Rolf Pinkos | Researchain

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Tetrahedron Letters | 1990

Molecular structures of a seco-dodecahedradiene and an iso-dodecahedrane

Hermann Irngartinger; Uwe Reifenstahl; Horst Prinzbach; Rolf Pinkos; Klaus Weber

Abstract The olefinic carbon atoms on the closed side of seco-dodecahedradiene 1 are strongly pyramidalized (o = 35.3°). The transanular C1C2 bond of non-pentagonal isododecahedrane 2 is one of the longest CC bonds (1.691A) ever measured in cage structures.

Tetrahedron Letters | 1989

Domino and pincer cycloadditions with syn-o,o'-dibenzenes pressure dependence and mechanistic implications

Frank-Gerrit Klärner; Uwe Artschwager‐Perl; Wolf-Dieter Fessner; Clemens Grund; Rolf Pinkos; Johann-Peter Melder; Horst Prinzbach

Abstract For additions of acetylenic dienophiles to various syn-o,o′-dibenzenes a two-step mechanism is inferred from relative rate enhancements and stereoselectivities in high-pressure vs. ambient-pressure reactions.

Journal of the American Chemical Society | 1993

The pagodane route to dodecahedranes : highly functionalized, saturated and (bis-)unsaturated pentagonal dodecahedranes via SN2 cyclizations

Rolf Pinkos; Johann Peter Melder; Klaus Weber; Dieter Hunkler; Horst Prinzbach

Chemische Berichte | 1986

Studien im Umfeld funktionalisierter/anellierter acs-Tetracyclo[7.2.1.04,11•06,10]dodeca-2,7-dien-Gerüste ― Röntgenstrukturanalysen einer «face-to-face»-Dibenzoverbindung und eines Tetraoxadihydro-pagodans

Gottfried Sedelmeier; Wolf-Dieter Fessner; Rolf Pinkos; Clemens Grund; Bulusu A. R. C. Murty; Dieter Hunkler; Grety Rihs; Hans Fritz; Carl Krüger; Horst Prinzbach

Chemische Berichte | 1992