Robert M. Hough

Nanoparticle factories: Biofilms hold the key to gold dispersion and nugget formation

Biofilms living on gold (Au) grains play a key role in the biogeochemical cycle of Au by promoting the dispersion of Au via the formation of Au nanoparticles as well as the formation of secondary biomorphic Au. Gold grains from Queensland, Australia, are covered by a polymorphic, organic-inorganic layer that is up to 40 μm thick. It consists of a bacterial biofilm containing Au nanoparticles associated with extracellular polymeric substances as well as bacterioform Au. Focused ion beam (FIB) sectioning through the biofilm revealed that aggregates of nanoparticulate Au line open spaces beneath the active biofilm layer. These aggregates (bacterioform Au type 1) resulted from the reprecipitation of dissolved Au, and their internal growth structures provide direct evidence for coarsening of the Au grains. At the contact between the polymorphic layer and the primary Au, bacterioform Au type 2 is present. It consists of solid rounded forms into which crystal boundaries of underlying primary Au extend, and is the result of dealloying and Ag dissolution from the primary Au. This study demonstrates that (1) microbially driven dissolution, precipitation, and aggregation lead to the formation of bacterioform Au and contribute to the growth of Au grains under supergene conditions, and (2) the microbially driven mobilization of coarse Au into nanoparticles plays a key role in mediating the mobility of Au in surface environments, because the release of nanoparticulate Au upon biofilm disintegration greatly enhances environmental mobility compared to Au complexes only.

Naturally occurring gold nanoparticles and nanoplates

During the weathering of gold deposits, exceptionally pure, <200 nm diameter, nanoparticulate gold plates (6 nm thick) are formed. The particles display controlled growth of both size and shape and signs of assembly to form belts and sheets. The gold is associated and intergrown with minerals formed by evaporation and is interpreted to have been deposited rapidly from saline groundwater during a drying event. The size and morphology of the gold nanoparticles and nanoplates are identical to the products of experimentally manufactured gold colloids. This represents the fi rst direct observation of colloidal nanoparticulate gold in nature, confi rming this as an active mechanism of gold transport during the weathering of gold deposits.

An anomalous basaltic meteorite from the innermost main belt

The Meteorite Who Fell to Earth Orbital data is available for only a handful of meteorites. Some are found long after they fell to Earth. Others are recovered after they have been observed falling through the atmosphere, but their trajectories are rarely recorded. Bland et al. (p. 1525) used a photographic camera network located in the Australian desert to track a fireball in the sky, find the meteorite, and establish its orbit. The meteorite is a basaltic achondrite; most such rocks have been traced to the major asteroid Vesta. In this case, the meteorites isotopic composition and orbital properties suggest a distinct parent asteroid—a different source of basaltic material residing in the innermost main belt. This meteorite’s composition and orbital properties are such that it cannot be traced to the parent asteroid. Triangulated observations of fireballs allow us to determine orbits and fall positions for meteorites. The great majority of basaltic meteorites are derived from the asteroid 4 Vesta. We report on a recent fall that has orbital properties and an oxygen isotope composition that suggest a distinct parent body. Although its orbit was almost entirely contained within Earth’s orbit, modeling indicates that it originated from the innermost main belt. Because the meteorite parent body would likely be classified as a V-type asteroid, V-type precursors for basaltic meteorites unrelated to Vesta may reside in the inner main belt. This starting location is in agreement with predictions of a planetesimal evolution model that postulates the formation of differentiated asteroids in the terrestrial planet region, with surviving fragments concentrated in the innermost main belt.

The New Maia Detector System: Methods For High Definition Trace Element Imaging Of Natural Material

Motivated by the need for megapixel high definition trace element imaging to capture intricate detail in natural material, together with faster acquisition and improved counting statistics in elemental imaging, a large energy‐dispersive detector array called Maia has been developed by CSIRO and BNL for SXRF imaging on the XFM beamline at the Australian Synchrotron. A 96 detector prototype demonstrated the capacity of the system for real‐time deconvolution of complex spectral data using an embedded implementation of the Dynamic Analysis method and acquiring highly detailed images up to 77 M pixels spanning large areas of complex mineral sample sections.

Maia X-ray fluorescence imaging: Capturing detail in complex natural samples

Motivated by the challenge of capturing complex hierarchical chemical detail in natural material from a wide range of applications, the Maia detector array and integrated realtime processor have been developed to acquire X-ray fluorescence images using X-ray Fluorescence Microscopy (XFM). Maia has been deployed initially at the XFM beamline at the Australian Synchrotron and more recently, demonstrating improvements in energy resolution, at the P06 beamline at Petra III in Germany. Maia captures fine detail in element images beyond 100 M pixels. It combines a large solid-angle annular energy-dispersive 384 detector array, stage encoder and flux counter inputs and dedicated FPGA-based real-time event processor with embedded spectral deconvolution. This enables high definition imaging and enhanced trace element sensitivity to capture complex trace element textures and place them in a detailed spatial context. Maia hardware and software methods provide per pixel correction for dwell, beam flux variation, dead-time and pileup, as well as off-line parallel processing for enhanced throughput. Methods have been developed for real-time display of deconvoluted SXRF element images, depth mapping of rare particles and the acquisition of 3D datasets for fluorescence tomography and XANES imaging using a spectral deconvolution method that tracks beam energy variation.

Three-dimensional morphology of magmatic sulfides sheds light on ore formation and sulfide melt migration

The morphology of magmatic sulfides in igneous cumulates is controlled by the wetting properties of sulfide liquids against silicates. The formation of nickel sulfide ores, the behavior of sulfide liquids during mantle melting, and potentially the segregation of the Earth9s core, are all controlled by the ability of sulfide liquids to migrate through the pore space of partially molten silicates. Three-dimensional X-ray tomographic images of sulfide aggregates in komatiitic olivine cumulates indicate that sulfide liquids have a limited tendency to wet olivine crystals, forming interconnected networks only in the absence of silicate melt. Consequently, the ability of sulfide liquids to migrate through the pore space of olivine cumulates is limited. We conclude that disseminated sulfide ores in komatiites formed by accumulation of transported sulfide blebs a few millimeters in size, and not by settling of sulfide-olivine aggregates, and that sulfides accumulated in the proportions in which they are now found, rather than by percolation through cumulate pore space. It is unlikely that sulfide droplets can be entrained and carried from the mantle at low degrees of partial melting. Our results also support the hypothesis that segregation of the Earth9s core took place from a magma ocean, rather than by percolation of sulfidic melt through partially molten mantle.

Reduced As components in highly oxidized environments: Evidence from full spectral XANES imaging using the Maia massively parallel detector

Abstract Synchrotron X-ray fluorescence (SXRF) and X-ray absorption spectroscopy (XAS) have become standard tools to measure element concentration, distribution at micrometer- to nanometer-scale, and speciation (e.g., nature of host phase; oxidation state) in inhomogeneous geomaterials. The new Maia X-ray detector system provides a quantum leap for the method in terms of data acquisition rate. It is now possible to rapidly collect fully quantitative maps of the distribution of major and trace elements at micrometer spatial resolution over areas as large as 1 × 5 cm2. Fast data acquisition rates also open the way to X-ray absorption near-edge structure (XANES) imaging, in which spectroscopic information is available at each pixel in the map. These capabilities are critical for studying inhomogeneous Earth materials. Using a 96-element prototype Maia detector, we imaged thin sections of an oxidized pisolitic regolith (2 × 4.5 mm2 at 2.5 × 2.5 μm2 pixel size) and a metamorphosed, sedimentary exhalative Mn-Fe ore (3.3 × 4 mm2 at 1.25 × 5 μm2). In both cases, As K-edge XANES imaging reveals localized occurrence of reduced As in parts of these oxidized samples, which would have been difficult to recognize using traditional approaches.

Geochemistry of carbonaceous impactites from the Gardnos impact structure, Norway

Abstract The Gardnos impact structure in southern Norway is one of only two known impact structures (among ∼175) whose impactites contain significant amounts (typically 0.2–1.0 wt.%) of carbon, or 5 to 10 times the amount present in the target rocks; Sudbury, Canada is the other. This study extends a previous investigation of the geochemistry and petrology of Gardnos impactites (French et al., 1997) with additional sampling and a detailed investigation of the nature and possible origin of the carbonaceous material present. Two principal carbon components have been identified in Gardnos impactites: (1) impact-produced diamonds, 0.5 to 1 μm in size, with a cubic crystal structure, predominantly hexagonal morphologies with platey layers and an estimated concentration of Geochemical data suggests that there are no suitable target rocks that could provide a single source for the carbon in Gardnos impactites. However, Raman spectroscopy, stable isotope analysis and transmission electron microscopy of the impact diamonds and graphitic carbon suggests that there were at least two episodes of C emplacement in Gardnos impactites: an impact-related incorporation and shock transformation of graphitic material from target rocks followed by later mobilization of C, possibly during postimpact cooling or later regional metamorphism.

The Australian Desert Fireball Network: a new era for planetary science

Through an international collaboration between Imperial College London, the Ondřejov Observatory in the Czech Republic and the Western Australian Museum, the installation of the Australian Desert Fireball Network in the Nullarbor Region of Western Australia was completed in 2007. Currently, the Network, which is the first to be established in the southern hemisphere, comprises four all-sky autonomous observatories providing precise triangulation of fireball records to constrain pre-atmospheric orbits and fall positions of meteorites over an area of approximately 200 000 km2. To date, the Network has led to the successful recovery of two observed meteorite falls. The first recovery was three fragments (174, 150 and 14.9 g) of the same meteorite fall recorded on 20 July 2007 at 19 h 13 m 53.2 s±0.1 s UT that were found within 100 m of the predicted fall line. Named Bunburra Rockhole, the meteorite is a basaltic achondrite with an oxygen isotopic composition (Δ17O = −0.112 ‰) distinguishing it from basaltic meteorites belonging to the Howardite–Eucrite–Diogenite clan thought to be derived from asteroid 4Vesta, and therefore must have come from another differentiated asteroid in the terrestrial planet region. Bunburra Rockhole was delivered to Earth from an Aten-like orbit that was almost entirely contained within the Earths orbit. The second recovered fall was detected by the Network on 13 April 2010 and led to the recovery of a 24.54 g meteorite fragment that is yet to be fully described. To date, the Network has recorded ∼550 fireballs. Records from which precise orbits and trajectories can be determined number ∼150. In addition to the two recovered falls twelve fireballs are considered to have resulted in meteorite falls. Of these, four are probable falls (10s–100 g), and five are certain falls (>100 g). Having proved the potential of the Network, ultimately a large dataset of meteorites with orbits will provide the spatial context for the interpretation of meteorite composition that is currently lacking in planetary science.

Microstructural evolution and trace element mobility in Witwatersrand pyrite

Microstructural analysis of pyrite from a single sample of Witwatersrand conglomerate indicates a complex deformation history involving components of both plastic and brittle deformation. Internal deformation associated with dislocation creep is heterogeneously developed within grains, shows no systematic relationship to bulk rock strain or the location of grain boundaries and is interpreted to represent an episode of pyrite deformation that predates the incorporation of detrital pyrite grains into the Central Rand conglomerates. In contrast, brittle deformation, manifest by grain fragmentation that transects dislocation-related microstructures, is spatially related to grain contacts and is interpreted to represent post-depositional deformation of the Central Rand conglomerates. Analysis of the low-angle boundaries associated with the early dislocation creep phase of deformation indicates the operation of <010>{100} slip systems. However, some orientation boundaries have geometrical characteristics that are not consistent with simple <010>{100} deformation. These boundaries may represent the combination of multiple slip systems or the operation of the previously unrecognized <001>{120} slip system. These boundaries are associated with order of magnitude enrichments in As, Ni and Co that indicate a deformation control on the remobilization of trace elements within pyrite and a potential slip system control on the effectiveness of fast-diffusion pathways. The results confirm the importance of grain-scale elemental remobilization within pyrite prior to their incorporation into the Witwatersrand gold-bearing conglomerates. Since the relationship between gold and pyrite is intimately related to the trace element geochemistry of pyrite, the results have implications for the application of minor element geochemistry to ore deposit formation, suggest a reason for heterogeneous conductivity and localized gold precipitation in natural pyrite and provide a framework for improving mineral processing.