Robert Pollard

Plasmonic nanorod metamaterials for biosensing.

Label-free plasmonic biosensors rely either on surface plasmon polaritons or on localized surface plasmons on continuous or nanostructured noble-metal surfaces to detect molecular-binding events. Despite undisputed advantages, including spectral tunability, strong enhancement of the local electric field and much better adaptability to modern nanobiotechnology architectures, localized plasmons demonstrate orders of magnitude lower sensitivity compared with their guided counterparts. Here, we demonstrate an improvement in biosensing technology using a plasmonic metamaterial that is capable of supporting a guided mode in a porous nanorod layer. Benefiting from a substantial overlap between the probing field and the active biological substance incorporated between the nanorods and a strong plasmon-mediated energy confinement inside the layer, this metamaterial provides an enhanced sensitivity to refractive-index variations of the medium between the rods (more than 30,000 nm per refractive-index unit). We demonstrate the feasibility of our approach using a standard streptavidin-biotin affinity model and record considerable improvement in the detection limit of small analytes compared with conventional label-free plasmonic devices.

Designed ultrafast optical nonlinearity in a plasmonic nanorod metamaterial enhanced by nonlocality

All-optical signal processing enables modulation and transmission speeds not achievable using electronics alone. However, its practical applications are limited by the inherently weak nonlinear effects that govern photon-photon interactions in conventional materials, particularly at high switching rates. Here, we show that the recently discovered nonlocal optical behaviour of plasmonic nanorod metamaterials enables an enhanced, ultrafast, nonlinear optical response. We observe a large (80%) change of transmission through a subwavelength thick slab of metamaterial subjected to a low control light fluence of 7 mJ cm(-2), with switching frequencies in the terahertz range. We show that both the response time and the nonlinearity can be engineered by appropriate design of the metamaterial nanostructure. The use of nonlocality to enhance the nonlinear optical response of metamaterials, demonstrated here in plasmonic nanorod composites, could lead to ultrafast, low-power all-optical information processing in subwavelength-scale devices.

High-performance biosensing using arrays of plasmonic nanotubes

We show that aligned gold nanotube arrays capable of supporting plasmonic resonances can be used as high performance refractive index sensors in biomolecular binding reactions. A methodology to examine the sensing ability of the inside and outside walls of the nanotube structures is presented. The sensitivity of the plasmonic nanotubes is found to increase as the nanotube walls are exposed, and the sensing characteristic of the inside and outside walls is shown to be different. Finite element simulations showed good qualitative agreement with the observed behavior. Free standing gold nanotubes displayed bulk sensitivities in the region of 250 nm per refractive index unit and a signal-to-noise ratio better than 1000 upon protein binding which is highly competitive with state-of-the-art label-free sensors.

Growth and properties of gold and nickel nanorods in thin film alumina

Arrays of nickel and gold nanorods have been grown on glass and silicon substrates using porous alumina templates of less than 500 nm thickness. A method is demonstrated for varying the diameter of the nanorods whilst keeping the spacing constant. Optical extinction spectra for the gold nanorods show two distinct maxima associated with the transverse and longitudinal axes of the rods. Adding small quantities of oxygen to the aluminium before anodization is found to improve the sharpness of the extinction peaks. The spectral position of the longitudinal peak is shown to be sensitive to the nanorod diameter for constant length and spacing. For the nickel nanorods it is shown that the magnetic properties are governed by both interactions between the wires and shape anisotropy.

Guided plasmonic modes in nanorod assemblies: strong electromagnetic coupling regime

We demonstrate that the coupling between plasmonic modes of oriented metallic nanorods results in the formation of an extended (guided) plasmonic mode of the nanorod array. The electromagnetic field distribution associated to this mode is found to be concentrated between the nanorods within the assembly and propagates normally to the nanorod long axes, similar to a photonic mode waveguided by an anisotropic slab. This collective plasmonic mode determines the optical properties of nanorod assemblies and can be tuned in a wide spectral range by changing the nanorod array geometry. This geometry represents a unique opportunity for light guiding applications and manipulation at the nanoscale as well as sensing applications and development of molecular plasmonic devices.

Electrically switchable nonreciprocal transmission of plasmonic nanorods with liquid crystal

The electro-optic response of a cell consisting of a thin layer of liquid crystal deposited onto gold nanorods embedded in thin film alumina with a transparent top electrode has been investigated. For p-polarized light incident from the liquid crystal side, the extinction peak associated with the nanorod longitudinal plasmon resonance is completely suppressed. The peak could be recovered by applying an external electric field parallel to the long axis of the nanorods. No extinction peak suppression is observed when the light was incident from the nanorod side of the cell. The effect is explained by polarization properties of liquid crystal.

Manipulating polarization of light with ultrathin epsilon-near-zero metamaterials

One of the basic functionalities of photonic devices is the ability to manipulate the polarization state of light. Polarization components are usually implemented using the retardation effect in natural birefringent crystals and, thus, have a bulky design. Here, we have demonstrated the polarization manipulation of light by employing a thin subwavelength slab of metamaterial with an extremely anisotropic effective permittivity tensor. Polarization properties of light incident on the metamaterial in the regime of hyperbolic, epsilon-near-zero, and conventional elliptic dispersions were compared. We have shown that both reflection from and transmission through λ/20 thick slab of the metamaterial may provide nearly complete linear-to-circular polarization conversion or 90° linear polarization rotation, not achievable with natural materials. Using ellipsometric measurements, we experimentally studied the polarization conversion properties of the metamaterial slab made of the plasmonic nanorod arrays in different dispersion regimes. We have also suggested all-optical ultrafast control of reflected or transmitted light polarization by employing metal nonlinearities.

Controlling optical transmission through magneto-plasmonic crystals with an external magnetic field

The magneto-optical properties of surface-plasmon polaritonic crystals on ferromagnetic substrates have been studied. The resonant optical transmission of such magneto-plasmonic nanostructures can be efficiently controlled with the applied static magnetic field. The effect is explained by the influence of magneto-optical effects on surface-plasmon polariton waves supported by the metal/magnetic-dielectric interface and, in particular, on the plasmonic bandgap formation.

Fabrication and optical properties of gold nanotube arrays

Arrays of gold nanotubes with polypyrrole cores were grown on glass substrates by electrodeposition into thin film porous alumina templates. Measurements of optical transmission revealed strong extinction peaks related to plasmonic resonances, which were sensitive to the polarization state and angle of incidence. On prolonging the electrodeposition of gold, the polypyrrole core became fully encapsulated and this had a dramatic effect on the optical properties of the arrays, which was rationalized by finite element simulation of the local field intensities resulting from plasmon excitation.

Ultrasensitive Non‐Resonant Detection of Ultrasound with Plasmonic Metamaterials

Ultrasound and photoacoustic imaging have recently been developed for clinical diagnostics and biomedical research. Optical sensors for ultrasound detection provide very high sensitivity and bandwidth, advancing the horizon for the biomedical application of acoustic waves. Here we take advantage of the high sensitivity of plasmonic nanorod metamaterials to variations in the refractive index of their surroundings to demonstrate the ultrasensitive detection of acoustic waves. The measured detection limit is approximately 500 Pa as determined by the signal to noise ratio. The theoretical detection limit of the metamaterial sensor has been shown to exceed that of surface plasmon resonance based sensors in resonant conditions, predicting an ultimate sensitivity of a few tens of Pa. The non-resonant nature, signal linearity, high-bandwidth and sub-nanosecond response time of metamaterial-based sensors make them very promising for state-of-the-art health and biomedical applications. Photoacoustic and ultrasound imaging is widely used in clinical diagnostics and bio-medical research. [ 1 , 2 ] Specialized and emerging ultrasound-based technologies include tissue characterization and image segmentation, microscanning and intravascular scanning, elasticity imaging, refl ex transmission imaging, computed tomography, Doppler tomography and thermo-acoustics, to name a few. [ 3 , 4 ] Most of the recent achievements in ultrasound imaging have been enabled by advances in ultrasound detection technology, [ 2 ] and some signifi cant recent progress has been made employing “acoustic” metamaterials as specially fabricated acoustic lenses that allow much higher, sub-wavelength spatial resolution imaging to be achieved. [ 5 , 6 ] It is widely recognized that both the detection sensitivity and bandwidth are important in order to attain highquality, high-resolution imaging [ 7 , 8 ] and the ultrasound detector