Richard M. Friedman

High‐precision isotopic characterization of USGS reference materials by TIMS and MC‐ICP‐MS

The Pacific Centre for Isotopic and Geochemical Research (PCIGR) at the University of British Columbia has undertaken a systematic analysis of the isotopic (Sr, Nd, and Pb) compositions and concentrations of a broad compositional range of U.S. Geological Survey (USGS) reference materials, including basalt (BCR-1, 2; BHVO-1, 2), andesite (AGV-1, 2), rhyolite (RGM-1, 2), syenite (STM-1, 2), granodiorite (GSP-2), and granite (G-2, 3). USGS rock reference materials are geochemically well characterized, but there is neither a systematic methodology nor a database for radiogenic isotopic compositions, even for the widely used BCR-1. This investigation represents the first comprehensive, systematic analysis of the isotopic composition and concentration of USGS reference materials and provides an important database for the isotopic community. In addition, the range of equipment at the PCIGR, including a Nu Instruments Plasma MC-ICP-MS, a Thermo Finnigan Triton TIMS, and a Thermo Finnigan Element2 HR-ICP-MS, permits an assessment and comparison of the precision and accuracy of isotopic analyses determined by both the TIMS and MC-ICP-MS methods (e.g., Nd isotopic compositions). For each of the reference materials, 5 to 10 complete replicate analyses provide coherent isotopic results, all with external precision below 30 ppm (2 SD) for Sr and Nd isotopic compositions (27 and 24 ppm for TIMS and MC-ICP-MS, respectively). Our results also show that the first- and second-generation USGS reference materials have homogeneous Sr and Nd isotopic compositions. Nd isotopic compositions by MC-ICP-MS and TIMS agree to within 15 ppm for all reference materials. Interlaboratory MC-ICP-MS comparisons show excellent agreement for Pb isotopic compositions; however, the reproducibility is not as good as for Sr and Nd. A careful, sequential leaching experiment of three first- and second-generation reference materials (BCR, BHVO, AGV) indicates that the heterogeneity in Pb isotopic compositions, and concentrations, could be directly related to contamination by the steel (mortar/pestle) used to process the materials. Contamination also accounts for the high concentrations of certain other trace elements (e.g., Li, Mo, Cd, Sn, Sb, W) in various USGS reference materials.

U-Th-Pb geochronology of the Coast Mountains batholith in north-coastal British Columbia: Constraints on age and tectonic evolution

Previously published and new U-Pb geochronologic analyses provide 313 zircon and 59 titanite ages that constrain the igneous and cooling history of the Coast Mountains batholith in north-coastal British Columbia. First-order findings are as follows: (1) This segment of the batholith consists of three portions: a western magmatic belt (emplaced into the outboard Alexander and Wrangellia terranes) that was active 177–162 Ma, 157–142 Ma, and 118–100 Ma; an eastern belt (emplaced into the inboard Stikine and Yukon-Tanana terranes) that was active ca. 180–110 Ma; and a 100–50 Ma belt that was emplaced across much of the orogen during and following mid-Cretaceous juxtaposition of outboard and inboard terranes. (2) Magmatism migrated eastward from 120 to 80 (or 60) Ma at a rate of 2.0–2.7 km/Ma, a rate similar to that recorded by the Sierra Nevada batholith. (3) Magmatic flux was quite variable through time, with high (>35–50 km 3 /Ma per km strike length) flux at 160–140 Ma, 120–78 Ma, and 55–48 Ma, and magmatic lulls at 140–120 Ma and 78–55 Ma. (4) High U/Th values record widespread growth (and/or recrystallization) of metamorphic zircon at 88–76 Ma and 62–52 Ma. (5) U-Pb ages of titanite record rapid cooling of axial portions of the batholith at ca. 55–48 Ma in response to east-side-down motion on regional extensional structures. (6) The magmatic history of this portion of the Coast Mountains batholith is consistent with a tectonic model involving formation of a Late Jurassic–earliest Cretaceous magmatic arc along the northern Cordilleran margin; duplication of this arc system in Early Cretaceous time by >800 km (perhaps 1000–1200 km) of sinistral motion (bringing the northern portion outboard of the southern portion); high-flux magmatism prior to and during orthogonal mid-Cretaceous terrane accretion; low-flux magmatism during Late Cretaceous–Paleocene dextral transpressional motion; and high-flux Eocene magmatism during rapid exhumation in a regime of regional crustal extension.

Cenozoic to Recent plate configurations in the Pacific Basin: Ridge subduction and slab window magmatism in western North America

Forearc magmatic rocks were emplaced in a semicontinuous belt from Alaska to Oregon from 62 to 11 Ma. U-Pb and 40 Ar39 Ar dating indicates that the magmatism was concurrent in widely separated areas. Eight new conventional isotope dilution–thermal ionization mass spectrometry (ID-TIMS) U-Pb zircon ages from forearc intrusions on Vancouver Island (51.2 ± 0.4, 48.8 ± 0.5 Ma, 38.6 ± 0.1, 38.6 ± 0.2, 37.4 ± 0.2, 36.9 ± 0.2, 35.4 ± 0.2, and 35.3 ± 0.3 Ma), together with previous dates, indicate that southwestern British Columbia was a particularly active part of the forearc. The forearc magmatic belt has been largely attributed to ridge-trench intersection and slab window formation involving subduction of the Kula-Farallon ridge. Integration of the new and previous ages reveals shortcomings of the Kula-Farallon ridge explanation, and supports the hypothesis of two additional plates, the Resurrection plate (recently proposed) and the Eshamy plate (introduced herein) in the Pacifi c basin during Paleocene and Eocene time. We present a quantitative geometric plate-tectonic model that was constructed from 53 Ma to present to best account for the forearc magmatic record using ridge-trench intersection and slab window formation as the main causes of magmatism. The model is also in accord with Tertiary to present inboard magmatic and structural features.

Timing the end-Triassic mass extinction: First on land, then in the sea?

The end-Triassic marks one of the five biggest mass extinctions, but current geologic time scales are inadequate for understanding its dynamics. A tuff layer in marine sedimentary rocks encompassing the Triassic-Jurassic transition yielded a U-Pb zircon age of 199.6 ± 0.3 Ma. The dated level is immediately below a prominent change in radiolarian faunas and the last occurrence of conodonts. Additional recently obtained U-Pb ages integrated with ammonoid biochronology confirm that the Triassic Period ended ca. 200 Ma, several million years later than suggested by previous time scales. Published dating of continental sections suggests that the extinction peak of terrestrial plants and vertebrates occurred before 200.6 Ma. The end-Triassic biotic crisis on land therefore appears to have preceded that in the sea by at least several hundred thousand years.

Archean zircons in Cretaceous strata of the western Canadian Cordillera: The “Baja B.C.” hypothesis fails a “crucial test”

The magnitude of late Mesozoic terrane translation along the western North American continental margin is controversial. Paleomagnetic data suggest more than 3000 km of dextral displacement of the Insular superterrane and associated assemblages between ca. 74 and 50 Ma. Conversely, geologic evidence is more compatible with less than 500 km of offset during this time. Precambrian cratonic rocks older than 2.5 Ga are restricted to northern latitudes (above 40°N) in North America, and the presence or absence of Archean zircons within easterly derived Cretaceous strata has been proposed as a “crucial test” of the major translation hypothesis. There is no plausible source of Archean and Early Proterozoic zircons found in the Queen Charlotte, Nanaimo, and Methow basins other than the Canadian Shield or closely associated Proterozoic strata. The coexistence of Archean–Early Proterozoic, Middle Proterozoic (1.5–1.6 Ga) and Mississippian detrital zircon in these basins indicates deposition in northern latitudes, incompatible with the Baja B.C. hypothesis.

Geologic history of Siletzia, a large igneous province in the Oregon and Washington Coast Range: Correlation to the geomagnetic polarity time scale and implications for a long-lived Yellowstone hotspot

Siletzia is a basaltic Paleocene and Eocene large igneous province in coastal Oregon, Washington, and southern Vancouver Island that was accreted to North America in the early Eocene. New U-Pb magmatic, detrital zircon, and 40Ar/39Ar ages constrained by detailed field mapping, global nannoplankton zones, and magnetic polarities allow correlation of the volcanics with the 2012 geologic time scale. The data show that Siletzia was rapidly erupted 56–49 Ma, during the Chron 25–22 plate reorganization in the northeast Pacific basin. Accretion was completed between 51 and 49 Ma in Oregon, based on CP11 (CP—Coccolith Paleogene zone) coccoliths in strata overlying onlapping continental sediments. Magmatism continued in the northern Oregon Coast Range until ca. 46 Ma with the emplacement of a regional sill complex during or shortly after accretion. Isotopic signatures similar to early Columbia River basalts, the great crustal thickness of Siletzia in Oregon, rapid eruption, and timing of accretion are consistent with offshore formation as an oceanic plateau. Approximately 8 m.y. after accretion, margin parallel extension of the forearc, emplacement of regional dike swarms, and renewed magmatism of the Tillamook episode peaked at 41.6 Ma (CP zone 14a; Chron 19r). We examine the origin of Siletzia and consider the possible role of a long-lived Yellowstone hotspot using the reconstruction in GPlates, an open source plate model. In most hotspot reference frames, the Yellowstone hotspot (YHS) is on or near an inferred northeast-striking Kula-Farallon and/or Resurrection-Farallon ridge between 60 and 50 Ma. In this configuration, the YHS could have provided a 56–49 Ma source on the Farallon plate for Siletzia, which accreted to North America by 50 Ma. A sister plateau, the Eocene basalt basement of the Yakutat terrane, now in Alaska, formed contemporaneously on the adjacent Kula (or Resurrection) plate and accreted to coastal British Columbia at about the same time. Following accretion of Siletzia, the leading edge of North America overrode the YHS ca. 42 Ma. The voluminous high-Ti basaltic to alkalic magmatism of the 42–35 Ma Tillamook episode and extension in the forearc may be related to the encounter with an active YHS. Clockwise rotation of western Oregon about a pole in the backarc has since moved the Tillamook center and underlying Siletzia northward ∼250 km from the probable hotspot track on North America. In the reference frames we examined, the YHS arrives in the backarc ∼5 m.y. too early to match the 17 Ma magmatic flare-up commonly attributed to the YHS. We suggest that interaction with the subducting slab may have delayed arrival of the plume beneath the backarc.

Evidence for protracted High Arctic large igneous province magmatism in the central Sverdrup Basin from stratigraphy, geochronology, and paleodepths of saucer-shaped sills

Field evidence, map compilation, geochemistry, geochronology, and potential field data document six intervals of Cretaceous magmatism in the central Sverdrup Basin. These are: (1) Hauterivian (ca. 130 Ma) volcaniclastic deposition in the lower Isachsen Formation; (2) 126.6 ± 1.2 Ma (U-Pb zircon) gabbroic intrusion; (3) 120.8 ± 0.8 Ma (U-Pb baddeleyite) diabasic intrusion; (4) 105.40 ± 0.22 Ma (U-Pb detrital zircon) pyroclastic deposition at the top of the Invincible Point Member, Christopher Formation; (5) upper Albian (ca. 103 Ma) pillow and hydroclastic breccia in the upper Christopher Formation; and (6) uppermost Albian (ca. 101 Ma) volcanic breccia and scoria in the Hassel Formation. Whole-rock geochemical data show that these magmatic rocks are similar to previously documented High Arctic large igneous province tholeiitic basalts, but analyses of fresh glass in tuffs reveal evolved ferroandesite to dacite compositions not recorded in whole-rock data. Approximate ages of saucer-shaped sills inferred from the relationship of sill width to depth of emplacement suggest at least three intervals of sill emplacement between 130 and 120 Ma. The new data show that volcanism in the Sverdrup Basin was of greater spatial extent, and that magmatism occurred more frequently, than was previously recognized. Comparison of the new central Sverdrup Basin data and interpretations with other data sets from the Sverdrup Basin, Svalbard, and Franz Josef Land suggests that High Arctic large igneous province magmatism occurred over a more extended period of time in the central Sverdrup Basin than in other regions.

Coherent French Range blueschist: Subduction to exhumation in <2.5 m.y.?

Coherent oceanic strata in the French Range belong to the exotic Cache Creek terrane of the Canadian Cordillera. They were metamorphosed to blueschist grade, tectonically extruded, eroded, and intruded by plutons—perhaps in <2.5 m.y. Sodic amphibole overprint chert as young as late Pliensbachian to Toarcian age (ca. 191 to ca. 177 Ma). Blueschist mineral assemblages defi ne the early metamorphic fabric along with phengite dated by 40 Ar/ 39 Ar as 173.7

In situ location and U‐Pb dating of small zircon grains in igneous rocks using laser ablation–inductively coupled plasma–quadrupole mass spectrometry

A new U‐Pb zircon dating protocol for small (10–50 mm) zircons has been developed using an automated searching method to locate zircon grains in a polished rock mount. The scanning electron microscopeenergy‐ dispersive X ray spectrum‐based automated searching method can routinely find in situ zircon grains larger than 5 mm across. A selection of these grains was ablated using a 10 mm laser spot and analyzed in an inductively coupled plasma‐quadrupole mass spectrometer (ICP‐QMS). The technique has lower precision (∼6% uncertainty at 95% confidence on individual spot analyses) than typical laser ablation ICP‐MS (∼2%), secondary ion mass spectrometry (<1%), and isotope dilution‐thermal ionization mass spectrometry (∼0.4%) methods. However, it is accurate and has been used successfully on fine‐grained lithologies, including mafic rocks from island arcs, ocean basins, and ophiolites, which have traditionally been considered devoid of dateable zircons. This technique is particularly well suited for medium‐ to fine‐grained mafic volcanic rocks where zircon separation is challenging and can also be used to date rocks where only small amounts of sample are available (clasts, xenoliths, dredge rocks). The most significant problem with dating small in situ zircon grains is Pb loss. In our study, many of the small zircons analyzed have high U contents, and the isotopic compositions of these grains are consistent with Pb loss resulting from internal a radiation damage. This problem is not significant in very young rocks and can be minimized in older rocks by avoiding high‐ U zircon grains.

INTEGRATED AMMONITE BIOCHRONOLOGY AND U-PB GEOCHRONOMETRY FROM A BASAL JURASSIC SECTION IN ALASKA

New results from integrated biochronologic and geochronometric studies on the basal Jurassic section at Puale Bay (Alaska Peninsula) improve the calibration of the Early Jurassic time scale. Previously, the interval around the Triassic-Jurassic system boundary was poorly dated, which hampered our understanding of geologic and biotic events, e.g., the end-Triassic mass extinction and subsequent recovery. Published suggestions for the presence of the earliest Hettangian (Planorbis Zone) and a continuous boundary section at Puale Bay are not substantiated. Although the Kamishak Formation is likely to contain an uninterrupted sedimentary record, pre‐middle Hettangian strata are locally faulted, resulting in an apparent Rhaetian to early Hettangian gap in the fossil record. The Hettangian ammonite zonal schemes developed locally for Nevada and the Queen Charlotte Islands permit reliable correlation with Alaska, but have limited applicability. The faunal succession recorded at Puale Bay is useful in the development of a regional zonation for North America. We obtained three U-Pb zircon dates that are tied into an ammonite biochronology at the zonal level. A middle Hettangian tuff layer from near the top of the Kamishak Formation is dated at 200.8 +2.7 / ‐2.8 Ma. Tuffs from the overlying Talkeetna Formation are bracketed by middle and late Hettangian ammonites and yield crystallization ages of 197.8 +1.2 / ‐0.4 and 197.8 ± 1.0 Ma. These new calibration points require that the Hettangian-Sinemurian boundary be younger than 199 Ma. The Triassic-Jurassic boundary is likely to fall between 200 and 205 Ma. Similar studies are needed for the uppermost Triassic to obtain tighter constraints. Zircon U-Pb systematics of two samples revealed strong Proterozoic and late Archean inheritance patterns that require revised tectonic models to account for the proximity of the Talkeetna arc to evolved crustal blocks.