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Dive into the research topics where Robert J. Rosenthal is active.

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Featured researches published by Robert J. Rosenthal.


Tetrahedron Letters | 1983

Dienophilic and dipolar additions to bicyclo[2.1.0]pent-2-ene

Waldemar Adam; Axel Beinhauer; O. De Lucchi; Robert J. Rosenthal

Abstract The dienophiles triazolinedione, singlet oxygen and in part tetracyanoethylene cyclo-add to bicyclo[2.1.0]pent-2-ene (1) across the central σ-bond to give bicyclo[2.2.1]heptene-type adducts, while the dipoles phenyl azide, benzonitrile oxide and diphenyldiazomethane cyclo-add at the π-bond with expected exo stereochemistry.


Tetrahedron Letters | 1983

Rearrangement in the 1,3′-bicyclopropenyl series

Albert Padwa; Mitchell Pulwer; Robert J. Rosenthal

Abstract The photochemical behavior of a representative 1,3′-bicyclopropene was studied and was found to undergo a novel rearrangement to a naphthalene derivative.


Journal of Organic Chemistry | 1984

Steady-state and laser photolysis studies of substituted 2H-azirines: spectroscopy, absolute rates, and arrhenius behavior for the reaction of nitrile ylides with electron deficient olefins

Albert Padwa; Robert J. Rosenthal; William Dent; Pedro Filho; Nicholas J. Turro; David A. Hrovat; Ian R. Gould


Journal of the American Chemical Society | 1987

On the question of 1,4-diradical intermediates in the di-.pi.-methane rearrangement of benzobicyclo[3.2.1]octadienes: azoalkanes as mechanistic probes

Waldemar Adam; Markus Dörr; Johanna Kron; Robert J. Rosenthal


Journal of Organic Chemistry | 1984

Synthesis and ring-opening reactions in the 1,3'-bicyclopropenyl series

Albert Padwa; Mitchell Pulwer; Robert J. Rosenthal


Chemische Berichte | 1984

Cycloaddition of singlet oxygen and 4-methyl-4H-1,2,4-triazole-3,5-dione to 7-adamantylidene-1,3,5-cycloheptatriene and derivatives

Waldemar Adam; Hector Rebollo; Robert J. Rosenthal; E.-M. Peters; Karl Peters; Hans Georg von Schnering


Journal of the American Chemical Society | 1981

Photochemistry of cyclopropene derivatives. 20. Deuterium isotope effects in the triplet-induced photochemistry of tetrasubstituted cyclopropenes

Albert Padwa; Chuen S. Chou; Robert J. Rosenthal; Byron Rubin


Angewandte Chemie | 1983

Kinetics of the Reaction of Electron Deficient Olefins with Nitrile Ylides Generated by Laser Flash Photolysis of Substituted Azirines

Nicholas J. Turro; David A. Hrovat; Ian R. Gould; Albert Padwa; William Dent; Robert J. Rosenthal


Journal of Organic Chemistry | 1987

Single-electron-transfer pathway in the coupling of cyclopropenyl cations with organometallic reagents

Albert Padwa; Steven Goldstein; Robert J. Rosenthal


Journal of the American Chemical Society | 1983

Synthesis of the benzotricyclo[3.2.0.02,7]heptene ring system via the intramolecular [2 + 2]-cycloaddition reaction of some cyclopropene derivatives

Albert Padwa; William F. Rieker; Robert J. Rosenthal

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David A. Hrovat

University of North Texas

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Ian R. Gould

Arizona State University

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