Rémi Champallier

Microstructures and rheology of hydrous synthetic magmatic suspensions deformed in torsion at high pressure

The relationship between magma rheology and characteristic magmatic microstructures was investigated by performing high-temperature high-pressure deformation experiments on hydrous synthetic magmatic suspensions in the range of 0% to 76% solid fraction (alumina grains). Torsion experiments were conducted at 300 MPa confining pressure, temperatures ranging from 475°C to 1000°C and shear strain rates ranging from 2.0 × 10 −5 to 2.1 × 10 −3 s −1 up to total strains of 21.3. Flow is Newtonian for a solid fraction of s = 0.0–0.16 with a log dynamic viscosity η = 10.3 Pa s (T = 500°C). A deviation from Newtonian behavior is observed for s > 0.16 with an increase in apparent viscosity of about 1 order of magnitude between s = 0.16 and 0.54. The shape fabric of the solid phase is characterized by a unimodal orientation that is almost stable and nearly parallel to the shear direction. Both shape fabric and deviation from Newtonian behavior originate from the increase in the number of particle clusters in the suspension. The apparent viscosity increases by 1.5 orders of magnitude between s = 0.54 and 0.65, and extrapolation of the data suggests a very sharp increase in apparent viscosity for s ≥ 0.65. At T ≥ 550°C and s = 0.54 the solid phase forms an almost entirely connected network composed of two alternating orientation domains. At T ≤ 550°C and s = 0.65, intragranular fracturing and tensile fractures result from high local stresses at contact points between neighboring particles. The resulting bulk extensional fabric is almost parallel to the shortening direction.

Porosity redistribution enhanced by strain localization in crystal-rich magmas

Magma degassing, characterized by changes in permeability and porosity distribution, has a crucial control on the style of eruption. During ascent, magma might develop large porosities and crystallize while it is subjected to shear. Shear, in turn, enhances complex fabrics that result from the reorganization of the different phases (crystals, gas, melt). Such fabrics have not yet been evaluated experimentally on a three-phase system. We performed torsion experiments on a synthetic crystal-rich hydrous magma at subsolidus conditions with 11 vol% porosity to establish a link between strain partitioning and porosity redistribution. Crystals induce non-Newtonian deformation, resulting in localization of the shear strain. Three-dimensional microtomography and two-dimensional scanning electron microscope imaging show gas accumulation in local microstructures caused by shear-induced crystal fabric. Our data show that strain localization is a mechanism that could enable magma degassing at very low vesicularity.

On the conditions of magma mixing and its bearing on andesite production in the crust.

Mixing between magmas is thought to affect a variety of processes, from the growth of continental crust to the triggering of volcanic eruptions, but its thermophysical viability remains unclear. Here, by using high-pressure mixing experiments and thermal calculations, we show that hybridization during single-intrusive events requires injection of high proportions of the replenishing magma during short periods, producing magmas with 55-58 wt% SiO2 when the mafic end-member is basaltic. High strain rates and gas-rich conditions may produce more felsic hybrids. The incremental growth of crustal reservoirs limits the production of hybrids to the waning stage of pluton assembly and to small portions of it. Large-scale mixing appears to be more efficient at lower crustal conditions, but requires higher proportions of mafic melt, producing more mafic hybrids than in shallow reservoirs. Altogether, our results show that hybrid arc magmas correspond to periods of enhanced magma production at depth.

Rheology and microstructure of experimentally deformed plagioclase suspensions

We present the result of the first deformation experiments at high-temperatures and high-pressures on synthetic magmatic suspensions of strongly anisometric particles. The results highlight the interplay between the rheological response and the development of microstructures and they demonstrate the critical importance of the shape of crystals on the mechanical behaviour of magmas. Plagioclase suspensions with two crystal fractions (0.38 and 0.52) were deformed both in compression and in torsion in a Paterson apparatus. With increasing crystal fraction, the rheological behaviour of the magmatic suspension evolves from nearly steady-state flow to shear weakening, this change being correlated with a microstructural evolution from a pervasive strain to a strain partitioning fabric. Magmatic suspensions of plagioclase have viscosities approximately five orders of magnitude higher than suspensions of equivalent crystallinities made of isometric particles such as quartz.

Experimental constrains on shear‐induced crystal breakage in magmas

Crystal breakage occurs along margins of conduit walls and basal zones of lava flows. It is usually interpreted as flow-related textures developed at large finite strains and strains rates. We have investigated the grain size and shape distributions in an experimentally deformed crystal-melt suspension in order to constrain the temperature T, the strain γ and the strain rate γr ranges of the crystal breakage process. The starting crystal-melt suspension is composed of a haplogranitic melt with 54 vol% alumina crystals. Torsion experiments were performed in a gas medium Paterson apparatus at 300 MPa confining pressure and subsolidus temperatures. Crystal size distribution and aspect ratio of alumina grains were measured on polished sections normal to the shear direction, i.e. from the centre to the rim of the deformed cylinders. A first minor occurrence of crystal breakage is evidenced in all experiments and low strains. It is related to intense stress localisation at some grain contacts in the initially connected solid framework. A second intense and penetrative crystal breakage process is observed for T≤ 550°C and γr > 6.2x10-4 s- 1. The evolution of the size distribution as a function of finite strain and the reduced aspect ratios of preserved largest crystals in intensely strained zones support that breakage occurs by abrasion of the larger crystals. This abrasion can be attributed to the partial stress propagation over both the melt and partially isolated crystals under visco-elastic conditions. Mechanical data show a transition from slight shear softening at low strain rates and highest temperatures to strain hardening for experiments that produced penetrative crystal breakage. The crystal-melt suspension exhibits a shear thinning behaviour with a stress exponent larger than 2.06 over the explored strain rate and temperature domain for the experiments without intensive crystal breakage. Our results are applicable to the interpretation of the crystal breakage often observed at the base of lava flows, in domes, and near conduit walls. This experimental reproduction of a process observed in nature is important because the controls of stress-induced breakage we quantified are also key parameters governing magma transport.

Integration of Fe in natural and synthetic Al-pyrophyllites: an infrared spectroscopic study

Abstract Numerous studies focus on the relationships between chemical composition and OH-band positions in the infrared (IR) spectra of micaceous minerals. These studies are based on the coexistence, in dioctahedral micas or smectites, of several cationic pairs around the hydroxyl group which each produce a characteristic band in the IR spectrum. The aim of this work is to obtain the wavenumber values of the IR OH vibration bands of the (Al-Fe3+)-OH and (Fe3+-Fe3+)-OH local cationic environments of ‘pyrophyllite type’ in order to prove, disprove or modify a model of dioctahedral phyllosilicate OH-stretching band decomposition. Natural samples are characterized by powder X-ray diffraction (XRD), Fourier transform infrared (FTIR) and Raman spectroscopies and electron microprobe; the hydrothermal synthesis products are also analysed by powder XRD and FTIR after inductively coupled plasma measurements to obtain the chemical compositions of starting gel phases. Natural samples contain some impurities which were eliminated after acid treatment; nevertheless, a small Fe content is found in the pyrophyllite structure. The amount of Fe which is incorporated within the pyrophyllite structure is much more important for the synthetic samples than for the natural ones. The IR OH bands were clearly observed in both natural and synthetic pyrophyllites and assigned to hydroxides bonded to (Al-Al), (Al-Fe) and (Fe-Fe) cationic pairs. During this study, three samples were analysed by DTG to check the cis- or trans-vacant character of the layers and to determine the influence of this structural character on the OH-stretching band position in IR spectroscopy.

HYDROTHERMAL SYNTHESIS OF BEIDELLITES: CHARACTERIZATION AND STUDY OF THE CIS- AND TRANS-VACANT CHARACTER

Low-charge beidellites were synthesized by a hydrothermal treatment applied to an amorphous gel phase in basic solution. The hydrothermal conditions for the syntheses were chosen from the stability field of beidellite previously investigated in the literature. The synthetic samples were characterized chemically and structurally using X-ray diffraction, infrared spectroscopy, cation exchange capacity measurement, and chemical and thermal analyses. We compared the synthetic sample with a natural beidellite sample (SbId) from Idaho, USA, looking at chemical composition and particle size. The main difference is the octahedral site occupancy (cis- or trans-vacant layer structure). The natural SbId sample has trans-vacant layers and the synthetic sample has a preferentially cis-vacant character. This character can be modulated, using specific synthesis conditions. The cis- or drafts-vacant layer structure of various synthetic beidellites was investigated at low temperature (<350°C) and pressure (<25 MPa). Depending on the pressure and/or synthesis temperature, the proportion of cis-vacant layers ranges from 20 to 100% and increases with the layer-charge deficit.

Chemical transfer during redox exchanges between H2 and Fe-bearing silicate melts

Abstract Kinetics and reaction paths of Fe3+ reduction by H2 in high-Fe and low-H2O silicate melts have been investigated at 800 ℃. Time-series experiments were performed in cold-seal pressure vessels at 50 bars of pure H2 using rapid-heating and rapid-quench strategies. Within the first minutes of the experiments, a fast partitioning of Na occurred between the gas and the melt due to the reducing conditions. Kinetically decoupled from the Na partitioning, the progression of a front of Fe3+ reduction within the quenched melt was observed and was identified as a diffusion-limited process. The growth of the reduced layer is accompanied by an increase in concentration of OH-groups suggesting that reduction operates through proton incorporation within the melt. As this growth rate is slightly faster than predicted from the diffusion of molecular H2O, a different and mobile waterderived species seems likely. One possible mechanism is the reduction of Fe3+ by the transport of molecular H2. As this process is limited by the flux of H2, it will depend on both diffusivity and solubility of H2 in the melt. Alternatively, migration of protons (H+) and electronic species within the melt could control the velocity of the reduction front. The increase in concentration of the reactionderived OH groups produces a water over saturation followed by partial dehydration of the melt. This dehydration leads to a change in the redox conditions within the gas that influences the Na partitioning between gas and melt.

Permeability Evolution in Variably Glassy Basaltic Andesites Measured Under Magmatic Conditions

Heat from inflowing magma may act to seal permeable networks that assist passive outgassing at volcanic conduit margins and in overlying domes, reducing the efficiency of overpressure dissipation. Here we present a study of the evolution of permeability – measured under magmatic conditions - with increasing temperature in glassy and glass-poor basaltic andesites from Merapi volcano (Indonesia). Whereas the permeability of glass-poor rocks decreases little up to a temperature of 1010°C, glassy specimens experience a pronounced decrease in permeability above the glass transition once the viscosity of the crystal suspension is low enough to relax under external stresses. Changes in temperature alone are thus not enough to significantly modify the permeability of the glass-poor rocks that commonly form Merapis dome. However, the presence of glass-rich domains in a dome may lead to local sealing of the volcanic plumbing between eruptions, exacerbating localized overpressure development that could contribute to explosivity.

Mechanical properties and processes of deformation in shallow sedimentary rocks from subduction zones: An experimental study

To better constrain the mechanical behavior of sediments accreted to accretionary prism, we conducted triaxial mechanical tests on natural samples from the Miura-Boso paleo-accretionary prism (Japan) in drained conditions with confining pressures up to 200 MPa as well as postexperiments P-wave velocity (Vp) measurements. During experiments, deformation is principally noncoaxial and accommodated by two successive modes of deformation, both associated with strain-hardening and velocity-strengthening behavior: (1) compaction-assisted shearing, distributed in a several mm-wide shear zone and (2) faulting, localized within a few tens of μm-wide, dilatant fault zone. Deformation is also associated with (1) a decrease in Youngs modulus all over the tests, (2) anomalously low Vp in the deformed samples compared to their porosity and (3) an increase in sensitivity of Vp to effective pressure. We interpret this evolution of the poroelastic properties of the material as reflecting the progressive breakage of intergrain cement and the formation of microcracks along with macroscopic deformation. When applied to natural conditions, these results suggest that the deformation style (localized versus distributed) of shallow (z < a few km) sediments is mainly controlled by the variations in stress/strain rate during the seismic cycle and is therefore independent of the porosity of sediments. Finally, we show that the effect of strain, through cement breakage and microcracks formation, may lower Vp for effective pressure up to 40 MPa. As a consequence, the low Vp anomalies observed in Nankai accretionary prisms by seismic imaging between 2 and 4 km depth could reflect sediment deformation rather than porosity anomalies.