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Featured researches published by Robert E. Bachman.


Tetrahedron Letters | 1992

The thermal rearrangements of halocyclopropenes

W. E. Billups; Robert E. Bachman

Abstract The gas phase thermal chemistry of several halocyclopropenes has been investigated. In each instance the cyclopropene was converted cleanly to an allene. The gas phase thermolysis of halocyclopropenes leads to allenes.


Journal of Organometallic Chemistry | 1994

Molecular and crystal structure of [Et4N][Cl]·2[Fe2(CO)6Te2]

Robert E. Bachman; Kenton H. Whitmire

Abstract [Et4N]2[Fe2(CO)8] reacts with TeCl4 to yield Fe2(CO)6Te2. The product crystallizes in the space group Pca21 (no. 29) with two tetrahedral cluster molecules co-crystallized with one molecule of [Et4N]Cl per asymmetric unit. The presence of the chloride stabilizes the lattice and helps to create an intricate packing array through a variety of intermolecular contacts.


Inorganic Chemistry | 1993

Hypervalent bismuth alkoxide dimer complexes: syntheses, structures, and thermal decompositions of [Bi(OCH(CF3)2)2(.mu.-OCH(CF3)2)(THF)]2 and [Bi(OC6F5)2(.mu.-OC6F5)Xn]2.cntdot.zY (X = Y = C7H8, n = 1, z = 1 or 2; X = THF, Y = C6H14, n = 2, z = 0 or 1)

Carolyn M. Jones; Michael D. Burkart; Robert E. Bachman; Deborah L. Serra; Shiou-Jyh Hwu; Kenton H. Whitmire


Inorganic Chemistry | 1998

Metal-Ligand Bonding in Coinage Metal-Phosphine Complexes: The Synthesis and Structure of Some Low-Coordinate Silver(I)-Phosphine Complexes.

Robert E. Bachman; David F. Andretta


Inorganic Chemistry | 1994

The Synthesis and Characterization of a Series of Iron Carbonyl Clusters Containing Selenium and Tellurium

Robert E. Bachman; Kenton H. Whitmire


Organometallics | 1993

Reduction of tellurium by Na2[Fe(CO)4]: synthesis and reactivity of [PPN]2[Fe2(CO)6(Te2)2]

Robert E. Bachman; Kenton H. Whitmire


Inorganic Chemistry | 1995

SYNTHESIS AND STRUCTURE OF CARBONYL-METALATED ORGANOBISMUTH COMPLEXES

Robert E. Bachman; Kenton H. Whitmire


Inorganica Chimica Acta | 2003

Bismuth ladder polymers: structural and thermal studies of [Bi(OCH2CH2)3N]n and [(BixTb1−x(O2C2H2)3N·2H2O]n

Robert E. Bachman; Kenton H. Whitmire; John H. Thurston; Aurelian Gulea; Olexa Stavila; Vitalie Stavila


Inorganic Chemistry | 1996

Isolation and Structural Characterization of [P(AuPPh(3))(5)][BF(4)](2) via Cleavage of a P-P Bond by Cationic Gold Fragments: Direct Evidence of the Structure of the Elusive Tetrakis[phosphineaurio(I)]phosphonium(+) Cation.

Robert E. Bachman; Hubert Schmidbaur


Inorganic Chemistry | 1994

Synthesis and Structure of an Anionic Arsenic Hydride Complex: [PPN]2[HAs{Fe(CO)4}3].cntdot.0.5THF

Robert E. Bachman; Suzanne K. Miller; Kenton H. Whitmire

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