Sally Solomon

Photon to thermal response of a single patterned gold nanorod cluster under near-infrared laser irradiation

The potential applications of the photon to thermal conversion technique by gold nanorods has attracted attention for biomedical applications since they show an intense absorption spectrum in the near-infrared region, and therefore, penetrate more deeply into biological tissues. The goal in this study is to assess a local heating phenomenon with a single patterned cluster of gold nanorods that are prepared as a wet chemically synthesized gold nanorod solution and mixed with aqueous 1% alginate and 0.1 M calcium chloride. In particular, we utilized the initiated chemical vapor deposition method to coat the cluster with poly(2-hydroxyethyl methacrylate) to enhance its high temperature resistance in the solution. The influence of the thermal energy on the surroundings is studied by measuring the surface temperature of the single patterned gold nanorod cluster as a function of laser irradiation time. The experimental results were compared with numerical simulation results. The results showed that the irradiated gold nanorods could rapidly heat to maximum surface temperatures of over 60 °C within 120 s. Furthermore, the temperature remained almost constant (i.e. reached a steady state) under continuous laser irradiation and rapidly cooled to the initial temperature within 90 s when the laser was turned off.

Diffusion Rates on the Overhead Projector:: Amines Compared to HCl

Diffusion rates of selected amines are compared to that of HCl using a method very similar to those described for NH3 versus HCl diffusion. Well-defined white amine hydrochloride rings form quickly and Grahams Law can be tested for different molar masses.

Addition of IBr to fatty acids on the overhead projector

The interhalogen compound IBr dissolved in CCl4 is added to petroleum ether solutions of fatty acids to test for unsaturation.

A bulletin board demonstration on humidity

A demonstration of the color changes of cobalt chloride with relative humidity is described in this note.

Reaction of bromine with hydrocarbons on the overhead, real or simulated

A simulation that looks like the addition of bromine to hydrocarbons but is not (the bromine is simulated using a mixture of food colorings).

Rotation of polarized light by stereoisomers of limonene

Neat samples of limonene stereoisomers are used to demonstrate the rotation of polarized light on an overhead projector.