Roberto J. Anima

Historical trends of metals in the sediments of San Francisco Bay, California

Abstract Concentrations of Ag, Al, Cr, Cu, Fe, Hg, Mn, Ni, Pb, V and Zn were determined in six sediment cores from San Francisco Bay (SFB) and one sediment core in Tomales Bay (TB), a reference estuary. SFB cores were collected from between the head of the estuary and its mouth (Grizzly Bay, GB; San Pablo Bay, SP; Central Bay, CB; Richardson Bay, RB, respectively) and ranged in length from 150 to 250 cm. Concentrations of Cr, V and Ni are greater than mean crustal content in SFB and TB sediments, and greater than found in many other coastal sediments. However, erosion of ultramafic rock formations in the watershed appears to be the predominant source. Baseline concentrations of other metals were determined from horizons deposited before sediments were influenced by human activities and by comparing concentrations to those in TB. Baseline concentrations of Cu co-varied with Al in the SFB sediments and ranged from 23.7±1.2 μg/g to 41.4±2.4 μg/g. Baseline concentrations of other metals were less variable: Ag, 0.09±0.02 μg/g; Pb, 5.2±0.7 μg/g; Hg, 0.06±0.01 μg/g; Zn, 78±7 μg/g. The earliest anthropogenic influence on metal concentrations appeared as Hg contamination (0.3–0.4 μg/g) in sediments deposited at SP between 1850 and 1880, apparently associated with debris from hydraulic gold mining. Maximum concentrations of Hg within the cores were 20 times baseline. Greater inventories of Hg at SP and GB than at RB verified the importance of mining in the watershed as a source. Enrichment of Ag, Pb, Cu and Zn first appeared after 1910 in the RB core, later than is observed in Europe or eastern North America. Maximum concentrations of Ag and Pb were 5–10 times baseline and Cu and Zn concentrations were less than three times baseline. Large inventories of Pb to the sediments in the GB and SP cores appeared to be the result of the proximity to a large Pb smelter. Inventories of Pb at RB are similar to those typical of atmospheric inputs, although influence from the Pb smelter is also suspected. Concentrations of Hg and Pb have decreased since the 1970s (to 0.30 μg/g and 25 μg/g, respectively) and were similar among all cores in 1990. Early Ag contamination was perhaps a byproduct of the Pb smelting process, but a modern source of Ag is also indicated, especially at RB and CB.

Sedimentary record of anthropogenic and biogenic polycyclic aromatic hydrocarbons in San Francisco Bay, California

Dated sediment cores collected from Richardson and San Pablo Bays in San Francisco Bay were used to reconstruct a history of polycyclic aromatic hydrocarbon (PAH) contamination. The sedimentary record of PAHs in Richardson Bay shows that anthropogenic inputs have increased since the turn of the century, presumably as a result of increasing urbanization and industrialization around the Bay Area. Concentrations range from about 0.04–6.3 μg g−1. The dominant origin of the PAHs contributing to this modern contamination is from combustion processes. Depth profiles in San Pablo Bay indicate higher concentrations of PAHs since the 1950s than during the late 1800s, also presumably resulting from an increase in urbanization and industrialization. Total PAHs in San Pablo Bay range from about 0.04–1.3 μg g−1. The ratios of methylphenanthrenes/phenanthrene and (methylfluoranthenes+methylpyrenes)/fluoranthene were sensitive indicators of anthropogenic influences in the estuary. Variations in the ratio of 1,7-dimethylphenanthrene/2,6-dimethylphenanthrene indicate a gradual replacement of wood by fossil-fuel as the main combustion source of PAHs in San Francisco Bay sediments. The profile of perylene may be an indicator of eroding peat from marshlands.

Sediment chronology in San Francisco Bay, California, defined by 210Pb, 234Th, 137Cs, and 239,240Pu

Abstract Sediment chronologies based on radioisotope depth profiles were developed at two sites in the San Francisco Bay estuary to provide a framework for interpreting historical trends in organic compound and metal contaminant inputs. At Richardson Bay near the estuary mouth, sediments are highly mixed by biological and/or physical processes. Excess 234 Th penetration ranged from 2 to more than 10 cm at eight coring sites, yielding surface sediment mixing coefficients ranging from 12 to 170 cm 2 /year. At the site chosen for contaminant analyses, excess 210 Pb activity was essentially constant over the upper 25 cm of the core with an exponential decrease below to the supported activity between 70 and 90 cm. Both 137 Cs and 239,240 Pu penetrated to 57-cm depth and have broad subsurface maxima between 33 and 41 cm. The best fit of the excess 210 Pb profile to a steady state sediment accumulation and mixing model yielded an accumulation rate of 0.825 g/cm 2 /year (0.89 cm/year at sediment surface), surface mixing coefficient of 71 cm 2 /year, and 33-cm mixed zone with a half-Gaussian depth dependence parameter of 9 cm. Simulations of 137 Cs and 239,240 Pu profiles using these parameters successfully predicted the maximum depth of penetration and the depth of maximum 137 Cs and 239,240 Pu activity. Profiles of successive 1-year hypothetical contaminant pulses were generated using this parameter set to determine the age distribution of sediments at any depth horizon. Because of mixing, sediment particles with a wide range of deposition dates occur at each depth. A sediment chronology was derived from this age distribution to assign the minimum age of deposition and a date of maximum deposition to a depth horizon. The minimum age of sediments in a given horizon is used to estimate the date of first appearance of a contaminant from its maximum depth of penetration. The date of maximum deposition is used to estimate the peak year of input for a contaminant from the depth interval with the highest concentration of that contaminant. Because of the extensive mixing, sediment-bound constituents are rapidly diluted with older material after deposition. In addition, contaminants persist in the mixed zone for many years after deposition. More than 75 years are required to bury 90% of a deposited contaminant below the mixed zone. Reconstructing contaminant inputs is limited to changes occurring on a 20-year time scale. In contrast, mixing is much lower relative to accumulation at a site in San Pablo Bay. Instead, periods of rapid deposition and/or erosion occurred as indicated by frequent sand-silt laminae in the X-radiograph. 137 Cs , 239,240 Pu , and excess 210 Pb activity all penetrated to about 120 cm. The distinct maxima in the fallout radionuclides at 105–110 cm yielded overall linear sedimentation rates of 3.9 to 4.1 cm/year, which are comparable to a rate of 4.5±1.5 cm/year derived from the excess 210 Pb profile.

Seafloor geology of the Monterey Bay area continental shelf

Abstract Acoustic swath-mapping of the greater Monterey Bay area continental shelf from Point Ano Nuevo to Point Sur reveals complex patterns of rock outcrops on the shelf, and coarse-sand bodies that occur in distinct depressions on the inner and mid-shelves. Most of the rock outcrops are erosional cuestas of dipping Tertiary rocks that make up the bedrock of the surrounding lands. A mid-shelf mud belt of Holocene sediment buries the Tertiary rocks in a continuous, 6-km-wide zone on the northern Monterey Bay shelf. Rock exposures occur on the inner shelf, near tectonically uplifting highlands, and on the outer shelf, beyond the reach of the mud depositing on the mid-shelf since the Holocene sea-level rise. The sediment-starved shelf off the Monterey Peninsula and south to Point Sur has a very thin cover of Holocene sediment, and bedrock outcrops occur across the whole shelf, with Salinian granite outcrops surrounding the Monterey Peninsula. Coarse-sand deposits occur both bounded within low-relief rippled scour depressions, and in broad sheets in areas like the Sur Platform where fine sediment sources are limited. The greatest concentrations of coarse-sand deposits occur on the southern Monterey Bay shelf and the Sur shelf.

Nearshore morphology and late Quaternary geologic framework of the northern Monterey Bay Marine Sanctuary, California

A combination of side-scanning sonar and high-resolution seismic reflection data image seafloor bedrock exposures and erosional features across the nearshore shelf. Sediment-filled troughs incise the inner shelf rock exposures and tie directly to modern coastal streams. The resulting bedrock geometry can be related to its resistance to erosion. Comparison of the depth of the transgressive erosional surface to recently developed sea level curves suggests a period of slow sea level rise during the early stages of post-interglacial marine transgression. The slow rise of sea level suggests an erosional episode that limited the preservation of buried paleo-channels beyond 70 m water depth. Seafloor features suggest that localized faulting in the area may have influenced the morphology of bedrock exposures and the coastline.

Coarse-sediment bands on the inner shelf of southern Monterey Bay, California

Abstract Bands of coarse sand that trend parallel to the shore, unlike the approximately shore-normal bands found in many inner shelf areas, occur in southern Monterey Bay at water depths of 10–20 m, less than 1 km from the shore. The bands are 20–100 m wide and alternate with bands of fine sand that are of similar width. The coarse-sand bands are as much as 1 m lower than the adjacent fine-sand bands, which have margins inclined at angles of about 20°. The mean grain sizes of the coarse and fine sand are in the range of 0.354–1.0 mm and 0.125–0.354 mm, respectively. Wave ripples that average about 1 m in spacing always occur in the coarse-sand bands. Over a period of 3 yrs, the individual bands moved irregularly and changed in shape, as demonstrated by repeated sidescan sonar surveys and by the monitoring of rods jetted into the sea floor. However, the overall pattern and distribution of the bands remained essentially unchanged. Cores, 0.5–1.0 m long, taken in coarse-sand bands contain 0.2–0.5 m of coarse sand overlying fine sand or interbedded fine and coarse sand. Cores from fine-sand bands have at least one thin coarse sand layer at about the depth of the adjacent coarse-sand band. None of the cores revealed a thick deposit of coarse sand. The shore-parallel bands are of unknown origin. Their origin is especially puzzling because approximately shore-normal bands are present in parts of the study area and immediately to the north.

Subaqueous grain flows at the head of Carmel Submarine Canyon, California

ABSTRACT The head of Carmel Submarine Canyon lies in 15 m of water about 200 m off a coarse-sand beach in the southeast corner of Carmel Bay, California. Very coarse sand is the predominate material on the beach, adjacent shelf, and upper canyon-head slopes, while silt and clay cover the surface below a water depth of about 35 m. Along a shore-normal transect, median grain size decreases between the beach and canyon rim but increases down the upper canyon-head slope. On angle-of-repose slopes in the upper canyon head, downslope-coarsening deposits, which are everywhere there is active sand movement, are similar to a type of sediment gravity flow deposit formed by grain flows (sand avalanches). Using three sand fractions that were dyed different fluorescent colors, scuba divers generated sand avalanches that produced deposits similar to the natural deposits. The dyed-sand deposits, which extended as far as 25 m below the initiation point, were inversely graded and increased in grain size downslope. Inverse grading was well developed within two m of the initiation point, though the thicknesses of the three layers varied in a nonsystematic manner both across and down slope. The minor amount of native material found within the dyed-sand layers showed hat entrainment of the underlying sand was minimal.

Field Study of Subaqueous Avalanching: ABSTRACT

Many submarine canyon walls consist of unconsolidated sand sitting at the angle of repose (~ 31°). The sand walls commonly maintain this slope for many tens of meters before leveling out at the canyon bottom. Where such angle-of-repose sand slopes occur within scuba diving depth, they present an opportunity to study subaqueous grain flows in situ. Such a study has been conducted in the head of Carmel submarine canyon, Carmel Bay, California. End_Page 918------------------------------ The object of the study was to determine the depositional pattern associated with subaqueous, gravity-driven grain flows. In particular, we attempted to determine whether the resulting deposits would exhibit inverse grading, as has been observed on the foresets of eolian dunes and in beach foreshore laminations. The experiments consisted of dumping dyed sand onto the slope, which generated a grain flow approximately 25 m long, and taking undisturbed cores both across and down the flow. The cores were dissected and the distribution of dyed grains determined. Because the sand was divided into three size fractions that were each dyed a different color, grading and sorting patterns were readily discernible. In addition to inverse grading, we found sorting both down and across the flow, and the largest grains traveled the greatest distances. Because samples from natural, angle-to-repose sand slopes of Carmel Canyon show a downslope increase in grain size, we conclude that similar processes operate there. Once the slopes begin to level out, deposition of fine material from suspension becomes important and coarse material is no longer found in surficial samples. End_of_Article - Last_Page 919------------

SURVEYS OF COASTAL STRUCTURES USING GEOPHYSICAL TECHNIQUES

This report will update the coastal zone practitioner on the National Flood Insurance Program (NFIP) as it affects the implementation of manmade changes along the coastline. It is our intent to place in proper perspective this fast-changing and often difficult to interpret national program. Readers will achieve an overall understanding of the NFIP on the coast, and will be in a position to apply the programs requirements in their efforts. We will begin with a history of the application of the NFIP to the coastal zone. The history of the problems encountered will lead into current regulations, methodologies, and the changes the Federal Emergency Management Agency plans for the future.The spatial variability of the nearshore wave field is examined in terms of the coherence functions found between five closely spaced wave gages moored off the North Carolina coast in 17 meters depth. Coherence was found to rapidly decrease as the separation distance increased, particularly in the along-crest direction. This effect is expressed as nondimensional coherence contours which can be used to provide an estimate of the wave coherence expected between two spatial positions.Prediction of depositional patterns in estuaries is one of the primary concerns to coastal engineers planning major hydraulic works. For a well-mixed estuary where suspended load is the dominant transport mode, we propose to use the divergence of the distribution of the net suspended load to predict the depositional patterns. The method is applied to Hangzhou Bay, and the results agree well qualitatively with measured results while quantitatively they are also of the right order of magnitude.