Rosaria Ciriminna

Polymers of Limonene Oxide and Carbon Dioxide: Polycarbonates of the Solar Economy

Limonene epoxide (1,2-limonene oxide) readily reacts with carbon dioxide inserted in a ring-opening copolymerization reaction and forms polycarbonates of exceptional chemical and physical properties. Both poly(limonene carbonate) and poly(limonene dicarbonate) can be synthesized using low-cost Zn or Al homogeneous catalysts. This study addresses selected relevant questions concerning the technical and economic feasibility of limonene and carbon dioxide polymers en route to the bioeconomy.

Solvent-Free Chemoselective Hydrogenation of Squalene to Squalane

Squalene is selectively and entirely converted into squalane over the spherical sol–gel-entrapped Pd catalyst SiliaCat Pd(0) under solvent-free and mild reaction conditions of 3 bar H2 and 70 °C. The catalyst was reused successfully in eight consecutive cycles, with palladium leaching values <2 ppm, opening the route to sustainable and less-expensive hydrogenation of phytosqualene with important sustainability consequences.

Antifouling and Photocatalytic Antibacterial Activity of the AquaSun Coating in Seawater and Related Media

Prolonged testing of the new xerogel photocatalytic coating AquaSun applied to a surface probe immersed in ocean water irradiated with simulated solar radiation shows excellent action against biofouling. Activated by moderate solar radiation, the organosilica film has also good antimicrobial properties. Considering the high stability, the environmental footprint, and the low cost of this sol–gel marine coating, the technology has significant potential toward replacing conventional antifouling and foul-release coatings with a single product of broad applicability.

Guidelines for Integrating Solar Energy in Sicily’s Buildings

Abstract Wise utilization of today’s new solar energy technologies provides buildings with new aesthetic value which is no longer in conflict with efficiency in solar energy conversion. We outline the criteria for incorporating solar photovoltaic (PV) and solar thermal (ST) technologies in the building design in Sicily’s built environment. Better education in solar energy and in solar architecture of architects and civil engineers, as well as better communication efforts of solar energy companies, will be instrumental to afford the long-awaited local and global boom in the adoption of building-integrated PVs.

Has the Time Come for Preprints in Chemistry? A Perspective onto a Meaningful Change

Chemistry is the last natural science discipline to embrace prepublishing, namely the publication of non-peer reviewed scientific articles on the internet. After a brief insight into the origins and the purpose of prepublishing in science, we conduct a concrete analysis of the concrete situation, aiming at providing an answer to several questions. Why the chemistry community has been late in embracing prepublishing? Is this in relation with the slow acceptance of open access publishing by the same community? Will prepublishing become a common habit also for chemistry

Has the Time Come for Preprints in Chemistry

Chemistry is among the last of the core natural sciences to embrace preprints, namely, the publication of non peer-reviewed scientific articles on the Internet. After a brief insight into the origins and the purpose of preprints in science, we conducted a concrete analysis of the concrete situation, aiming at providing an answer to several questions. Why has the chemistry community been late in embracing preprints? Is this in relation with the slow acceptance of open-access publishing by the same community? Will preprints become a common habit also for chemistry scholars?