Sahebrao Sonkamble

Electrical resistivity and hydrochemical indicators distinguishing chemical characteristics of subsurface pollution at Cuddalore coast, Tamil Nadu

Electrical resistivity methods are applied extensively for shallow sub-surface objectives but it has constraints in distinguishing the chemical characteristics of the medium. However, this complexity can be resolved by integrated investigations where geophysical anomaly would be validated with hydro-geochemical data. The present study highlights the notable importance of integrated geophysical and hydrogeological investigations in demarcating sub-surface pollution due to saline water intrusion and industrial effluents at Cuddalore coast in India. Geophysical scanning encompassing a total of 35 vertical electrical sounding (VES) were validated with drilling lithologs, water level and water quality parameters from a network of 125 observation wells at a test site of 17 km2. To understand the spatial variation of sub-surface contamination, two profiles of apparent resistivity sections were generated covering VES points parallel to the coast. Results revealed that, the low order of resistivity range 3 to 10 Ω-m (up to 30–40 m depth) and total dissolved solids range 2000 to 10,000 mg/l of groundwater reflects sub-surface contamination but cannot distinguish kind of salinity which is further verified by chemical analysis of Ca2+ (1200–2041 mg/l), SO42− (3000–9480 mg/l) which confirms the gypsum pollution and Na+ (750–1000 mg/l), Cl− (1000–2000 mg/l) designate the marine water contamination. Further, static groundwater head measurements demarcate the study area into above mean sea level (MSL) and below MSL zones. This study has provided a rapid and comprehensive picture about spatial variations of groundwater contamination which can help in planning, protection and safe management of coastal aquifers in India and worldwide.

Delineation of fresh aquifers in tannery belt for sustainable development — A case study from southern India

The tannery effluents discharged by the existing units on either side of the Palar river at Ambur town (known for tannery industry), has resulted in vertical and lateral spread of pollution. The study area of 55.3 km2 is situated on a granitic terrain of Archaean age with undulating topography and hillocks. The shallow aquifers, in flood plain and valley fills of the river are highly polluted (with EC: 15340 μS/cm) by tannery effluents making groundwater unfit for any use, hence the local population (20000) face health hazards and shortage of potable water. Hydrogeological, geophysical and in-situ groundwater quality measurement were carried out to demarcate fresh groundwater zones and to delineate lateral and vertical extent of pollution. The results show, brackish aquifer was characterized by low order of resistivity (<20 Ω-m) with a thickness of 8.5 to 28 m located in the flood plains, valley fills, and partially in hard rock formations, whereas the fresh water aquifer resistivity varying from 23 to 216 Ω-m in hard rock. Further, these results were correlated with the water quality data and Ground Penetrating Radar (GPR) signals. The integrated studies revealed that pollution due to tannery effluents has spread over an area of 33.4 km2 (60.4 %) on either side of the river and only a small area of 21.9 km2 (39.6 %) was identified as fresh groundwater zone, which has to be conserved and exploited in sustainable manner for future generations.

Source speciation resolving hydrochemical complexity of coastal aquifers.

There is a growing concern of seawater intrusion to freshwater aquifers due to groundwater overexploitation in the eastern coastal belt of Southern India. The problem becomes complex in the regions where industrial effluents are also contaminating the freshwater aquifers. In order to understand the hydrochemical complexity of the system, topographic elevation, static water level measurements, major ion chemistry, ionic cross plots, water type contours and factor analysis were applied for 144 groundwater samples of shallow and deep sources from Quaternary and Tertiary coastal aquifers, located within the industrial zone of 25 km(2) area near Cuddalore, Southern India. The ionic cross plots indicates dissolution of halite minerals from marine sources and seawater mixing into inland aquifers up to the level of 9.3%. The factor analysis explains three significant factors totaling 86.3% of cumulative sample variance which includes varying contribution from marine, industrial effluent and freshwater sources.

Natural treatment system models for wastewater management: a study from Hyderabad, India

Wastewater generated on a global scale has become a significant source of water resources which necessitates appropriate management strategies. However, the complexities associated with wastewater are lack of economically viable treatment systems, especially in low- and middle-income countries. While many types of treatment systems are needed to serve the various local issues, we propose natural treatment systems (NTS) such as natural wetlands that are eco-friendly, cost-effective, and can be jointly driven by public bodies and communities. In order for it to be part of wastewater management, this study explores the NTS potential for removal of pollutants, cost-effectiveness, and reuse options for the 1.20 million m3/day of wastewater generated in Hyderabad, India. The pilot study includes hydro-geophysical characterization of natural wetland to determine pollutant removal efficiency and its effective utilization for treated wastewater in the peri-urban habitat. The results show the removal of organic content (76-78%), nutrients (77-97%), and microbes (99.5-99.9%) from the wetland-treated wastewater and its suitability for agriculture applications. Furthermore, the wetland efficiency integrated with engineered interventions led to the development of NTS models with different application scenarios: (i) constructed wetlands, (ii) minimized community wetlands, and (iii) single outlet system, suitable for urban, peri-urban and rural areas, respectively.

Hydro-geophysical characterization and performance evaluation of natural wetlands in a semi-arid wastewater irrigated landscape

Natural wetlands are green infrastructure systems that are energy-efficient for wastewater treatment and can be found in diverse geo-environmental settings around the world. Their structure and functions, which defines the treatment efficiencies are highly varied. Wetlands over shallow bedrock and geological lineaments (weak zones) have been known to contribute to groundwater contamination. However, not many studies have been performed to understand the structure in different geological settings to identify the efficiency determining factors. Therefore, it is important to investigate the geological suitability of the natural wetlands. We examined wastewater fed natural wetlands in diverse geological settings aiming at studying the depth, geo-stability, bio-chemical interactions, and hydrogeological attributes that improve the wastewater quality, within the Musi River basin, India. The integrated geophysical scans encompassing electrical resistivity tomography (ERT), hydrogeological test, bathymetric study and hydro-chemical analysis were carried out to explore the physical structure and hydro-dynamic processes in the wetlands. ERT investigations showed that, the depth to bedrock up to 20-25 m devoid of geo-fractures (lineaments) indicated the effective depth of saturated zone as a passable scope for potential bio-chemical interactions, implying the proportionality of the deep seated (deep bedrock) wetland to the pollutant removal efficiency. The lower order of electrical resistivity range 10-35 Ωm and hydraulic conductivity 2.938 md-1 acquired for saturated weathered zone were found catalyzing the bioremediation, sedimentation, adsorption, redox reactions and ion exchange processes. It caused the deep seated wetland removing nitrate 194.34 kgd-1 (97.18%); sulphate 333.75 kgd-1 (77.70%); phosphate 9.66 kgd-1 (82.53%); microbes 99.99%, BOD 80%, and COD 80% load with discharge 1408 m3d-1 of treated wastewater. Further, the strategies for designating the natural wetlands as wastewater treatment systems are also discussed in this paper.

Spatio-Temporal Distribution and Chemical Characterization of Groundwater Quality of a Wastewater Irrigated System: A Case Study

Wastewater irrigation is a common livelihood practice in many parts of the developing world. With the continuous irrigation supply, groundwater systems in these regions perceive adverse impacts due to inadequate infrastructure to treat the wastewater. The current study area, Musi River irrigation system, is one such case study located in the peri-urban Hyderabad of South India. The Musi River water, which is used for irrigation, is composed of untreated and secondary treated wastewater from Hyderabad city. Kachiwani Singaram micro-watershed in the peri-urban Hyderabad is practicing wastewater irrigation for the last 40 years. The current quality of (untreated) wastewater used for irrigation is expected to have adverse impacts on the local aquifers, but detailed investigations are lacking. To elucidate the groundwater quality dynamics and seasonality of the wastewater irrigation impacts on the peri-urban agricultural system, we analyzed the groundwater quality on a monthly basis for one hydrological year in the wastewater and groundwater irrigated areas, which exist next to each other. The spatio-temporal variability of groundwater quality in the watershed was analyzed with respect to wastewater irrigation and seasonality using multivariate statistical analysis, multi-way modeling and self-organizing maps. This study indicates the significance of combining various statistical techniques for detailed evaluation of the groundwater processes in a wastewater irrigated agricultural system. The results suggest that concentrations of the major ionic substances increase after the monsoon season, especially in wastewater irrigated areas. Multi-way modeling identified the major polluted groundwaters to come from the wastewater irrigated parts of the watershed. Clusters of chemical variables identified by using self-organizing maps indicate that groundwater pollution is highly impacted by mineral interactions and long-term wastewater irrigation. The study recommends regular monitoring of water resources and development of sustainable management strategies to mitigate the aquifer pollution in wastewater irrigation systems.

Vertical electrical sounding to delineate the potential aquifer zones for drinking water in Niamey city, Niger, Africa

Niger is a landlocked African country and the only source of surface water is the Niger River which flows in the western part of Niger and only few villages near to the river gets benefited from it, leaving most of the areas dependent on groundwater solely. The groundwater resources in Niger are mainly used for drinking, livestock and domestic needs. It can be observed that the water exploitation is minimal there due to several factors like undeveloped areas, less population, limited wells, rain-fed irrigation, etc. The delineation of potential aquifer zones is an important aspect for groundwater prospecting. Hence, the direct current (DC) resistivity soundings method also known as vertical electrical sounding (VES) is one of the most applied geophysical techniques for groundwater prospecting that was used in the capital city, Niamey of Niger. Twelve VES surveys, each of AB spacing 400 m were carried out in lateritic and granitic rock formations with a view to study the layer response and to delineate the potential zones. Potential aquifer zones were at shallow depth ranging from 10 to 25 m for the drilled borehole depth of 80–85 m in every village. Analysis of the result showed a good correlation between the acquired data and the lithologs.

Vulnerability Assessment of Coastal Aquifer System for Irrigation Suitability - A Classical Approach from Southern India

The vulnerability of the shallow aquifer system for saline water intrusion has been evaluated using the classical tools at a coastal area, southern India. Groundwater samples (N=144) from Quaternary aquifer system within 25 km2 area in pre- and post-monsoon seasons were analyzed for major ion chemistry including Electrical Conductivity (EC). The hydrochemical parameters are examined applying classical irrigation suitability tools. Based on their weight percentages (ratios in meq/l) the dominance of cations and anions was established as Na-Cl and Ca-SO4 type. Results show that high hydraulic conductivity (10−2 to 1 cm/s) of the sandy aquifer enhanced the vertical recharge leading to major spatial distribution suitable for irrigation use in post-monsoon. The overexploitation of groundwater resources has generated reversal of hydraulic gradient enhancing salinity intrusion from marine sources in pre-monsoon. Further, the Differential Global Positioning System (DGPS) survey and water level measurements are assessed to demarcate the study area into zones of water table ‘above mean sea level (amsl)’ and ‘below mean sea level (bmsl)’. It was deduced that, the industrial effluent and seawater were the prime sources of groundwater salinity of water table ‘amsl’ and ‘bmsl’ zones, respectively. The area up to 600 m from marine source is found vulnerable which is falling under ‘Unsuitable’ category of irrigation classifications. The remedial measures are also framed to protect further extension of aquifer vulnerability for sustainable agriculture.