Raonei Alves Campos

CVD Diamond Films Growth on Silicon Nitride Inserts (Si3N4) with High Nucleation Density by Functionalization Seeding

Silicon Nitride is largely used as the base material to manufacture cutting tools. Due to its low thermal expansion coefficient it is ideal candidate for CVD diamond deposition. In this work, we functionalized the surface of silicon nitride inserts (Si3N4) with a polymer (PDDA Poly (diallyldimethylamonium chloride - Mw 40000)) to promote seeding with nanodiamond particles. The seeding was performed in water slurry containing 4 nm diamond particles dispersed by PSS Poly (sodium4-styrenesulfonate) polymer. CVD diamond films, with high nucleation density, were deposited in a hot filament reactor. Film morphology was characterized by Atomic Force Microscopy (AFM) and Scanning Electron Microscopy (SEM). Diamond film quality was determined by Raman Spectroscopy. CVD diamond film adherence was evaluated using Rockwell C indentation.

Nano- and microcrystalline diamond deposition on pretreated WC–Co substrates: structural properties and adhesion

Many developments have been made to improve the quality and adherence of CVD diamond films onto WC–Co hard metal tools by the removing the cobalt from the substrate surface through substrate pretreatments. Here we compare the efficiency of three chemical pretreatments of WC–Co substrates for this purpose. First, the work was focused on a detailed study of the composition and structure of as-polished and pretreated substrate surfaces to characterize the effects of the substrate preparation. Considering this objective, a set of WC–9% Co substrates, before and after pretreatment, was analyzed by FEG-SEM, EDS and x-ray diffraction (XRD). The second stage of the work was devoted to the evaluation of the influence of seeding process, using 4 nm diamond nanoparticles, on the morphology and roughness of the pretreated substrates. The last and most important stage was to deposit diamond coatings with different crystallite sizes (nano and micro) by hot-filament CVD to understand fully the mechanism of growth and adhesion of CVD diamond films on pretreated WC–Co substrates. The transition from nano to microcrystalline diamond was achieved by controlling the CH4/H2 gas ratio. The nano and microcrystalline samples were grown under same time at different substrate temperatures 600 °C and 800 °C, respectively. The different substrate temperatures allowed the analysis of the cobalt diffusion from the bulk to the substrate surface during CVD film growth. Furthermore, it was possible to evaluate how the coating adhesion is affected by the diffusion. The diamond coatings were characterized by Raman spectroscopy, XRD, EDS, FEG-SEM, atomic force microscope and 1500 N Rockwell indentation to evaluate the adhesion.

WC-Co substrate preparation and deposition conditions for high adhesion of CVD diamond coating

Different substrate surface pretreatments have been used to improve the adhesion of CVD diamond coatings on WC-Co substrates. In this paper, we report the results of our experiments using a pretreatment method based on two-step chemical etching: one in Murakami solution and another in aqua regia. A systematic study was performed to evaluate the influence of the pretreatment on the composition and morphology of the WC-Co substrate. Furthermore, the effect of diamond nanoparticle seeding on the morphology and roughness of the substrate was also analyzed. After these studies, diamond coating was deposited on seeded WC-Co substrate by hot-filament CVD. The characterization of the CVD diamond coating was performed by Raman spectroscopy, FEG-SEM and AFM. Rockwell C indentation test was used to evaluate the adhesion between the CVD diamond coating and the WC-Co substrate.

Effect of Heat Treatment on Microstructure and Mechanical Property of Diamonds Substrates Brazed with Active Filler Metal

This study aims to identify the effects caused by diffusion through heat treatment in diamonds, brazed components with metals and its effects on mechanical properties and microstructure. It will be used diamond films produced by CVD process, brazed by active filler metals with metallic substrate, using a high vacuum furnace at MAT / LNLS / CNPEM; the samples were heat treated in the atmosphere furnace at MAT too. The characterizations are carried out by hardness testing, vacuum sealing equipment at the MAT / LNLS / CNPEM facilities, and chemical and microstructural characterization will be performed using the scanning electron microscopes and EDS at LNNano / CNPEM.