Robert Prentner
ETH Zurich
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Featured researches published by Robert Prentner.
Angewandte Chemie | 2013
Sieghard Albert; Philippe Lerch; Robert Prentner; Martin Quack
Tunneling and chemical reactions by tunneling switching are reported for phenol and ortho-deuterophenol on the basis of high-resolution FTIR spectroscopy. Tunneling splittings are measured for the torsional motion in the ground and several vibrationally excited states of phenol. Tunneling times range from 10 ns to 1 ps, depending on excitation. For more-highly excited torsional levels in ortho-deuterophenol, delocalization and chemical reaction by tunneling switching is found.
Molecular Physics | 2016
Sieghard Albert; Ziqiu Chen; Csaba Fábri; Philippe Lerch; Robert Prentner; Martin Quack
ABSTRACT We report results on the dynamics of tunnelling switching based on a high-resolution spectroscopic investigation of meta-D-phenol in GHz and THz ranges. The pure rotational spectra were recorded in the range of 72–117 GHz and assigned to the localized syn- and anti-structures in the ground and the first excited torsional states. Specific torsional states were unambiguously assigned by comparison of the experimental rotational constants with theoretical results from quasiadiabatic channel reaction path Hamiltonian (RPH) calculations. The torsional fundamental νT at ≈ 309 cm−1 and the first hot band (2νT – νT) at ≈ 277 cm−1 were subsequently assigned in synchrotron based high-resolution Fourier transform infrared (FTIR, THz) spectra. The analyses provided accurate spectroscopic constants of all six states involved. It was found that the 2νT states are interacting through anharmonic resonances, indicating tunnelling switching as predicted by theory. Furthermore, tunnelling–rotation–vibration transitions were assigned and the tunnelling splitting in 2νT was determined as 1.72450(17) cm−1. This key result allowed the assignment of two Q branches at 275.21303(9) and 277.67127(9) cm−1 to vibration-tunnelling transitions of the (syn ← anti) type, hence confirming tunnelling switching dynamics in m-D-phenol. The ground-state energy difference of the syn- and anti-isotopomers is obtained experimentally as E0 (syn) - E0 (anti) = (hc)0.82 cm−1 in satisfactory agreement with the theoretical ab initio predictions of (hc)1.5 cm−1 given the small absolute values arising from the tiny zero point energy effects. The results are discussed in relation to further fundamental aspects of tunnelling in slightly asymmetric potentials including the effects of the parity violating electroweak interaction in chiral molecules.
Physical Chemistry Chemical Physics | 2018
Csaba Fábri; Sieghard Albert; Ziqiu Chen; Robert Prentner; Martin Quack
We introduce the concept of a molecular quantum switch and demonstrate it with the example of meta-d-phenol, based on recent theoretical and high-resolution spectroscopic results for this molecule. We show that in the regime of tunneling switching with localized low-energy states and delocalized high-energy states the molecular quantum switch can be operated in two different ways: (i) a quasiclassical switching by coherent infrared radiation between the two isomeric structures syn- and anti-m-d-phenol; and (ii) a highly nonclassical switching making use of bistructural quantum superposition states of the syn and anti structures, which can be observed by their time-dependent spectra after preparation.
72nd International Symposium on Molecular Spectroscopy | 2017
Ziqiu Chen; Daniel Zindel; Martin Quack; Robert Prentner; Csaba Fábri; Sieghard Albert
Tunneling switching is a fundamental phenomenon of interest in molecular quantum dynamics including also chiral molecules and parity violation.a,b,c Deuterated phenols have been identified as prototypical achrial candidates.d We report the high resolution spectroscopic investigation of the ortho-D-phenol in the GHz and THz ranges following our recent discovery of tunneling switching in its isotopomer meta-D-phenol.e Here we report new results on ortho-D-phenol.The pure rotational spectra were recorded in the range of 72-117 GHz and assigned to the synand antistructures in the ground and the first excited torsional states. Specific torsional states were assigned based on a comparison of experimental rotational constants with the quasiadiabatic channel reaction path Hamiltonian (RPH) calculations. The torsional fundamental at 308 cm−1 and the first hot band at 275 cm−1 were subsequently assigned. The analyses of pure rotational and rovibrational spectra shall be discussed in detail in relation to possible tunneling switching.
Journal of Physical Chemistry A | 2015
Robert Prentner; Martin Quack; Jürgen Stohner; Martin Willeke
Philosophies | 2017
Robert Prentner
Constructivist Foundations | 2017
Chris Fields; Donald D. Hoffman; Chetan Prakash; Robert Prentner
Open Philosophy | 2018
Robert Prentner
Frontiers in Psychology | 2017
Robert Prentner
Foundations of Chemistry | 2017
Robert Prentner