Rubén López-Doncel

Weathering of volcanic tuff rocks caused by moisture expansion

Moisture expansion in natural building stones is considered one of the most important factors affecting their weathering and deterioration. The processes that may be responsible for the expansion under determinate relative humidity (hygric dilatation) and water-saturated conditions (hydric dilatation) are generally attributed to the presence of swellable clay minerals. In contrast to this assumption, our investigations show that moisture expansion also takes place in volcanic tuff building stones almost free from clay minerals. To provide a deeper understanding of the processes, swelling and deterioration were performed on 14 volcanic tuffs used as important building stones of different ages, compositions and weathering stages from Mexico, Germany and Hungary. The investigations undertaken include extensive chemical, petrophysical and fabric analyses. The samples show a wide range of effective porosity, microporosity, capillary water absorption, moisture expansion, and CEC values. High moisture expansion does not seem to depend on clay mineral content alone. We also observed that there is no significant effect on dilatation if clay minerals are present but only form a thin coat on the outer shell of bigger pores. Moreover, we identified a correlation between microporosity, average pore radius and moisture expansion. The investigations highlight the fact that moisture expansion cannot only be attributed to swellable clay minerals, and suggest that the presence and accumulation of micropores and their average radius and distribution play an important role for non-clay associated swelling intensity, which can most probably be attributed to the disjoining pressure.

Moisture expansion associated to secondary porosity: an example of the Loseros Tuff of Guanajuato, Mexico

The old mining city of Guanajuato in middle Mexico preserves one of the most important historical legacies in colonial buildings, the UNESCO declared the city World Heritage Site in 1988. Practically all the colonial constructions were built with natural stones from the neighbourhood, of which stands a greenish to reddish vulcanite, called Loseros Tuff. Although the Loseros Tuff is widely used in historical buildings in the city. It shows significant deterioration and weathering effects, principally in the parts where the tuff shows a coarse grain size. The petrographic, petrophysical, mineralogical and geochemical properties of the Loseros Tuff were analysed in order to determine the causes, effects, behaviour and response to deterioration of this volcanic rock. The results of the investigations suggest that in addition to the parameters like the grain size and the porosity properties, the pore radii distribution is decisive for the effectiveness of porosity and the water transport into the rock. It is recognized that once the liquid water invades the rock the dissolution of the matrix occurs, which is accompanied by a sudden moisture expansion favoured by the newly formed secondary porosity and the high content of expandable clay minerals.

In situ and nondestructive characterization of mechanical properties of heritage stone masonry

The necessity of conserving and preserving the heritage is nowadays a developing study line for several researchers. From a civil engineering perspective, one of the most important issues for the conservation of historical buildings is to ensure the structural stability. For this purpose, it is necessary to determine the mechanical properties of the ancient construction materials. However, these structures cannot be evaluated by destructive tests due to politics and restrictions for preserving the heritage built. As a consequence, new methods that do not put in risk the integrity of the materials and the structure are becoming useful tools for researchers who work on structural engineering of heritage buildings. This paper presents a nondestructive method (NDM) that has been used to characterize the mechanical properties of different constructive systems of the San Antonio de Padua Temple, which is a religious icon in Aguascalientes, Mexico. This method includes the measuring of seismic waves’ travel time in order to obtain shear and compressional velocity waves. Results show that with this method mechanical properties of masonry can be obtained such as Young’s modulus, Poisson ratio and bulk density, which are needed for the structural analysis using numerical simulation models.

Deterioro de las rocas en los muros de mampostería de la Catedral de Aguascalientes, México

Se utilizaron tobas volcanicas de alta porosidad para construir los muros de mamposteria de la Catedral de la ciudad de Aguascalientes, en el centro de mexico. En la actualidad, la mamposteria de piedra muestra evidencias de deterioro, principalmente en la parte inferior de las paredes exteriores debido al efecto de la humedad y la contaminacion ambiental que esta causando danos tales como microdescamacion, descamacion y patina. Se realizaron estudios petrologicos que incluyeron difractometria de rayos X y analisis petrofisico como determinaciones de porosidad, densidad y densidad aperente, asi como un levantamiento de danos de piedra para obtener informacion sobre los tipos de rocas utilizados para elaborar los muros de mamposteria, sus caracteristicas petrologicas y danos fisicos. No se desarrollaron pruebas compresionales debido a la falta de muestras de piedra pero hay datos reportados para estas piedras por otros autores. Los resultados permiten identificar el tipo de piedra mas propenso a deteriorarse, el mecanismo de deterioro de la piedra, y los factores que aceleran el deterioro. Aunque los resultados tienen un uso pragmatico para las obras de restauracion de la Catedral de la ciudad de Aguascalientes, la metodologia aplicada podria ser utilizada para determinar la vulnerabilidad de las rocas a deteriorarse en edificios patrimoniales en cualquier lugar del exterior

Assessment of the acid drainage neutralization capacity and the toxic metals lixiviation of tailing from Guanajuato mining district, Mexico

In Mexico, many environmental problems are generated by large mining activities taking place in several mining districts. These mining activities produce great quantities of residues; large majorities of these have high sulfur content, which could generate acid drainage due to their interaction with the oxygen in the environment. The study area was located in the Mining District of Guanajuato, Mexico with abandoned tailings generated mainly by the gold and silver production. Two areas, called as Monte de San Nicolás (SN) and Peregrina (P) were selected for this study. The results study shows that there was no risk of production of acid drainage, since these tailings contained high amount of carbonates, which neutralized the generation of acidity and consequently decreased the possibility of leaching of some elements. However, not all elements leach in acid pH, as arsenic bound to oxyhydroxides, which is in a basic environment and its increased release by increasing the pH.

Endocranial morphology of the extinct Antillean shrew Nesophontes (Lipotyphla: Nesophontidae) from natural and digital endocasts of Cuban taxa

This paper documents and describes fossil microbial structures inferred to be of algal/bacterial origin in the Upper Cretaceous Agua Nueva Formation in the Xilitla area (San Luis Potosi, Mexico), located in the southern part of the Tampico-Misantla basin. The sequence consists of alternating decimeter-thick beds of limestone with occasional brown shale and green bentonite layers. The limeston also include intermittent beds of black chert. The sedimentary succession shows two calcareous facies: 1) dark laminated limestones containing fossil remains of holosteans, teleosteans and shark teeth, as well as lenticular layers of sedimentary pyrite, and high content of organic matter (Corg 1 ‒ 8 wt%); and 2) gray, non-laminated, bioturbated limestones with low content of organic matter (Corg < 1.0 wt%). Petrographic and scanning electron microscope analyses of the laminated limestone reveal a micritic matrix with sub-parallel wavy lamination, continuous and discontinuous folded laminae with shreds of organic matter, as well as different kinds of filaments, coated grains and planktonic foraminifera. On the other hand, the non-laminated, bioturbated limestone comprises infrequent filaments and pyrite. Both textures and biomorphic structures are very similar to those previously described for ancient and recent sediments representative of microbial origin. Furthermore, the occurrence of filaments embedded in the organic-matter-rich laminae suggests in situ production related to benthic microbial activity. Concurrence of lamination due to the absence of bioturbation, pervasive framboidal pyrite, and the high concentration of organic matter in the laminated limestones are consistent with persistent dysoxic/anoxic conditions, whereas the bioturbated limestones might represent recurrent relatively well-oxygenated episodes. The presence of the planktonic foraminifera Rotalipora cushmani concomitant with Inoceramus labiatus indicates a time interval from the Late Cenomanian to the Earliest Turonian for the Agua Nueva Formation at Xilitla, thus indicating that this interval of intermittent severe oxygen deficient conditions is coeval with the global Oceanic Anoxic