Rosenani Abu Bakar

Characterization and Feasibility Assessment of Recycled Paper Mill Sludges for Land Application in Relation to the Environment

The disposal of industrial paper mill sludge waste is a big issue and has a great importance all over the world. A study was conducted to determine the chemical properties of recycled paper mill sludge (RPMS) and assess its possibilities for land application. RPMS samples were collected from six different paper mills in Malaysia and analyzed for physical and chemical properties, heavy metals, polycyclic aromatic hydrocarbons, 13C-NMR spectra and for the presence of dioxins/furans. The RPMS was dewatered, sticky with a strong odour, an average moisture of 65.08%, pH 7.09, cation exchange capacity (CEC) 14.43 cmol (+) kg–1, N 1.45, P 0.18, K 0.12, Ca 0.82, Mg 0.73, Na 0.76 and Al, 1.38%. The polycyclic aromatic hydrocarbons (PAHs) and heavy metals levels were below the standard Class 2 limits. The dioxin and furan were in below the standard concentration of Class 1. The most prominent peak in the 13C-NMR spectra of RPMS was centered at 31 ppm, proving the presence of methylene (-CH2) groups in long aliphatic chains, with lipids and proteins. The signal at 89 ppm and highly shielded shoulder at 83 ppm were due to presence of cellulose carbon C-4, and the peak at 63 and 65 ppm was due to the cellulose carbon spectrum. The RPMS therefore contains significant amount of nutrients with safe levels of heavy metals and PAHs for environment and can be used as a fertilizer and soil amendment for land application.

Application of raw and composted Recycled Paper Mill Sludge on the growth of Khaya senegalensis and their effects on soil nutrients and heavy metals.

The paper industry performs an essential role in the global economy of the world. A study was conducted on the paper mill sludge that is applied on the Khaya senegalensis for 4 crop cycle for 1 year growth at glasshouse, Faculty of Agriculture, Universiti Putra Malaysia. Paper Mill Sludge (PMS) and composted Recycled Paper Mill Sludge (RPMS) was used with nitrogen (0, 150, 300 and 600 kg ha-1) at the ratio of 1:1 (Recycled Paper Mill Sludge (RPMS): Empty Fruit Bunch (EFB). The growth parameters were measured twice a month for 6 months. Plant nutrients and heavy metal uptake were determined. The paper mill sludge has the potential to be a supplementary N fertilizer as well as a soil amendment. The application of RPMS with N, significantly contributed to the improvement in plant growth parameters such as plant height (193 cm), basal diameter (27.00 mm), total plant biomass and improved soil physical and chemical properties. Total concentrations of heavy metals in soils were below the critical values. Hence, the paper mill sludge can be successfully used as soil amendment in acidic soil without any serious threat. The use of paper mill sludge for soil fertility, shows improvement in land application and signifies a unique opportunity to recycle sludge back to the land to alleviate the potential waste management problem.

In-situ immobilization of lead using different source of phosphate amendments for the organic production of misai kucing (Orthosiphon stamineus)

Sustainable organic herbal production requires utilization of bio-waste materials as plant nutrient sources due to its economical aspect and would ensure continuous productivity. The usage of organic wastes in organic farming system (OFS) as fertilizers and soil amendments should be monitored as the accumulation of heavy metals has been reported in several studies. Glasshouse study has been conducted to assess the effectiveness of Pb immobilization due to chicken manure application using different sources of phosphate materials; bone meal (BM), Egyptian rock phosphate (ERP) and triple super phosphate (TSP). From the fractionation of glasshouse study, the percentage of exchangeable fraction of Pb was reduced with application of P-amendments with the highest of 20.2% of reduction recorded for 2 t/ha application of TSP. This is followed by reduction in exchangeable fraction for others treatments: 2 t/ha of BM (4.1%), 4 t/ha of BM (5.1%), 1 t/ha of ERP (8.1%) and 2 t/ha of ERP at 17.6%. These treatments were recorded as being able to stabilize the Pb as indicated in the percentage reduction of phyto available pools into a more stable form of residual pool.