Rodney A. Bryant

An uncertainty analysis of mean flow velocity measurements used to quantify emissions from stationary sources

Point velocity measurements conducted by traversing a Pitot tube across the cross section of a flow conduit continue to be the standard practice for evaluating the accuracy of continuous flow-monitoring devices. Such velocity traverses were conducted in the exhaust duct of a reduced-scale analog of a stationary source, and mean flow velocity was computed using several common integration techniques. Sources of random and systematic measurement uncertainty were identified and applied in the uncertainty analysis. When applicable, the minimum requirements of the standard test methods were used to estimate measurement uncertainty due to random sources. Estimates of the systematic measurement uncertainty due to discretized measurements of the asymmetric flow field were determined by simulating point velocity traverse measurements in a flow distribution generated using computational fluid dynamics. For the evaluated flow system, estimates of relative expanded uncertainty for the mean flow velocity ranged from ±1.4% to ±9.3% and depended on the number of measurement locations and the method of integration. Implications: Accurate flow measurements in smokestacks are critical for quantifying the levels of greenhouse gas emissions from fossil-fuel-burning power plants, the largest emitters of carbon dioxide. A systematic uncertainty analysis is necessary to evaluate the accuracy of these measurements. This study demonstrates such an analysis and its application to identify specific measurement components and procedures needing focused attention to improve the accuracy of mean flow velocity measurements in smokestacks.

Evaluating measurements of carbon dioxide emissions using a precision source—A natural gas burner

A natural gas burner has been used as a precise and accurate source for generating large quantities of carbon dioxide (CO2) to evaluate emissions measurements at near-industrial scale. Two methods for determining carbon dioxide emissions from stationary sources are considered here: predicting emissions based on fuel consumption measurements—predicted emissions measurements, and direct measurement of emissions quantities in the flue gas—direct emissions measurements. Uncertainty for the predicted emissions measurement was estimated at less than 1%. Uncertainty estimates for the direct emissions measurement of carbon dioxide were on the order of ±4%. The relative difference between the direct emissions measurements and the predicted emissions measurements was within the range of the measurement uncertainty, therefore demonstrating good agreement. The study demonstrates how independent methods are used to validate source emissions measurements, while also demonstrating how a fire research facility can be used as a precision test-bed to evaluate and improve carbon dioxide emissions measurements from stationary sources. Implications: Fossil-fuel-consuming stationary sources such as electric power plants and industrial facilities account for more than half of the CO2 emissions in the United States. Therefore, accurate emissions measurements from these sources are critical for evaluating efforts to reduce greenhouse gas emissions. This study demonstrates how a surrogate for a stationary source, a fire research facility, can be used to evaluate the accuracy of measurements of CO2 emissions.

Characterizing Inward Leakage in a Pressure-Demand, Self-Contained Breathing Apparatus

An analytical model of the flow across a resistive flow path such as an orifice or pipe was applied to predict the inward leakage in the facepiece of a self-contained breathing apparatus (SCBA) during a steady below-ambient facepiece pressure. The model was used to estimate leakage rates with respect to the size of the leak and for below-ambient (negative) pressure conditions reflective of measured occurrences. Results of the model were also used to make quantitative estimates of the protection level of the respirator. Experiments were designed to induce a continuous below-ambient pressure inside the facepiece of a pressure-demand SCBA mounted on a headform. Negative facepiece pressure measured in the presence of a leak correlated with the measured particle concentration ratio. Results show that the analytical model generated reasonable estimates of leakage rates during conditions of negative pressure inside the facepiece. Thus, the analytical model performed well for constant flow conditions, demonstrating the capability to predict a momentary compromise in respirator protection during momentary negative facepiece pressure conditions.

An Investigation of Extinguishment by Thermal Agents Using Detailed Chemical Modeling of Opposed Jet Diffusion Flames

Abstract : The manufacture of the halons widely used in fire extinguishing systems was banned in 1994 due to their deleterious effect on stratospheric ozone. Since the late 198Os there have been ongoing research efforts to identify replacement agents having comparable properties. This search has proven difficult and continues today with a large directed effort known as the Next Generation Fire Suppression Technology Program (NGP). As part of the NGP, the National Institute of Standards and Technology is investigating whether highly effective thermal agents are feasible. Thermal agents are defined as those that obtain their effectiveness solely by heat extraction and dilution. Excluded from investigation are species that directly or indirectly disrupt the combustion chemistry such as halons, which derive much of their effectiveness by the release of bromine atoms that catalytically remove hydrogen atoms in the flame zone. A great deal is known about the effects of thermal agents on flames.