Rosario García-Giménez

Biomonitoring of chemical elements in an urban environment using arboreal and bush plant species

PurposeThe aim of this work was to investigate the possibility of using several bush and arboreal plant species, usually present as ornamental plants in street and parks, as environmental indicators of pollution. This is a research paper that evaluates the real possibility of using a fast and low-cost procedure to evaluate the pollution degree through data obtained from plant species growing within an urban environment.MethodsLeaves of six different bush and arboreal species were collected from different parts of Madrid (Spain), ranging from highly polluted considered areas to medium and low contaminated ones. A total of 66 chemical elements, from major to minor and trace, were determined for every leaf sample by inductively coupled plasma-mass spectrometry. Statistical analyses were carried out using mainly box and whisker plots, linear discriminant analysis and cluster analysis.ResultsThe pollution by different elements of the studied areas of Madrid cannot be considered generally dangerous for human health. The level detected for the contaminants, in general, is similar or lower than other urban cities. Pb and V concentrations in plant samples tend to increase as traffic density increases. The different studied plant species showed a different capability of accumulation of certain elements. Cedrus deodara accumulates specially Ag, Hg, Mo and V; Cupressus sempervirens, Zr; Pinus pinea, As and Sb; Nerium oleander Ni, Pb, Mo and Se; Ligustrum ovalifolium, Sc and V; and Pittosporum tobira, Ag, Cd, Rb and Sc.ConclusionsThe leaves and needles collected from bush and arboreal plants common in this city have demonstrated to be useful to evaluate the level of pollution not only through the chemical analysis but also through the recognition of the visual injury symptoms. The application of multivariate statistical techniques combined with determining of element concentration and correlation analysis has been proved to be an effective tool for reach the objectives of the present work. This allows visualising quickly the damages and leading the sampling through the points of high-level pollution, saving analysis, time and money.

Thermodynamic Evaluation of Pozzolanic Reactions between Activated Pozzolan Mix of Clay Waste/Fly Ash and Calcium Hydroxide

AbstractThe mixture of activated paper sludge and fly ash can successfully be used as pozzolans for the manufacture of a more ecological portland cement. The saturation indexes and the mineral stab...

Aeolian sands and soils of a Wetland Biosphere Reserve: The Tablas de Daimiel

Three soil profiles were characterized from a sandy area situated in a transitional zone in the “Tablas de Daimiel” UNESCO wetland biosphere reserve (TDNP) in the Mancha Plain (Central Spain). The original thickness of the soil layer in this area was as much as 100 cm, but the combined effect of unbalanced cultivation (including irrigation) and an increasingly dry climate has partially eroded their natural properties, almost leading to a desertification process. The main properties of these soils, classified as Xeropsamments (Soil Survey Staff 2006) or Arenosols (IUSS Working Group WRB 2006), are the dominance of sand in the soil matrix, its basic character, and low soil organic matter and carbonate contents. Scanning electron microscopy of the quartz grain surfaces indicated that the superficial textureswere commonly well preserved and characteristic of specific conditions of aeolian formation. Exoscopy revealed a mixture of sub-angular and rounded quartz morphotypes withwell-preserved mechanical impacts on the grain surfaces. These percussion effects are characteristic of aeolian processes and confirmed that mechanical actions were more significant than chemical processes in their pedogenesis.This micromorphological study of the textural sands in the transitional zone of the TDNP revealed that the (red) sands were transported to this area by wind, probably from material of degraded red soils, and deposited on soil horizons previously developed over marls and limestones. The relict character of these materials and specially their susceptibility to degradation should be considered as a priority argument to preserve this area and introduce management measurements to avoid soil erosion.