S. Miraldo

Cost-efficient one-part alkali-activated mortars with low global warming potential for floor heating systems applications

Increasing building energy efficiency is one the most cost-effective ways to reduce emissions. The use of thermal insulation materials mitigates heat loss in buildings, therefore minimising heat energy needs. In recent years, several papers were published on the subject of foam alkali-activated cements with enhanced thermal conductivity. However, on those papers cost analysis was strangely avoided. This paper presents experimental results on one-part alkali-activated cements. It also includes global warming potential assessment and cost analysis. Foam one-part alkali-activated cements cost simulations considering two carbon dioxide social costs scenarios are also included. The results show that one-part alkali-activated cements mixtures based on 26%OPC + 58.3%FA + 8%CS + 7.7%CH and 3.5% hydrogen peroxide constitute a promising cost-efficient (67 euro/m3), thermal insulation solution for floor heating systems. This mixture presents a low global warming potential of 443 KgCO2eq/m3. The results confirm that in both carbon dioxide social cost scenarios the mixture 26 OPC + 58.3 FA + 8 CS + 7.7 CH with 3.5% hydrogen peroxide foaming agent is still the most cost efficient.

Compressive strength, microstructure and hydration products of hybrid alkaline cements

Ordinary Portland cement (OPC) is the dominant binder in the construction industry with a global production that currently reaches a total of 3 Gt per year. As a consequence, the cement industrys contribution to the total worldwide CO2 emissions is of about 7% of the total emissions. Publications on the field of alkali-activated binders (also termed geopolymers), state that this new material is, potentially, likely to fbecome an alternative to Portland cement. However, recent LCA studies show that the environmental performance of alkali-activated binders depends, to great extent, of their composition. Also, researchers report that these binders can be produced in a more eco-efficient manner if the use of sodium silicate is avoided. This is due to the fact that the referred component is associated to a high carbon footprint. Besides, most alkali-activated cements suffer from severe efflorescence, a reaction originated by the fact that the alkaline and/or soluble silicates that are added during processing cannot be totally consumed. This paper presents experimental results on hybrid alkaline cements. The compressive strength results and the efflorescence observations show that some of the new mixes already exhibit a promising performance.

Nanoparticles for high performance concrete (HPC)

Abstract: According to the 2011 ERMCO statistics, only 11% of the production of ready-mixed concrete relates to the high performance concrete (HPC) target. This percentage has remained unchanged since at least 2001 and appears a strange choice on the part of the construction industry, as HPC offers several advantages over normal-strength concrete, specifically those of high strength and durability. It allows for concrete structures requiring less steel reinforcement and offers a longer serviceable life, both of which are crucial issues in the eco-efficiency of construction materials. Despite the growing importance of nanotechnology, investigations into the incorporation of nanoparticles into concrete are rare (100 out of 10,000 Scopus concrete-related articles published in the last decade). It therefore remains to be seen how research in this area will contribute to concrete eco-efficiency. This chapter summarizes the state of current knowledge in the field and considers the influence of nanoparticles on the mechanical properties of concrete and its durability. It also includes the control of calcium leaching. The problem of efficient dispersion of nanoparticles is analyzed.

The suitability of concrete using recycled aggregates (RAs) for high-performance concrete (HPC)

Most studies related to concrete made with recycled aggregates (RA) use uncontaminated aggregates produced in the laboratory, revealing the potential to re-use as much as 100%. However, industrially produced RA contain a certain level of impurities that can be deleterious for Portland cement concrete, thus making it difficult for the concrete industry to use such investigations unless uncontaminated RA are used. This chapter reviews current knowledge on concrete made with RA, with a focus on the crucial importance of the presence of impurities, and how those aggregates are not suitable for the production of high-performance concrete (HPC). The potential of geopolymers to produce HPC based on high volume RA is also discussed.

An eco-efficient approach to concrete carbonation

Abstract: Carbonation is a major cause of concrete structure deterioration, leading to expensive maintenance and conservation operations. The eco-efficient construction agenda favors the increase of the use of supplementary cementitious materials (SCMs) to reduce Portland cements consumption and also the use of recycled aggregates concrete (RAC) in order to reduce the consumption of primary aggregates and to avoid landfill disposal of concrete waste. A wide range of literature has been published in the field of concrete carbonation related to the use of SCMs and/or RCA. Fowever, the different conditions used limit comparison, and in some cases contradictory findings are noted. Besides, since most investigations are based on the use of the phenolphthalein indicator, which provides a poor estimate of the real concrete carbonation depth, there is a high probability that past research could have underestimated the corrosion potential associated with concrete carbonation. This chapter reviews current knowledge on concrete carbonation addressing carbonation depth measurement and the use of SCMs and RAC.