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Richard V. C. Carr

University of Chicago

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Featured researches published by Richard V. C. Carr.

Chemical Physics Letters | 1976

Photochemistry and photophysics of 1,4-dewarnaphthalene

Richard V. C. Carr; Bongsub Kim; Jeffrey K. McVey; N. C. Yang; Wolfgang Gerhartz; Josef Michl

Abstract Photoexcited 1,4-dewarnaphthalene (1) rearranges in high efficiency to excited naphthalene in both the singlet and the triplet manifold. Assuming the relative efficiencies of fluorescence to intersystem crossing of 1 are similar to those of substituted benzenes, the rearrangement of triplet 1 to triplet naphthalene may be adiabatic. The relative efficiencies of fluorescence to rearrangement to singlet excited naphthalene from singlet excited 1 at 77 K depends on the wavelength of exciting light, the shorter the wavelength, the more efficient the rearrangement.

Journal of Organic Chemistry | 1983

Dienophilic properties of phenyl vinyl sulfone and trans-1-(phenylsulfonyl)-2-(trimethylsilyl)ethylene. Their utilization as synthons for ethylene, 1-alkenes, acetylene, and monosubstituted alkynes in the construction of functionalized six-membered rings via [4 + 2] .pi. cycloaddition methodology

Richard V. C. Carr; Richard Vaughan Williams; Leo A. Paquette

Journal of the American Chemical Society | 1980

An ethylene and terminal olefin equivalent in [4 + 2] .pi. cycloadditions. General synthetic application of phenyl vinyl sulfone to the construction of functionalized six-membered rings

Richard V. C. Carr; Leo A. Paquette

Journal of the American Chemical Society | 1980

Electronic control of stereoselectivity. 3. Stereoselection operative in [4 + 2].pi. cycloadditions to cyclopentadiene rings fused at C2,C3 to bicyclic frameworks

Leo A. Paquette; Richard V. C. Carr; Michael C. Boehm; Rolf Gleiter

Journal of the American Chemical Society | 1980

Reaction of singlet oxygen with .alpha.,.beta.-unsaturated ketones and lactones

Harry E. Ensley; Richard V. C. Carr; Robert S. Martin; Tillman E. Pierce

Journal of Organic Chemistry | 1980

Electronic control of stereoselectivity. 7. Stereospecificity of N-methyltriazolinedione cycloaddition to tricyclo[5.2.1.02,6]deca-2,5-diene, tricyclo[5.2.1.02,6]deca-2,5,8-triene, and tricyclo[5.2.2.02,6]undeca-2,5,8-triene

Leo A. Paquette; Richard V. C. Carr; Pana Charumilind; John F. Blount

Journal of the American Chemical Society | 1974

2,3-Naphtho-2,5-bicyclo[2.2.0]hexadiene

N. C. Yang; Richard V. C. Carr; Ellen Li; Jeffrey K. McVey; Stuart A. Rice

Journal of Organic Chemistry | 1980

Electronic control of stereoselectivity. 5. Stereochemistry of singlet oxygen capture by cyclopentadiene rings fused to norbornyl and norbornenyl frameworks

Leo A. Paquette; Richard V. C. Carr; Edward Arnold; Jon Clardy

Journal of the American Chemical Society | 1980

Response of syn-1,2,3,4,5,6,7,8-octahydro-1,4:5,8-dimethanonaphthalene and related molecules to oxidation with ozone, singlet oxygen, and triplet oxygen. Strain and steric effects as controllers of reactivity

Leo A. Paquette; Richard V. C. Carr

Journal of Organic Chemistry | 1982

[1,5]-Hydrogen sigmatropy within isodicyclopentadiene. Cycloadditive capture of a fleeting isomer with dienophiles of low reactivity

Leo A. Paquette; Richard Vaughan Williams; Richard V. C. Carr; Pana Charumilind; John F. Blount

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Leo A. Paquette

Ohio State University

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N. C. Yang

University of Chicago

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Richard Vaughan Williams

University of Idaho

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Jeffrey K. McVey

University of Chicago

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John F. Blount

Princeton University

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Pana Charumilind

Ohio State University

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Edward Arnold

Cornell University

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Jon Clardy

Harvard University

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Rolf Gleiter

Heidelberg University

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Stuart A. Rice

University of Chicago

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