Rowel Go

3 W Continuous-Wave Room Temperature Single-Facet Emission From Quantum Cascade Lasers Based On Nonresonant Extraction Design Approach

A strain-balanced, InP-based quantum cascade laser structure, designed for light emission at 4.6 μm using a new nonresonant extraction design approach, was grown by molecular beam epitaxy. Removal of the restrictive two-phonon resonant condition, currently used in most structure designs, allows simultaneous optimization of several design parameters influencing laser performance. Following the growth, the structure was processed in buried heterostructure. Maximum single-ended continuous-wave optical power of 3 W was obtained at 293 K for devices with stripe dimensions of 5 mm×11.6 μm. Corresponding maximum wallplug efficiency and threshold current density were measured to be 12.7% and 0.86 kA/cm2.

1.6W high wall plug efficiency, continuous-wave room temperature quantum cascade laser emitting at 4.6μm

A strain-balanced, InP-based quantum cascade laser structure designed for light emission at 4.6μm was grown by metal-organic chemical vapor deposition. A maximum total optical power of 1.6W was obtained in continuous-wave mode at 300K for uncoated devices processed in buried heterostructure geometry with stripe dimensions of 5mm by 9.5μm. Corresponding maximum wall plug efficiency and threshold current density were measured to be 8.8% and 1.05kA∕cm2, respectively. Fully hermetically packaged laser of identical dimensions produced in excess of 1.5W under the same conditions.

High-sensitivity detection of TNT

We report high-sensitivity detection of 2,4,6-trinitrotoluene (TNT) by using laser photoacoustic spectroscopy where the laser radiation is obtained from a continuous-wave room temperature high-power quantum cascade laser in an external grating cavity geometry. The external grating cavity quantum cascade laser is continuously tunable over ≈400 nm around 7.3 μm and produces a maximum continuous-wave power of ≈200 mW. The IR spectroscopic signature of TNT is sufficiently different from that of nitroglycerine so that unambiguous detection of TNT without false positives from traces of nitroglycerine is possible. We also report the results of spectroscopy of acetylene in the 7.3-μm region to demonstrate continuous tunability of the IR source.

High power thermoelectrically cooled and uncooled quantum cascade lasers with optimized reflectivity facet coatings

We present a method of preserving the device wall-plug efficiency by adjusting mirror losses with facet coatings for longer cavity quantum cascade lasers. An experimental study of output power and wall-plug efficiency as functions of mirror losses was performed by varying the front facet coating reflectivity with a high-reflectivity-coated rear facet. The use of optimized reflectivity coatings on 7-mm-long chips resulted in continuous-wave output power of 2.9 W at 293 K for thermoelectrically cooled devices mounted on AlN submounts and average and continuous-wave output power in excess of 1 W for uncooled devices emitting at 4.6 m.

High-sensitivity detection of triacetone triperoxide (TATP) and its precursor acetone

Triacetone triperoxide (C(9)H(18)O(6), molecular mass of 222.24 g/mol) (TATP) is a powerful explosive that is easy to synthesize using commonly available household chemicals, acetone, and hydrogen peroxide 1 2. Because of the simplicity of its synthesis, TATP is often the explosive of choice for terrorists, including suicide bombers. For providing safety to the population, early detection of TATP and isolation of such individuals are essential. We report unambiguous, high-sensitivity detection of TATP and its precursor, acetone, using room-temperature quantum cascade laser photoacoustic spectroscopy (QCL-PAS). The available sensitivity is such that TATP, carried on a person (at a nominal body temperature of 37 degrees C), should be detectable at some distance. The combination of demonstrated detection of TATP and acetone should be ideal for screening at airports and other public places for providing increased public safety.

Optically multiplexed multi-gas detection using quantum cascade laser photoacoustic spectroscopy.

We report high-throughput, nondispersive optical multiplexing of laser beams using a scanning galvanometer. We have utilized this technique for multispecies trace-gas detection using multiple quantum cascade laser photoacoustic spectroscopy. We demonstrate switching from one laser to another in less than 1 s, a performance level needed for a comprehensive multispecies sensor, and a high signal-to-noise ratio detection of five gaseous components, NH(3), NO(2), dimethyl methyl phosphonate (DMMP, a simulant for nerve agents), acetone, and ethylene glycol, in a room air gas mixture containing approximately 3 ppb of NH(3), approximately 8 ppb of NO(2), approximately 20 ppb of DMMP, approximately 30 ppb of acetone, and approximately 40 ppb of ethylene glycol.

High-performance continuous-wave room temperature 4.0-μm quantum cascade lasers with single-facet optical emission exceeding 2 W

A strain-balanced, AlInAs/InGaAs/InP quantum cascade laser structure, designed for light emission at 4.0 μm using nonresonant extraction design approach, was grown by molecular beam epitaxy. Laser devices were processed in buried heterostructure geometry. An air-cooled laser system incorporating a 10-mm × 11.5-μm laser with antireflection-coated front facet and high-reflection-coated back facet delivered over 2 W of single-ended optical power in a collimated beam. Maximum continuous-wave room temperature wall plug efficiency of 5.0% was demonstrated for a high-reflection-coated 3.65-mm × 8.7-μm laser mounted on an aluminum nitride submount.

Tapered 4.7 μm quantum cascade lasers with highly strained active region composition delivering over 4.5 watts of continuous wave optical power

A strain-balanced, Al0.7In0.22As/In0.72Ga0.28As/InP quantum cascade laser structure, designed for light emission at 4.7µm using the non-resonant extraction design approach, was grown by molecular beam epitaxy. Laser devices were processed in tapered buried heterostructure geometry and then mounted on AlN/SiC composite submounts using hard solder. A 10 mm long laser with 7.5µm-wide central section tapered up to 20µm at laser facets generated over 4.5W of single-ended CW/RT optical power at 283K. Maximum wallplug efficiency of 16.3% for this laser was reached at 4W level. Reliability of over 2,000h has been demonstrated for an air-cooled system delivering optical power of 3W in a collimated beam with overall system efficiency exceeding 10%.

External cavity quantum cascade lasers with ultra rapid acousto-optic tuning

We report operation of tunable external cavity quantum cascade lasers with emission wavelength controlled by an acousto-optic modulator (AOM). A long-wave infrared quantum cascade laser wavelength tuned from ∼8.5 μm to ∼9.8 μm when the AOM frequency was changed from ∼41MHz to ∼49 MHz. The laser delivered over 350 mW of average power at the center of the tuning curve in a linewidth of ∼4.7 cm−1. Measured wavelength switching time between any two wavelengths within the tuning range of the QCL was less than 1 μs. Spectral measurements of infrared absorption features of Freon demonstrated a capability of obtaining complete spectral data in less than 20 μs.

Long-Wave IR Quantum Cascade Lasers for emission in the λ = 8-12μm spectral region

In this article we review a selection of recent results on long-wave quantum cascade lasers both for high power and for single-mode emission. Both MBE-grown and MOCVD-grown devices are examined and compared. Currently, LWIR QC lasers exhibit output powers in the Watt-level range and up to double-digit conversion efficiencies in the best cases.