Raquel Gracia

Polymers with redox properties: materials for batteries, biosensors and more

This minireview highlights the recent advances in the chemistry, characterization and applications of polymers with redox properties. The development of new redox polymers is clearly dominated by the interest in the area of batteries and biosensors. However, new applications in energy, materials science and biomedical fields have emerged together with the development of new polymeric materials. Historical works in the areas of ferrocene containing polymers and polyaniline conducting polymers have evolved today in a high number of innovative macromolecular structures whose singular properties indicate a bright future. The goal of this manuscript is to illustrate the state-of-the art in the development of polymers with redox properties and to highlight the most popular applications.

From Polymer Latexes to Multifunctional Liquid Marbles

A simple method to prepare multifunctional liquid marbles and dry water with magnetic, color, and fluorescent properties is presented. Multifunctional liquid marbles were prepared by encapsulation of water droplets using flocculated polymer latexes. First, the emulsion polymerization reaction of polystyrene and poly(benzyl methacrylate) was carried out using cheap and commercially available cationic surfactants. Subsequently, flocculation of the latex was provoked by an anion-exchange reaction of the cationic surfactant by the addition of lithium bis(trifluoromethanesulfonyl)imide salt. The flocculated polymer latex was filtered and dried, leading to very hydrophobic micronanoparticulated powders. These powders showed a great ability to stabilize the air/water interface. Stable liquid marbles were obtained by rolling water droplets onto the hydrophobic powders previously prepared. The use of very small polystyrene nanoparticles led us to the preparation of very stable and the biggest known liquid marbles up to 2.5 mL of water. Furthermore, the introduction of fluorescent comonomer dyes into the polymer powders allowed us to obtain new morphological images and new knowledge about the structure of liquid marbles by confocal microscopy. Furthermore, the introduction of magnetic nanoparticles into the polymer latex led to magnetic responsive liquid marbles, where the iron oxide nanoparticles are protected within a polymer. Altogether this method represents an accessible and general platform for the preparation of multifunctional liquid marbles and dry water, which may contribute to extending of their actual range of applications.

Synthesis and functionalization of dextran-based single-chain nanoparticles in aqueous media

Water-dispersible dextran-based single-chain polymer nanoparticles (SCPNs) were prepared in aqueous media and under mild conditions. Radiolabeling of the resulting biocompatible materials allowed the study of lung deposition of aqueous aerosols after intratracheal nebulization by means of single-photon emission computed tomography (SPECT), demonstrating their potential use as imaging contrast agents.