles vary with degree of interaction with the surrounding upland catchment and distance from the edge of the wetland as well as internal processes within the wetland. In wetlands, DOM production is offset by flushing resulting in decreasing DOC concentrations with increasing flows. Despite old carbon (2,000 to 3,000 years) at relatively shallow depths, 14C activity in DOC exported from wetlands is mostly modern (recent carbon), consistent with shallow flowpaths and export of DOM from shallow organic rich horizons. In contrast, the source area for DOM in upland catchments with developed B horizon soils increases with antecedent soil moisture conditions resulting in increasing DOC concentrations with higher stream flows. Activity of 14C in stream DOC from upland catchments span a range from low activities (older carbon) similar to B horizon soil water during dry moisture conditions to values slightly less than modern (more recent carbon) during high moisture conditions. The more modern carbon activities reflect the increased contribution of the organic rich litter and A horizon soil layers in the area immediately bordering the stream under wet antecedent moisture conditions. Reduced hydrologic export or loss of wetlands under drier climatic conditions may result in in larger fluctuations in stream DOC concentrations and reduced DOM loads to lakes.

Radiocarbon dating of total soil organic matter and humin fraction and its comparison with 14C ages of fossil charcoal

During the last decade radiocarbon dating has been used extensively in distinct regions of Brazil to provide information about soil chronology in paleoenvironmental studies. This paper presents (super 14) C dating of soil organic matter (SOM), humin fraction, and charcoal in several soil profiles under natural vegetation from different Brazil locations (north, central, and southeast regions). The main objective is to compare the obtained (super 14) C dating of total SOM with humin, the oldest fraction of SOM. In order to validate the humin ages these data are compared with the age of charcoal collected at similar depths. The (super 14) C ages obtained on charcoal were, in most of the cases, in agreement with the humin fraction considering the experimental errors, or 20% older in average. The dates obtained from total SOM showed significantly younger ages than the humin fraction indicating contamination by younger carbon. These results show the humin fraction is considered a reliable material for (super 14) C dating in soils. However, the humin fraction ages could be assumed as the minimum ages for carbon in soils.

Holocene paleohydrology and glacial history of the central Andes using multiproxy lake sediment studies

Here we document at century to millennial scale the regional changes of precipitation^evaporation from the late Pleistocene to present with multiproxy methods on a north^south transect of lake sites across the eastern cordillera of the central Andes. The transect of study sites covers the area from V14‡S to 20‡S and includes core studies from seven lakes and modern calibration water samples from twenty-three watersheds analyzed to constrain the down-core interpretations of stable isotopes and diatoms. We selected lakes in different hydrologic settings spanning a range of sensitivity to changes in the moisture balance. These include: (1) lakes directly receiving glacial meltwater, (2) overflowing lakes in glaciated watersheds, (3) overflowing lakes in watersheds without active glaciers, and (4) lakes that become closed basins during the dry season. The results of our current work on multiple lakes in the Bolivian Andes show that while the overall pattern of Holocene environmental change is consistent within the region, conditions were not always stable over centennial to over millennial timescales and considerable decadal- to centuryscale climate variability is evident [Abbott et al., Quat. Res. 47 (1997) 70^80, Quat. Res. 47 (1997) 169^180, Quat. Sci. Rev. 19 (2000) 1801^1820; Polissar, Master’s thesis, University of Massachusetts (1999)]. Comparison of the paleoclimate record from one well-studied site, Lago Taypi Chaka Kkota (LTCK), with others within the region illustrates a consistent overall pattern of aridity from the late glacial through the middle Holocene. Previous work noted a difference between the timing of water-level rise in Lake Titicaca V5.0^3.5 ka B.P. [Abbott et al., Quat. Res. 47 (1997) 169^180; Cross et al., Holocene 10 (2000) 21^32; Rowe et al., Clim. Change 52 (2002) 175^199] and the onset of wetter conditions at 2.3 ka B.P. in LTCK, a lake that drains into the southern end of Lake Titicaca [Abbott et al., Quat. Res. 47 (1997) 70^80]. Sedimentary and oxygen isotope evidence from Paco Cocha (13‡54PS) located in the northern reaches of the expansive 57 000 km 2 Titicaca watershed, which spans V14‡S to 17‡S, indicates that

Nitrate Isotopes in Groundwater Systems

Nitrate contamination, often associated with agricultural activities, is a major problem in some shallow aquifers and is increasingly becoming a threat to groundwater supplies (Gillham and Cherry, 1978; Ronen et al., 1983; Spalding and Exner, 1991). The intake of high levels of nitrate can cause methemoglobinemia in infants, and there is substantial evidence collected from animal experiments that N-nitroso compounds are carcinogens. Similar conclusive evidence is not yet available for humans but many observations suggest that these compounds can function as initiators of human carcinogenesis. These findings are the basis for the maximum permissible limit of 10 ppm nitrate-N (50 ppm as NO3) in drinking water set by the World Health Organization and the U.S. Environmental Protection Agency. The impact of high loading of nutrients such as nitrate and phosphorous from agricultural practices via groundwater into surface water is also a major environmental concern, causing eutrophication of streams, rivers and lakes (Hill, 1978; Bohlke and Denver, 1995).

Stable chlorine and carbon isotope measurements of selected chlorinated organic solvents

Abstract Stable Cl and C isotope ratio results for 3 selected chlorinated solvents, perchloroethylene (PCE), trichloroethylene (TCE) and 1,1,1-trichloroethane (TCA) provided by 4 different manufacturers are presented. The isotope ratio for all compounds range between −3.5 and +6.0‰ for δ 37 Cl and from −37.2 to −23.3%. for δ 13 C . The greatest 37 Cl difference between manufacturers is observed in the TCE samples which show δ 37 CI values of −2.5%o for PPG, +2.43‰ for ICI and +4.4‰ for DOW. TCAs show a smaller range (−2.4 to +2.0‰), while the TCEs have slightly different 37 Cl contents. The 13 C data show the most distinct δ 13 C values for PCEs (−23.3 for DOW, −24.1 for Vulcan, −33.8 for PPG and −37.2‰ for ICI) while both TCEs and TCAs show a smaller δ 13 C range, but still distinct differences. These preliminary data suggest that each manufacturer and solvent type may have distinctive δ 637 Cl and δ 13 C values. These results show that by using a combination of 37 Cl and 13 C, there is a potential to indicate a specific source of chlorinated solvents, as well as an ability to delineate contamination episodes caused by these compounds in groundwaters.

Bofedales: high altitude peatlands of the central Andes

Existe un grupo excepcional de turberas (bofedales) de alta montana en el mundo situados en la estepa arida de los Andes centrales. Los bofedales en el norte de Chile estan presentes en la parte mas arida de su rango. Las principales especies de plantas responsables de la formacion de turba corresponden a miembros de Juncaceae. El agua fresca y medianamente salina de los bofedales proviene de agua subterranea asociada a riachuelos proveniente de glaciares, derretimiento de nieve y lluvia. Investigaciones paleoecologicas sugieren que algunos bofedales son integrantes recientes del paisaje, habiendose desarrollado durante los ultimos tres mil anos o menos. Estos bofedales son entidades unicas, extremadamente fragiles por su dependencia del agua, sensibles a los cambios climaticos y vulnerables a la alteracion humana tal como la actividad minera en la region. Se requiere mucho mas trabajo para desarrollar programas de manejo y conservacion, con solidas bases cientificas, de las plantas y animales que viven en ellos, y para asegurar la capacidad futura de pastoreo de la cual dependen los pueblos indigenas

The carbon isotope record in soils along a forest-cerrado ecosystem transect: implications for vegetation changes in the Rondonia state, southwestern Brazilian Amazon region

This paper presents carbon isotope data on soil organic matter (SOM) collected along an ecosystem transect that includes a wooded savannah (cerrado), a tropical semideciduous forest (cerradão), a forest tran sition type and a tropical forest. The study area is located in the Rondonia state, southwestern Brazilian Amazon region. 14C data of total soil organic matter and charcoal indicate that the organic matter in these soils is at least Holocene in age. The forest and forest transition sites are characterized by δ13C soil depth profiles gener ated typically by C3 plants, indicating no major changes in plant communities have occurred in this region during the time period represented by the isotope data. In contrast, the cerrado and cerradão have experienced significant vegetation changes during the Holocene. The d13C data (-30‰ to -27‰) obtained in the deepest part of the profile at the cerradão site show the expansion of the C3 forest vegetation into this region during early Holocene. A vegetation change consisting of increased C4 plant influence is reflected in the 13C-enriched 13C record shows a clear expansion of C3 vegetation, particularly at the cerradão site. The regression/expansion of the forest and savannah vegetation documented at the cerradão and cerrado sites is probably related to changes from a humid to a drier climate and a return to more humid conditions and is in agreement with palaeoclimatic information reported for Brazil and the Bolivian Altiplano. This study suggests that large areas in the Amazon basin have been affected by vegetation changes during the Holocene and that soil organic matter in the transition areas between savannah and forest ecotones contains a valuable palaeorecord of vegetation changes in the Ama zon region.