Robert Peticzka

A comparison of 14 soil phosphorus extraction methods applied to 50 agricultural soils from Central Europe

Phosphorus (P) fertilization is commonly based on soil testing, for which a variety of different soil P extraction methods are in use. The aim of this study was to compare 14 soil P extraction methods in terms of their extrac tion yield and their relation to soil properties. Fifty contrasting agricultural topsoils were sampled from Austria and Germany. The soils were extracted with the following methods/extractants: H 2 O, CaCl 2 , LiCl, Olsen, Bray and Kurtz II (Bray II), Mehlich 3, calcium-acetate-lactate (CAL), iron oxide impregnated filter papers (Fe-oxide P i ), cation and anion exchange membranes (CAEM), acid ammonium oxalate, citrate-bicarbonate-dithionite, HCl, organic P and total P. The extracted P varied over three orders of magnitude and increased in the order H 2 O < CaCl 2 < LiCl < Fe-oxide P i < Olsen < CAL < CAEM < Mehlich 3 < Bray II < dithionite < organic P < HCl < oxalate < total P. This sequence is in accordance with previous studies and reflects different extraction mechanisms and P pools. The different extraction methods were generally well correlated, especially when P extraction was achieved by a similar mechanism. The soil properties most influential on P extractability were pH, carbonate content, texture as well as iron oxide content and crystallinity. Our results show that the different extraction methods extract distinct pools of soil P with strongly varying extractability, and that the extractability of a given pool may be influenced by different soil properties to different extents. If and how these relationships translate to plant P uptake requires further ex amination.

Casting new light on the chronology of the loess/paleosol sequences in Lower Austria

This paper presents a review on recently dated sections in well-known loess/paleosol sequences of Lower Austria. The dating results indicate that there was loess deposition during the Upper Würmian Pleniglacial as recorded in the profile Joching. However, most obtained ages are older than the Last Glacial Maximum (LGM) and therefore erosional processes, which led to the removal of younger deposits can be supposed. Soil formation between ~28 ka and ~35 ka mainly resulted in the formation of Cryosols. Hence, in the studied profiles, there is no evidence for more intense interstadial pedogenesis during this time span. This might be of particular relevance to the stratigraphy of ‘Stillfried B’ (sensu Fink). The 2 age cluster lies between ~35 ka and ~57 ka i. e. the Middle Pleniglacial (Würmian) and is dominated by loess deposits intercalated with different Cryosols. This period is also characterized by colluvial processes. There is a significant hiatus between ~57 ka and ~106 ka, a fact which might be due to long lasting and intensive erosional processes in the study areas. The oldest measured age of the Last Glacial is 106 ± 12 ka for the loess on top of ‘Stillfried A’ in Paudorf (Paudorfer Bodenbildung). Immediately below this pedocomplex and equivalents to it, ages of 124 ± 25 ka (Göttweig-Aigen), 159 ± 20 ka (Paudorf 1), and 170 ± 16 ka (Joching) were obtained in loess. Furthermore, there is evidence for older Middle Pleistocene deposits in Stratzing, Paudorf 2, Göttweig-Furth and Langenlois. (Löss-/Paläoboden sequenzen in niederösterreich im Licht neuer chronologischer Ergebnisse) Kurzfassung: Der vorliegende Artikel gibt einen Überblick über neu datierte Abschnitte in bekannten Löss/Paläoboden-Sequenzen Niederösterreichs. Die Ergebnisse der Datierungen im Profil Joching deuten darauf hin, dass es im letzten Hochglazial zur Lösssedimentation kam. Die meisten erfassten Alter sind jedoch älter als das letzte Hochglazial, was auf Erosionsprozesse hindeutet, die zur Abtragung der jüngeren Lösse geführt hat. In dem Abschnitt zwischen ~28 ka and ~35 ka wurden überwiegend Tundragleye gebildet. Eine intensivere interstadiale Bodenbildung ist nicht nachzuweisen. Dieses Ergebnis kann auch für die stratigraphische Einstufung von ‚Stillfried B‘ (sensu Fink) von Bedeutung sein. Der folgende chronologische Abschnitt liegt zwischen ~35 ka and ~57 ka in Lösssedimenten mit eingeschalteten Tundragleyen. Auch dieser Abschnitt ist durch Umlagerungsprozesse charakterisiert. Im Zeitraum von ~57 ka bis ~106 ka befindet sich eine markante Zeitlücke, die vermutlich auf langandauernde und intensive Erosionsprozesse im Untersuchungsgebiet zurückzuführen ist. Die älteste Datierung in den Sedimenten des letzten Glazials mit 106 ± 12 ka befindet sich in Paudorf direkt über dem ‚Stillfried A‘Komplex (Paudorfer Bodenbildung). Direkt unter diesem Pedokomplex, bzw. vergleichbaren Pedokomplexen treten in Lössablagerungen Alter von 124 ± 2 5 ka (Göttweig-Aigen), 159 ± 20 ka (Paudorf 1), and 170 ± 16 ka (Joching) auf. Darüber hinausgehende Alter konnten in Stratzing, Paudorf 2, Göttweig-Furth und Langenlois nachgewiesen werden.

Impact of adjacent land use on coastal wetland sediments.

Coastal wetlands link terrestrial with marine ecosystems and are influenced from both land and sea. Therefore, they are ecotones with strong biogeochemical gradients. We analyzed sediment characteristics including macronutrients (C, N, P, K, Mg, Ca, S) and heavy metals (Mn, Fe, Cu, Zn, Al, Co, Cr, Ni) of two coastal wetlands dominated by Phragmites australis at the Darss-Zingst Bodden Chain, a lagoon system at the Southern Baltic Sea, to identify the impact of adjacent land use and to distinguish between influences from land or sea. In the wetland directly adjacent to cropland (study site Dabitz) heavy metal concentrations were significantly elevated. Fertilizer application led to heavy metal accumulation in the sediments of the adjacent wetland zones. In contrast, at the other study site (Michaelsdorf), where the hinterland has been used as pasture, heavy metal concentrations were low. While the amount of macronutrients was also influenced by vegetation characteristics (e.g. carbon) or water chemistry (e.g. sulfate), the accumulation of heavy metals is regarded as purely anthropogenic influence. A principal component analysis (PCA) based on the sediment data showed that the wetland fringes of the two study sites are not distinguishable, neither in their macronutrient status nor in their concentrations of heavy metals, whereas the interior zones exhibit large differences in terms of heavy metal concentrations. This suggests that seaside influences are minor compared to influences from land. Altogether, heavy metal concentrations were still below national precautionary and action values. However, if we regard the macronutrient and heavy metal concentrations in the wetland fringes as the natural background values, an accumulation of trace elements from agricultural production in the hinterland is apparent. Thus, coastal wetlands bordering croplands may function as effective pollutant buffers today, but the future development has to be monitored closely to avoid breakthroughs due to exceeded carrying capacities.

Quicklime application instantly increases soil aggregate stability

Abstract Agricultural intensification, especially enhanced mechanisation of soil management, can lead to the deterioration of soil structure and to compaction. A possible amelioration strategy is the application of (structural) lime. In this study, we tested the effect of two different liming materials, ie limestone (CaCO3) and quicklime (CaO), on soil aggregate stability in a 3-month greenhouse pot experiment with three agricultural soils. The liming materials were applied in the form of pulverised additives at a rate of 2 000 kg ha−1. Our results show a significant and instantaneous increase of stable aggregates after quicklime application whereas no effects were observed for limestone. Quicklime application seems to improve aggregate stability more efficiently in soils with high clay content and cation exchange capacity. In conclusion, quicklime application may be a feasible strategy for rapid improvement of aggregate stability of fine textured agricultural soils.