Rima J. Isaifan

Critical Review on Nanofluids

Heat transfer fluids are a crucial parameter that affects the size and costs of heat exchangers. However, the available coolants like water and oils have low thermal conductivities, which put many limitations to the development of heat transfer to achieve high performance cooling. The need for development of new classes of fluids which enhance the heat transfer capabilities attracted the attention of many researchers. In the last few decades, modern nanotechnology developed nanoparticles, which have unique thermal and electrical properties that could help improve heat transfer using nanofluids. A “nanofluid” is a fluid with suspended fine nanoparticles which increases the heat transfer properties compared with the original fluid. Nanofluids are considered a new generation of heat transfer fluids and are considered two-phase fluids of liquid solid mixtures. The efficiency of the fluid could be improved by enhancing its thermal properties, especially the thermal conductivity, and it is expected that the nanofluids will have a greater thermal conductivity than the base fluids. This paper reviews the preparation of metallic and nonmetallic nanofluids along with the stability of the produced nanofluids. Physical and thermal properties as well as a range of applications are also discussed in detail.

Improved Self-cleaning Properties of an Efficient and Easy to Scale up TiO 2 Thin Films Prepared by Adsorptive Self-Assembly

Transparent titania coatings have self-cleaning and anti-reflection properties (AR) that are of great importance to minimize soiling effect on photovoltaic modules. In this work, TiO2 nanocolloids prepared by polyol reduction method were successfully used as coating thin films onto borosilicate glass substrates via adsorptive self-assembly process. The nanocolloids were characterized by transmission electron microscopy and x-ray diffraction. The average particle size was around 2.6 nm. The films which have an average thickness of 76.2 nm and refractive index of 1.51 showed distinctive anti soiling properties under desert environment. The film surface topography, uniformity, wettability, thickness and refractive index were characterized using x-ray diffraction, atomic force microscopy, scanning electron microscopy, water contact angle measurements and ellipsometry. The self-cleaning properties were investigated by optical microscopy and UV-Vis spectroscopy. The optical images show 56% reduction of dust deposition rate over the coated surfaces compared with bare glass substrates after 7 days of soiling. The transmission optical spectra of these films collected at normal incidence angle show high anti-reflection properties with the coated substrates having transmission loss of less than 6% compared to bare clean glass.

Synthesis of CuNi/C and CuNi/-Al2O3 Catalysts for the Reverse Water Gas Shift Reaction

A new polyol synthesis method is described in which CuNi nanoparticles of different Cu/Ni atomic ratios were supported on both carbon and gamma-alumina and compared with Pt catalysts using the reverse water gas shift, RWGS, reaction. All catalysts were highly selective for CO formation. The concentration of CH4 was less than the detection limit. Cu was the most abundant metal on the CuNi alloy surfaces, as determined by X-ray photoelectron spectroscopy, XPS, measurements. Only one CuNi alloy catalyst, Cu50Ni50/C, appeared to be as thermally stable as the Pt/C catalysts. After three temperature cycles, from 400 to 700°C, the CO yield at 700°C obtained using the Cu50Ni50/C catalyst was comparable to that obtained using a Pt/C catalyst.

Graphene nanoplatelets doping of P3HT:PCBM photoactive layer of bulk heterojunction organic solar cells for enhancing performance

Hybrid organic photovoltaic (OPV) cells based on conjugated polymers photoactive materials are promising candidates for flexible, high-performance and low-cost energy sources owing to their inexpensive materials, cost-effective processing, and ease of fabrication by simple solution processes. However, the modest PV performance obtained to date -in particular the low power conversion efficiency (PCE)- has impeded the large scale deployment of OPV cells. The low PCE in OPV solar cells has been mainly attributed to low carrier mobility, which is closely correlated to the transport diffusion length of the charge carriers within the photoactive layers. The 2D graphene material can be an excellent candidate for assisting the charge transport improvement in the active layer of OPV cells due to its huge carrier mobility, thermal and chemical stability, and its compatibility with the solution process. In this work, we report on the improvement of optoelectronic properties and photovoltaic performance of graphene nanoplatelets (GNP) doped P3HT:PCBM photoactive blended layers, integrated into a bulk heterojunction (BHJ) organic photovoltaic based device, using PEDOT:PSS on ITO/glass substrate. First, the light absorption capacity was observed to increase with respect to the GNP contents while the photoluminescence showed a clear quenching, indicating electrons transfer between the graphene sheets and the polymeric matrix. Then, the incorporation of GNP into the BHJ active layer has resulted in enhanced PV performance with respect to a reference cell, and the best PV performances were obtained with 3 wt. % of GNP loading, with an open-circuit voltage of 1.24 V, a short-circuit current density value of 6.18 mA/cm2, a fill factor of 47.12 %, and a power conversion efficiency of about 3.61 %. We believe that the obtained results contribute to the development of organic photovoltaic devices and to the understanding of the impact of sp2-bonded carbon therein.Hybrid organic photovoltaic (OPV) cells based on conjugated polymer photoactive materials are promising candidates for flexible, high-performance and low-cost energy sources owing to their inexpensive materials, cost-effective processing and ease of fabrication by simple solution processes. However, the modest PV performance obtained to date-in particular the low power conversion efficiency (PCE)-has impeded the large scale deployment of OPV cells. The low PCE in OPV solar cells is mainly attributed to the low carrier mobility, which is closely correlated to the transport diffusion length of the charge carriers within the photoactive layers. The 2D graphene material could be an excellent candidate for assisting charge transport improvement in the active layer of OPV cells, due to its huge carrier mobility, thermal and chemical stability, and its compatibility with the solution process. In this work, we report on the improvement of the optoelectronic properties and photovoltaic performance of graphene nanoplatelet (GNP)-doped P3HT:PCBM photoactive blended layers, integrated into a bulk heterojunction (BHJ) organic-photovoltaic-based device, using PEDOT:PSS on an ITO/glass substrate. First, the light absorption capacity was observed to increase with respect to the GNP content, while the photoluminescence showed clear quenching, indicating electron transfer between the graphene sheets and the polymeric matrix. Then, the incorporation of GNP into the BHJ active layer resulted in enhanced PV performance with respect to the reference cell, and the best PV performance was obtained with 3 wt.% of GNP loading, with an open-circuit voltage of 1.24 V, a short-circuit current density value of 6.18 mA cm-2, a fill factor of 47.12%, and a power conversion efficiency of about 3.61%. We believe that the obtained results contribute to the development of organic photovoltaic devices and to the understanding of the impact of sp2-bonded carbon therein.

A review on the direct effect of particulate atmospheric pollution on materials and its mitigation for sustainable cities and societies

Particulate matter (PM) has gained significant attention due to the increasing concerns related to their effects on human health. Although several reviews have shed light on the effect of PM on human health, their critical adverse effect on material’s structure and sustainability was almost neglected. The current study is an attempt to fill this gap related to PM impact on structural materials under the overall consideration of sustainability. More specifically, this review highlights the existing knowledge by providing an overview on PM classification, composition, and sources in different locations around the world. Then, it focuses on PM soiling of surfaces such as solar panels due to an increasing need to mitigate the impact of soiling on reducing photovoltaic (PV) power output and financial competitiveness in dusty regions. This topic is of critical importance for sustainable deployment of solar energy in arid and desert areas around the world to help in reducing their impact on overall climate change and life quality. In addition, this review summarizes climate change phenomena driven by the increase of PM concentration in air such as radiative forcing and acid rain deposition due to their impact on human health, visibility and biodiversity. To this end, this work highlights the role of process management, choice of fuel, the implementation of clean technologies and urban vegetation as some possible sustainable mitigation policies to control PM pollution in cities and urban regions. This research is designed to conduct a comprehensive narrative literature review which targets broad spectrum of readers and new researchers in the field. Moreover, it provides a critical analysis highlighting the need to fill main research gaps in this domain. The findings of this review paper show that PM pollution imposes severe adverse impacts on materials, structures and climate which directly affect the sustainability of urban cities. The advantages of this review include the value of the extensive works that elaborate on the negative impacts of PM atmospheric pollution towards high level of public awareness, management flexibility, stakeholder’s involvements, and collaboration between academy, research, and industry to mitigate PM impact on materials and human welfare.

Use of CuNi/YSZ and CuNi/SDC Catalysts for the Reverse Water Gas Shift Reaction

Cu50Ni50 nanoparticles were synthesized using a modified polyol method and deposited on samarium-doped ceria, SDC, and yttria-stabilized zirconia, YSZ, supports to form reverse water-gas shift, RWGS, catalysts. The best CO yields, obtained with the Cu50Ni50/SDC catalyst, were about 90% of the equilibrium CO yields. In contrast CO yields using Pt/SDC catalysts were equal to equilibrium CO yields at 700°C. Catalyst selectivity to CO was 100% at hydrogen partial pressures equal to CO2 partial pressures, 1 kPa, and decreased as methane was formed when the hydrogen partial pressure was 2 kPa or greater. The reaction results were explained using a combination of Eley-Rideal and Langmuir-Hinshelwood mechanisms that involved adsorption on the metal surface and the concentration of oxygen vacancies in the support. Finally the Cu50Ni50/SDC catalyst was found to be thermally stable for 48 hours at 600/700°C.