S. Falconi

Incommensurate high-pressure and high-temperature structures in group VI elements

In this paper we provide a review of the revolution that has taken place over the past few years in our ability to produce and exploit ultra-bright, ultra-short pulses of X-radiation. For some time, nanosecond and picosecond optical lasers have been used to generate K-shell line radiation to interrogate rapid structural changes in matter. A good example of such work is the recent observation of the shock-induced alpha-epsilon transition in iron. [1] However, relatively small femtosecond lasers are now routinely used to produce bursts of X-rays with pulse-lengths of a few hundred femtoseconds. Such systems can be used to study rapid changes in materials -for example the atomic motion in both coherent acoustic and optical phonons have been directly followed.[2] Sub-bunch-length temporal resolution can also be achieved on third generation sources, either by use of streak-cameras to get to picosecond timescales, [3] or by laser-slicing to achieve 100-fsec resolution. [4] Within the next few years hardX-ray free-electron lasers (FELs) will come on line. These systems, with X-ray pulse-lengths of order 100-fsec, will have spectral brightnesses ten orders of magnitude greater than any extant synchrotron. [5] They will be fully spatially coherent, and temporal coherence can easily be achieved by spectral filtering. Such systems will have many unique applications, and considerable effort is already being devoted to designing experiments to enable diffraction from single bio-molecules.[6] An ability to obtain in a direct manner structural information from molecules that do not crystallize clearly has wide-ranging applications. The non-lasing precursor to such sources the short pulse photon source at Stanford has already produced remarkable results, with the shortest X-ray bursts yet produced being used to follow non-thermal melting in laser-irradiated semiconductors.[7] We also note that once the pulse lengths of the X-rays, and/or the time-scales of the phenomena of interest, start to become comparable with an extinction-depth traversal time, the diffraction process itself becomes time-dependent.[8]

X-ray diffraction study in liquid Cs up to 9.8 GPa

We describe an x-ray diffraction study of liquid Cs at high pressure and temperature conducted in order to characterize the structural changes associated with the complex melting curve and phase transitions observed in the solid phases. At 3.9 GPa we observe a discontinuity in the density of the liquid accompanied by a decrease in the coordination number from about 12 to 8, which marks a change to a nonsimple liquid. The specific volume of liquid Cs, combined with structural analysis of the diffraction data, strongly suggest the existence of dsp(3) electronic hybridization above 3.9 GPa, similar to that reported on compression in the crystalline phase.