S. Lee Barbour

Controls on the spatial distribution of soil moisture and solute transport in a sloping reclamation cover

A detailed field study was conducted to map the spatial distribution of soil moisture and salt transport within a sloping clay-rich reclamation cover overlying a saline-sodic shale overburden landform. The soil moisture data suggest that: lower-slope positions are wetter in spring due to the down-slope movement of surface run-off; infiltration occurs via preferential flow paths while the ground is frozen; and, interflow occurs along the cover–shale surface when the ground thaws. Soil moisture conditions also remain wetter in lower-slope positions throughout the summer and fall. Salt transport from the shale into the overlying cover is affected predominantly by soil moisture conditions and lateral groundwater flux. Quasi one-dimensional modelling of in situ profiles of pore-water Na+ concentration demonstrate that: (i) increased soil moisture conditions in lower-slope positions accelerate salt transport into the cover through diffusion; (ii) snow melt infiltration water bypasses the soil matrix higher in t...

Reservoirs of Selenium in Coal Waste Rock: Elk Valley, British Columbia, Canada.

Selenium (Se) reservoirs in coal waste rock from the Elk Valley, southeastern British Columbia, the location of Canadas major steelmaking coal mines, were characterized and quantified by analyzing samples collected from the parent rock, freshly blasted waste rock (less than 10 days old), and aged waste rock (deposited between 1982 and 2012). Se is present throughout the waste rock dumps at a mean digestible (SeD) concentration of 3.12 mg/kg. Microprobe analyses show that Se is associated with the primary minerals sphalerite, pyrite, barite, and chalcopyrite and secondary Fe oxyhydroxides. Selenium K-edge X-ray absorption near-edge spectroscopy analyses indicate that, on average, 21% of Se is present as selenide (Se(2-)) in pyrite and sphalerite, 19% of Se is present as selenite (Se(4+)) in barite, 21% of Se is present as exchangeable Fe oxyhydroxide and clay-adsorbed Se(4+), and 39% of Se is present as organoselenium associated with coaly matter. The dominant source minerals for aqueous-phase Se are pyrite and sphalerite. Secondary Fe oxyhydroxide sequesters, on average, 37% of Se released by pyrite oxidation. Measured long-term Se fluxes from a rock drain at the base of a waste dump suggest that at least 20% of Se(2-)-bearing sulfides were oxidized and released from that dump over the past 30 year period; however, the Se mass lost was not evident in SeD analyses.

Evolution of the Hydraulic Conductivity of Reclamation Covers over Sodic/Saline Mining Overburden

The evolution of the field saturated hydraulic conductivity of four covers located on a reclaimed saline-sodic shale overburden from oil sands mining is presented. Three covers consisted of a surface layer of peat/glacial topsoil over a mineral, soil. and one cover was a single layer of mixed peat and mineral soil. Measurements of the field saturated hydraulic conductivity of the cover and shale materials were made with a Guelph permeameter between 2000 and 2004. The hydraulic conductivity of the cover materials in the multilayered covers increased by one to two orders of magnitude over the first few monitoring seasons. The hydraulic conductivity of the single-layer cover system, which was placed three years before the multilayered covers, marginally increased from 2000 to 2002 and then remained relatively unchanged. The hydraulic conductivity of the shale underlying all four covers increased approximately one order of magnitude. Soil temperature measurements indicated that one freeze/thaw cycle occurred ...

In situ experiment to determine advective-diffusive controls on solute transport in a clay-rich aquitard

Solute transport in clay-rich aquitards is characterized as molecular diffusion- or advection-dominated based on the Péclet number (P(e)). However, few field-based measurements of the coefficient of molecular diffusion (D(e)) exist, and none with a range of advection- or diffusion-dominated conditions in the same aquitard. In this long-term field experiment, standing water in a recovering well was spiked with deuterium ((2)H), then water-level recovery and δ(2)H values were monitored as the well returned to static conditions over 1054 days. After a second (2)H spike, water levels and δ(2)H values were monitored to day 1644 while under near static conditions. Modeling of the second spike was used to define the D(e) of (2)H as (3-4)× 10(-10)m(2)s(-1) for an accessible porosity of 0.31. Reservoir concentrations from the initial spike were modeled to define the transition from advection- to diffusion-dominated transport. This occurred after 200 days, consistent with a transition in P(e) from <1 to >1 when the length term is taken as the radial extent of the tracer plume (normalized concentration <0.05). This study verifies plume extent as the characteristic length term in the calculation of P(e) and demonstrates the transition from advection- to diffusion-dominated transport as the value of P(e) decreases below unity.

Characterization of physical mass transport through oil sands fluid fine tailings in an end pit lake: a multi-tracer study

Soft tailings pose substantial challenges for mine reclamation due to their high void ratios and low shear strengths, particularly for conventional terrestrial reclamation practices. Oil sands mine operators have proposed the development of end pit lakes to contain the soft tailings, called fluid fine tailings (FFT), generated when bitumen is removed from oil sands ore. End pit lakes would be constructed within mined-out pits with FFT placed below the lake water. However, the feasibility of isolating the underlying FFT has yet to be fully evaluated. Chemical constituents of interest may move from the FFT into the lake water via two key processes: (1) advective-diffusive mass transport with upward pore water flow caused by settling of the FFT; and (2) mixing created by wind events or unstable density profiles through the lake water and upper portion of the FFT. In 2013 and 2014, temperature and stable isotopes of water profiles were measured through the FFT and lake water in the first end pit lake developed by Syncrude Canada Ltd. Numerical modelling was undertaken to simulate these profiles to identify the key mechanisms controlling conservative mass transport in the FFT. Shallow mixing of the upper 1.1 m of FFT with lake water was required to explain the observed temperature and isotopic profiles. Following mixing, the re-establishment of both the temperature and isotope profiles required an upward advective flux of approximately 1.5 m/year, consistent with average FFT settling rates measured at the study site. These findings provide important insight on the ability to sequester soft tailings in an end pit lake, and offer a foundation for future research on the development of end pit lakes as an oil sands reclamation strategy.

Geochemical and mineralogical characterization of sulfur and iron in coal waste rock, Elk Valley, British Columbia, Canada

Exposure of coal waste rock to atmospheric oxygen can result in the oxidation of sulfide minerals and the release of sulfate (SO42-) and associated trace elements (e.g., Se, As, Cd, and Zn) to groundwaters and surface waters. Similarly, reduced iron minerals such as siderite, ankerite, and the sulfide, pyrite, present in the waste rock can also undergo oxidation, resulting in the formation of iron oxyhydroxides that can adsorb trace elements released from the oxidation of the sulfide minerals. Characterization and quantification of the distribution of sulfide and iron minerals, their oxidation products, as well as leaching rates are critical to assessing present-day and future impacts of SO42- and associated trace elements on receiving waters. Synchrotron-based X-ray absorption near edge spectroscopic analysis of coal waste rock samples from the Elk Valley, British Columbia showed Fe present as pyrite (mean 6.0%), siderite (mean 44.3%), goethite (mean 35.4%), and lepidocrocite (mean 14.3%) with S present as sulfide (mean 26.9%), organic S (mean 58.7%), and SO42- (mean 14.4%). Squeezed porewater samples from dump solids yielded mean concentrations of 0.28mg/L Fe and 1246mg/L SO42-. Geochemical modeling showed the porewaters in the dumps to be supersaturated with respect to Fe oxyhydroxides and undersaturated with respect to gypsum, consistent with solids analyses. Coupling Fe and S mineralogical data with long-term water quality and quantity measurements from the base of one dump suggest about 10% of the sulfides (which represent 2% of total S) in the dump were oxidized over the past 30years. The S from these oxidized sulfides was released to the receiving surface water as SO42- and the majority of the Fe precipitated as secondary Fe oxyhydroxides (only 3.0×10-5% of the Fe was released to the receiving waters over the past 30years). Although the data suggest that the leaching of SO42- from the waste rock dump could continue for about 300years, assuming no change in the rate of oxidation of sulfides, SO42- is currently not a concern in receiving surface waters as the concentration levels are below regulatory limits.

Fate and transport of dissolved methane and ethane in cretaceous shales of the Williston Basin, Canada

Baseline characteristics of dissolved methane (CH4) and ethane (C2H6) and their stable isotopes in thick, low hydraulic conductivity, Cretaceous shales were determined using high-resolution core profiling at four sites in the Williston Basin (WB), Canada. Positive correlations with the conservative natural tracer Cl- reflected a lack of measureable production or consumption of gases in the shale to the depth investigated (150 m below ground, BG) and suggest CH4 and C2H6 concentrations near the interface with overlying Quaternary sediments are controlled by lateral migration and dilution in permeable zones. Curvilinear increasing concentrations with depth in the shale at all sites coupled with 1-D solute transport modelling suggest long-term (over millions of years) upward diffusion of CH4 and C2H6 from deeper WB sources, likely the Second White Speckled Shale Formation (SWSS; ∼790 m BG). δ13C-CH4 profiles in the shale are consistent with upward diffusional fractionation of isotopes from the SWSS. Distinct CH4 and C2H6 isotope values of gases in the shales vs. 13C-enriched thermogenic isotopic signatures of CH4 and C2H6 in deeper oil-producing WB intervals could be used to identify fugitive gases originating deeper in the Basin. This article is protected by copyright. All rights reserved.

Measuring Solid Percentage of Oil Sands Mature Fine Tailings Using the Dual Probe Heat Pulse Method

The reclamation of mature fine tailings (MFT) is a critical challenge for the oil sands industry in western Canada, and a nonradioactive, automated, and inexpensive method to monitor the MFT solidification is needed. The objective of this paper is to evaluate the feasibility of a dual-probe heat pulse (DPHP) method to measure MFT solid percentage. Dual-probe heat pulse measurements were performed on three MFT samples, each at various solid percentages. A linear relationship ( = 0.9495 + 0.0558) was established between the DPHP-measured solid percentage () and that of oven-dry method (). Six additional MFT samples were collected and measured to validate the DPHP method. The specific heats of the six MFT solids were measured independently using a modulated differential scanning calorimetry method, and the sensitivity of DPHP-measured MFT solid percentage to the specific heat of MFT solids was evaluated. The result shows that the DPHP method can be used to accurately measure MFT solid percentages, and the accuracy can be further improved if the specific heat of the MFT solids is measured independently.

Evaluating the Effect of Fiber Reinforcement on the Anisotropic Undrained Stiffness and Strength of Peat

AbstractThis paper presents the results of an investigation into the role of peat fibers in the development of anisotropic stiffness and strength within peat samples taken from below three Canadian National Railway embankments across Canada. These sites include two from northern Alberta on the Edson and Lac-La-Biche subdivisions and one from the Levis subdivision in southern Quebec. The peat samples were collected in Shelby tubes and were subjected to a program of consolidated undrained triaxial testing. These samples represented a wide variation in fiber content and degree of humification. The measured pore-pressure response during undrained loading indicated that the peat samples were undergoing an anisotropic elastic response to loading. This pore-pressure response was similar in the peat from all three sites, with an anisotropic pore-pressure parameter, a, of approximately 0.3. The stiffness and strength of the different peats were also similar, with an elastic modulus of approximately 1.7–2.2 MPa and...

Long-term monitoring and modelling of a reclaimed watershed cover on oil sands tailings

Tailings sand associated with oil sands mining contains saline process-affected pore-water which can have a detrimental impact on the performance of reclamation covers. A reclamation cover site, located at the Syncrude Canada Ltd.s South West Sand Storage facility (SWSS), consisted of 45 cm of cover soil over tailings sand. The site was instrumented in 2001 to measure real-time local meteorology, soil temperature, water content and suction over an eight-year period. A one-dimensional numerical model (VADOSE/W) was created to calculate moisture fluxes through the cover/tailings interface over a long-term period (51 years). A pore-water volume method was then used to evaluate the potential risk of salt transport into the overlying cover soil. The long-term modelling demonstrated that the cumulative water flux across the cover/tailings interface is downward, towards the water table, when the water table is deeper than 3 m below the cover/tailings interface; although the water flux across this interface in any single year may be upward. The risk of cover salinisation due to the upward movement of saline tailings pore-water from the underlying water table under these conditions was low (less than one occurrence in over 50 years).