Rosalda Punturo

Alpine Metamorphism in the Aspromonte Massif: Implications for a New Framework for the Southern Sector of the Calabria-Peloritani Orogen, Italy

Structural, petrologic, and thermobarometric data presented in this paper contribute to our understanding of the tectono-metamorphic evolution of the lowest tectonic slices of the Aspromonte Massif (southern Calabria, Italy), which crop out in three main tectonic windows. Despite previously being considered different units, they exhibit the following similar features: the same tectonic evolution, analogous blasto-deformation relationships, and absence of Hercynian mineralogical assemblage relics. Similar P-T paths indicate early HP-LT Meso-Alpine metamorphism (400-600° C at 0.95-1.35 GPa), evolving in the Oligocene-Miocene toward a subsequent retrograde shearing event ranging from 480° to 610°C and 0.50 to 0.95 GPa. The latest retrograde evolution is characterized by 350-480°C and 0.32-0.62 GPa. In this new tectonic framework, it is proposed to group the metapelite sequences defining the Madonna di Polsi Unit. Data presented herein suggest that the pre-Alpine geodynamic setting of southern Calabria was a thinned continental margin made up of Hercynian basement and Mesozoic terrigenous-carbonate sedimentary cover. This continental margin evolved during the early Meso-Alpine stage into a subduction zone beneath the European plate, followed by Neo-Alpine syn-convergent exhumation along a deep-seated mylonitic shear zone. These processes are responsible for the Alpine metamorphic overprint on the Hercynian terranes, as well as for Alpine metamorphism of their Mesozoic cover.

Fault-related rocks: deciphering the structural–metamorphic evolution of an accretionary wedge in a collisional belt, NE Sicily

The Alpine chain exposed in the Western Mediterranean area represents a front several kilometres in width, dismembered by more recent tectonics and by opening of the Tyrrhenian Basin. In most exposures of this mountain belt, relics of older metamorphic rocks occur. The deformational sequence of events may be revealed by the recognition of metamorphic records associated with different structures. Within a tract of the Alpine front cropping out in the Peloritani Mountains (NE Sicily), we distinguished two metamorphic complexes characterized by different tectonometamorphic histories. Their present tectonic juxtaposition is a cataclastic thrust linked to the recent Africa-verging Sicilian–Maghrebian fold-and-thrust belt. The Lower Complex is characterized by Hercynian metamorphism (P > 0.2 GPa and T ≈ 350°C) exclusively. It essentially consists of very low-grade metapelites and metavolcanic rocks overlain by an unmetamorphosed sedimentary cover. The Upper Complex, comprising different tectonic slices, consists of medium- to high-grade Hercynian metamorphic rocks (P = 0.3–0.8 GPa and T up to 650°C) with Alpine metamorphic overprint (T > 250°C) affecting also the Mesozoic–Cenozoic cover. Lithotypes, structures, and inferred P–T conditions of investigated rocks suggest the existence of an Alpine accretionary wedge during the Cretaceous deformational collision. Within the Upper Complex, a polyphase Palaeogene mylonitic horizon involving rocks belonging to different tectonic slices fully preserves the tectonometamorphic evolution. For this reason, we focused our attention on these sheared rocks in order to reconstruct the entire tectonic history of this geologically complex area. Our new basic model allows the complex structure of the nappe-pile edifice of the Peloritani Mountains to be simplified, casting new light on the tectonic evolution of this key sector of the southern Calabrian-Peloritani Orogen.

Microstructure and elastic anisotropy of naturally deformed leucogneiss from a shear zone in Montalto (southern Calabria, Italy)

Abstract A strain gradient was mesoscopically recognized in sheared leucogneisses cropping out near Mount Montalto (Calabria, southern Italy) in the Aspromonte–Peloritani Unit on the basis of field observations. In order to investigate the relationship between textural and physical anisotropy, a microstructural and petrophysical study was carried out on selected mylonites exhibiting different stages of deformation. The main mineral assemblage is Qtz+Pl+Kfs+Wm, displaying S–C and shear-band textures; mica-fish and ribbon-like quartz are widespread. As strain increases K-feldspar, biotite and premylonitic low phengite white mica transformed to synmylonitic high phengite white mica and quartz, accompanied by an increasing albitization. Different quartz c-axis patterns are ascribable to non-coaxial progressive deformation; we suggest that deformation proceeded under greenschist- up to amphibolite-facies conditions owing to a local increase in shearing temperature. Laboratory seismic measurements were carried out on sample cubes (43 mm edged) cut according to the structural frame (foliation, lineation) of the rock. At 400 MPa and room temperature the averages of compressional (Vp) and shear-wave velocities (Vs) are very similar: 5.70–5.91 and 3.36–3.55 km s−1, respectively. Seismic anisotropy and shear-wave splitting are related to the modal amounts of constituent minerals (in particular mica) and their crystallographic preferred orientation. Importantly, anisotropy is lowest in the most strained rock.

Influence of dissolved organic matter on rare earth elements and yttrium distributions in coastal waters

Data collected during this study indicate that dissolved Y and REE (rare earth element) behaviour can be monitored through shale-normalised ratios. Relationships occurring between these ratios suggest that leaching from lithogenic materials is the main source of REE in the studied area. This process involves riverine detrital matter in the inner area of the Gulf of Palermo. Features of shale-normalised patterns and the relationship recognised between dissolved Fe and Y/Ho suggest that REE are released from Fe-rich coatings of atmospheric dust. Observed similarities between dissolved Fe and chlorophyll-α content suggest that leaching of Fe-rich atmospheric particulates induces a fertilisation of shallow water layers influencing the dissolved organic content. In turn, the increasing chlorophyll-α content causes a progressive decrease in amplitude of the negative Ce anomaly in seawater that is also observed in water in the Central Mediterranean Sea, suggesting that organic matter generally plays a key role in REE behaviour at the solid–liquid interface. Shale-normalised REE features recognised in suspended particulate matter (SPM) indicate the occurrence of three different fractions from lithogenic matter, biogenic carbonates and authigenic components, respectively. The latter is formed during REE scavenging onto the surface of detrital biogenic particles and is mainly recognised in inner gulf waters.

Garnet-spinel-pyroxenite xenoliths from Hyblean Plateau (South-eastern Sicily, Italy)

SummaryRare garnet-spinel pyroxenite xenoliths occur in some basaltic tuff-breccia levels of Miocene age from the Valle Guffari (Hyblean Plateau, Sicily), together with a number of spinel-bearing mantle xenoliths. The garnet-bearing pyroxenites may be divided into two groups (“a” and “b”) on textural and mineralogical bases. Garnet-bearing spinel websterites with a fully recrystallized texture represent the first group (a). Here the garnet (Py54.5 A1m32 Gr13.5), with a diffuse kelyphitic alteration, forms a reaction corona between coarse spinel grains and the in contact pyroxenes. The transition from the spinel-pyroxenite to the garnet-pyroxenite field may depend on isobaric cooling from higher (magmatic?) temperatures. Garnet-pyroxene geothermometry indicates that the last equilibration most probably occurred at P = 1.0 GPa (ca.), T = 750 °C (ca).The second lithotype (b) is an orthopyroxene-bearing garnet-spinel clinopyroxenite, exhibiting a complex texture. It consists of zones of coarse clinopyroxene grains enclosing euhedral spinel passing to zones where tiny rounded crystals of the same pyroxene and spinel are enclosed in relatively large patches of extensively kelyphitisized garnet (Py64.8 Alm25.6 Gr9.6). Garnet also occurs as inclusion-free grains up to 4 mm in diameter. P-T calculations give significantly higher values than for the former case (a). The origin of the b-type garnet may also depend on subsolidus reaction of spinel and pyroxenes after an isobaric cooling from still higher temperatures, but a primary magrnatic origin might also be possible, especially for the “granular” garnets.P-T estimates for both the pyroxenite types closely match a steady geotherm for 100 mW/m2 surface heat flow. Such a relatively intense heat flow may suggest the occurrence of huge masses of hot magma intruding the Hyblean lithospheric mantle and lower crust at different levels.ZusammenfassungSeltene Granat-Spinell-Pyroxenit-Xenolithe kommen in einigen basaltischen Tuff-Breckzien Horizonten miozänen Alters aus dem Valle Guffari (lblei-Plateau, Sizilien) zusammen mit einer Anzahl von Spinell-führenden Mantel-Xenolithen vor. Aufgrund textureller und mineralogischer Kriterien können die Granat-führenden Pyroxenite in zwei Gruppen („a” und „b”) unterteilt werden. Granat-führende Spinell-Websterite mit vollkommen rekristallisierter Textur repräsentieren die erste Gruppe („a”). Hier bildet Granat (Py54.5 Alm32 Gr13.5) mit einer diffusen kelyphitischen Umwandlung, einen Reaktionssaum zwischen grobkörnigem Spinell und Pyroxenen, mit denen er in Kontakt ist. Der übergang vom Spinell-Pyroxenit- zum Granat-Pyroxenit-Feld kann auf isobarische Abkühlung von höheren (magmatischen ?) Temperaturen zurückgehen. Granat-Pyroxen-Geothermometrie zeigt, dass die letzte Equilibrierung sehr wahrscheinlich bei P = 1.0 GPa (ca.), T = 750°C (ca.) erfolgte.Der zweite Typ von Granat-führenden Pyroxeniten ist ein („b”) Orthopyroxenführender Granat-Spinell-Klinopyroxenit, der komplexe Texturen zeigt. Er besteht aus Zonen von grobkörnigem Klinopyroxen mit Einschlüssen von idiomorphem Spinell, der in Zonen übergeht, wo kleine gerundete Kristalle des gleichen Pyroxens und Spinells in relativ große Bereiche von extensiv kelyphitisiertem Granat (Py64,8 Alm25,6 Gr9,6) eingeschlossen sind. Granat kommt auch als einschlußfreie Körner mit bis zu 4 mm Durchmesser vor. P-T Berechnungen geben wesentlich höhere Werte als für die Gesteine des Types („a”). Die Entstehung der b-Typ-Granaten kann auch durch Subsolidus-Reaktion von Spinell und Pyroxen nach isobarischer Abkühlung von noch höheren Temperaturen beeinflußt sein; ein primärer magmatischer Ursprung könnte auch möglich sein, besonders für die „körnigen” Granate.P-T Abschätzungen für beide Pyroxenit-Typen sind gut einer Geotherme für 100 mW/m2 Wärmefluß an der Oberfläche zuzuordnen. Ein solcher, relativ intensiver Wärmefluß könnte auf das Vorkommen von großen heißen Magmenkörpern hinweisen, die den lithosphärischen Mantel unter dem Iblei-Plateau und die untere Kruste in verschiedenen Niveaus intrudierten.

Microstructural, compositional and petrophysical properties of mylonitic granodiorites from an extensional shear zone (Rhodope Core complex, Greece)

At the southern boundary of the Rhodope Massif, NE Greece, the Kavala Shear Zone (KSZ) represents an example of the Eastern Mediterranean deep-seated extensional tectonic setting. During Miocene time, extensional deformation favoured syntectonic emplacement and subsequent exhumation of plutonic bodies. This paper deals with the strain-related changes in macroscopic, geochemical and microstructural properties of the lithotypes collected along the KSZ, comprising granitoids from the pluton, aplitic dykes and host rock gneisses. Moreover, we investigated the evolution of seismic anisotropy on a suite of granitoid mylonites as a result of progressive strain. Isotropic compressional and shear wave velocities ( V p , V s ) and densities calculated from modal proportions and single-crystal elastic properties at given pressure–temperature ( P – T ) conditions are compared to respective experimental data including the directional dependence (anisotropy) of wave velocities. Compared to the calculated isotropic velocities, which are similar for all of the investigated mylonites (average values: V p ~ 5.87 km s −1 , V s ~ 3.4 km s −1 , V p / V s = 1.73 and density = 2.65 g cm −3 ), the seismic measurements give evidence for marked P-wave velocity anisotropy up to 6.92% (at 400 MPa) in the most deformed rock due to marked microstructural changes with progressive strain, as highlighted by the alignment of mica, chlorite minerals and quartz ribbons. The highest P- and S-wave velocities are parallel to the foliation plane and lowest normal to the foliation plane. Importantly, V p remains constant within the foliation with progressive strain, but decreases normal to foliation. The potential of the observed seismic anisotropy of the KSZ mylonites with respect to detectable seismic reflections is briefly discussed.

The Calabria-Peloritani Orogen, a composite terrane in Central Mediterranean; its overall architecture and geodynamic significance for a pre-Alpine scenario around the Tethyan basin

The Calabria-Peloritani Orogen is an arcuate segment of the peri-Mediterranean orogenic Alpine nappe system that comprises the whole Calabria and the north-eastern sector of Sicily. It comprises the Sila and Catena Costiera Massifs in northern Calabria, the Serre and Aspromonte Massifs in central and southern Calabria, and the Peloritani Mountains in Sicily. In Sila and Catena Costiera Massifs, three tectonic complexes are recognisable: a) the basal Apennine Complex, which consists of carbonate platform sequences of passive continental margin; b) the intermediate Liguride Complex, made of oceanic-derived units, affected by HP/LT metamorphism; and c) the upper Calabride Complex, which represents a nearly entire section of continental crust. The Catanzaro Line separates the northern sector from the Serre Massif that also represents a nearly entire segment of Variscan continental crust unaffected by Alpine metamorphism. Further to the south, the Palmi Line separates the Serre from the Aspromonte Massif and the Peloritani Mountains. These two latter nappe edifices consist of either Variscan metamorphic units, Variscan units with Alpine overprint and units of continental derivation that are exclusively affected by Alpine metamorphism. The comparison between the geological evolutions of the various chain sectors, as well as their structural setting and their direction of tectonic transport, indicates that the Calabria-Peloritani Orogen is a composite terrane derived from the amalgamation of crustal blocks of different continental provenance. Northern Calabria represents a fragment of the Adria palaeomargin, whereas southern Calabria and northeastern Sicily are relics of an accretionary wedge resulting from the deformation of the European continental margin. As a consequence, nowadays a segment of the Europe-Adria collisional suture crops out in central Calabria.

Naturally occurring asbestos (NOA) in rock and soil and relation with human activities: the monitoring example of selected sites in Calabria (southern Italy)

The major aim of our research is to assess the occurrence, within the serpentinites and serpentinite-derived soils located in the area of Sila Piccola (northern Calabria), of asbestiform minerals that could be potentially harmful for human health. At this purpose, nine serpentinite rock samples and three agricultural soils have been collected nearby two inhabited centres (Gimigliano and Conflenti towns) and characterized in detail by means of Polarized Light Microscopy (PLM), X-Ray Powder Diffractometry (XRPD), Scanning Electron Microscopy combined with Energy-Dispersive Spectrometry (SEM/EDS). Further characterization by Differential Scanning Calorimetry (DSC), Thermogravimetric (TG) and by μ-Raman spectroscopy (μ-R) have allowed the discrimination among the three serpentine polytypes. Serpentinites from Gimigliano mainly consist of lizardite, antigorite while chrysotile is the dominant asbestos phase in the samples from Conflenti. Moreover in both investigated sample groups asbestos tremolite- actinolite was also detected. Furthermore, high amounts of chrysotile and asbestos tremolite-actinolite were found in agricultural soils, suggesting that human activities can disturb and provoke the release of inhalable asbestos in the atmosphere, triggering thus mechanisms of hazardous exposition for population.

Gravity Modeling in Fold-Thrust Belts: An Example from the Peloritani Mountains, Southern Italy

Laboratory measurement of density values of representative crystalline rocks of the Peloritani Mountains, southern Italy, constrain the interpretation of gravity data collected along a profile from the Tyrrhenian Sea to the Mt. Etna volcano. These data contribute detail to crustal models of this section of the southern Italy orogenic system. Regional gravity modeling, constrained by new petrophysical data, yields the following conclusions: (1) existence of a southward-transported nappe belt of a more internal domain; (2) interpretation of the Taormina tectonic line as the morphological evidence of the thrusting of the Kabilo-Calabrian terrane over the Apenninian-Maghrebian units; (3) reconstruction of the Moho geometry along the geotransect, confirming the abrupt change in depth just starting from the Tyrrhenian coastal zone of Sicily.

Quartz preferred orientation in naturally deformed mylonitic rocks (Montalto shear zone–Italy): a comparison of results by different techniques, their advantages and limitations

Abstract In the geologic record, the quartz c-axis patterns are widely adopted in the investigation of crystallographic preferred orientations (CPO) of naturally deformed rocks. To this aim, in the present work, four different methods for measuring quartz c-axis orientations in naturally sheared rocks were applied and compared: the classical universal stage technique, the computer-integrated polarization microscopy method (CIP), the time-of-flight (TOF) neutron diffraction analysis , and the electron backscatter diffraction (EBSD). Microstructural analysis and CPO patterns of quartz, together with the ones obtained for feldspars and micas in mylonitic granitoid rocks, have been then considered to solve structural and geological questions related to the Montalto crustal scale shear zone (Calabria, southern Italy). Results obtained by applying the different techniques are discussed, and the advantages as well as limitations of each method are highlighted. Importantly, our findings suggest that patterns obtained by means of different techniques are quite similar. In particular, for such mylonites, a subsimple shear (40% simple shear vs 60% pure shear) by shape analysis of porphyroclasts was inferred. A general tendency of an asymmetric c-maximum near to the Z direction (normal to foliation) suggesting dominant basal slip, consistent with fabric patterns related to dynamically recrystallization under greenschist facies, is recognized. Rhombohedral slip was likely active as documented by pole figures of positive and negative rhombs (TOF), which reveal also potential mechanical Dauphiné twinning. Results showed that the most complete CPO characterization on deformed rocks is given by the TOF (from which also other quartz crystallographic axes can be obtained as well as various mineral phases may be investigated). However, this use is restricted by the fact that (a) there are very few TOF facilities around the world and (b) there is loss of any domainal reference, since TOF is a bulk type analysis. EBSD is a widely used technique, which allows an excellent microstructural control of the user covering a good amount of investigated grains. CIP and US are not expensive techniques with respect the other kind of investigations and even if they might be considered obsolete and/or time-consuming, they have the advantage to provide a fine and grain by grain “first round” inspection on the investigated rock fabric.