Robert Harald Brazzle

Verification and interpretation of the I-Xe chronometer

Abstract Comparisons of I-Xe and Pb-Pb relative ages are made for phosphate and feldspar separates from 12 different meteorites. In all cases where I-Xe ages can be measured in phosphate, I-Xe and Pb-Pb chronometers agree within experimental uncertainty. No discordant phosphate samples are observed. With the exception of Allegan, I-Xe ages for feldspar separates generally agree with Pb-Pb ages for the corresponding phosphate. The general concordancy observed between I-Xe and Pb-Pb chronometers suggests that the I-Xe system is a reliable and interpretable chronometer when applied to single minerals systems. Allegan feldspar differs from the other feldspar separates, predating its phosphate by ∼17 Ma, with an I-Xe age indistinguishable from those of Orgueil and Murchison magnetites, among the oldest observed.

The I-Xe chronometer

Abstract129Xe, from the decay of the now-extinct 16.7 Ma129I, accumulates in iodine-bearing sites and since most iodine host phases are secondary, the I-Xe system is typically a chronometer for post-formational processes. The validity of the I-Xe chronometer is confirmed by comparison with Pb-Pb ages on phosphate and feldspar separates from twelve meteorites. Phosphate separates are found to be concordant with Pb-Pb for all six samples in which useful I-Xe data were obtained. Feldspar is a better iodine host than apatite in H chondrites, typically providing good I-Xe isochrons. These too are concordant with the Pb-Pb ages of the corresponding phosphates for five out of six feldspar separates. The exception is Allegan whose feldspar yields one of the oldest I-Xe ages observed, similar to those for CI and CM magnetites. We attribute this to a more primary mineralization, predating the secondary phosphate from which the comparison Pb-Pb age was obtained. Absolute I-Xe ages, found using the reported Pb-Pb age of Acapulco phosphate provide an absolute I-Xe age of 4.566 ± 0.002 Ga for both Shallowater and Bjurböle irradiation standards. This allows relative I-Xe ages to be interpreted in the context of absolute ages.