Salvador B. Rodriguez

Analysis Model for Sulfur-Iodine and Hybrid Sulfur Thermochemical Cycles

Abstract This paper presents a transient control volume modeling scheme for both the sulfur-iodine (SI) and Westinghouse hybrid sulfur (HyS) thermochemical cycles. These cycles are very important candidates for the large-scale production of hydrogen in the 21st century. In this study, transient control volume models of the SI and HyS cycles are presented, along with a methodology for coupling these models to codes that describe the transient behavior of a high-temperature nuclear reactor. The transient SI and HyS cycle models presented here are based on a previous model with a significant improvement, namely, pressure variation capability in the chemical reaction chambers. This pressure variation capability is obtained using the ideal gas law, which is differentiated with respect to time. The HyS model is based on a time-dependent application of the Nernst equation. Investigation of the new pressure assumption yields a peak pressure rate of change of 5.877 kPa/s for a temperature-driven transient test matrix and 2.993 kPa/s for a mass flow rate–driven transient test matrix. These high rates of pressure change suggest that an accurate model of the SI and/or HyS cycle must include some method of accounting for pressure variation. The HyS model suggests that the hydrogen production rate is directly proportional to the SO2 production rate.

SIMULATION OF SULFUR-IODINE THERMOCHEMICAL HYDROGEN PRODUCTION PLANT COUPLED TO HIGH-TEMPERATURE HEAT SOURCE

Abstract The sulfur-iodine (SI) cycle is one of the leading candidates in thermochemical processes for hydrogen production. In this paper a simplified model for the SI cycle is developed with chemical kinetics models of the three main SI reactions: the Bunsen reaction, sulfuric acid decomposition, and hydriodic acid decomposition. Each reaction was modeled with a single control volume reaction chamber. The simplified model uses basic heat and mass balance for each of the main three reactions. For sulfuric acid decomposition and hydriodic acid decomposition, reaction heat, latent heat, and sensible heat were considered. Since the Bunsen reaction is exothermic and its overall energy contribution is small, its heat energy is neglected. However, the input and output streams from the Bunsen reaction are accounted for in balancing the total stream mass flow rates from the SI cycle. The heat transfer between the reactor coolant (in this case helium) and the chemical reaction chamber was modeled with transient energy balance equations. The steady-state and transient behavior of the coupled system is studied with the model, and the results of the study are presented. It was determined from the study that the hydriodic acid decomposition step is the rate-limiting step of the entire SI cycle.

Development of design and simulation model and safety study of large-scale hydrogen production using nuclear power.

Before this LDRD research, no single tool could simulate a very high temperature reactor (VHTR) that is coupled to a secondary system and the sulfur iodine (SI) thermochemistry. Furthermore, the SI chemistry could only be modeled in steady state, typically via flow sheets. Additionally, the MELCOR nuclear reactor analysis code was suitable only for the modeling of light water reactors, not gas-cooled reactors. We extended MELCOR in order to address the above deficiencies. In particular, we developed three VHTR input models, added generalized, modular secondary system components, developed reactor point kinetics, included transient thermochemistry for the most important cycles [SI and the Westinghouse hybrid sulfur], and developed an interactive graphical user interface for full plant visualization. The new tool is called MELCOR-H2, and it allows users to maximize hydrogen and electrical production, as well as enhance overall plant safety. We conducted validation and verification studies on the key models, and showed that the MELCOR-H2 results typically compared to within less than 5% from experimental data, code-to-code comparisons, and/or analytical solutions.

Enhanced Passive Cooling for Waterless-Power Production Technologies

Recent advances in the literature and at SNL indicate the strong potential for passive, specialized surfaces to significantly enhance power production output. Our exploratory computational and experimental research indicates that fractal and swirl surfaces can help enable waterless-power production by increasing the amount of heat transfer and turbulence, when compared with conventional surfaces. Small modular reactors, advanced reactors, and non-nuclear plants (e.g., solar and coal) are ideally suited for sCO2 coolant loops. The sCO2 loop converts the thermal heat into electricity, while the specialized surfaces passively and securely reject the waste process heat in an environmentally benign manner. The resultant, integrated energy systems are highly suitable for small grids, rural areas, and arid regions.

Design Construction and Operation of a Supercritical Carbon Dioxide (sCO2) Loop for Investigation of Dry Cooling and Natural Circulation Potential for Use in Advanced Small Modular Reactors Utilizing sCO2 Power Conversion Cycles.

This report outlines the work completed for a Laboratory Directed Research and Development project at Sandia National Laboratories from October 2012 through September 2015. An experimental supercritical carbon dioxide (sCO2) loop was designed, built, and operated. The experimental work demonstrated that sCO2 can be utilized as the working fluid in an air-cooled, natural circulation configuration to transfer heat from a source to the ultimate heat sink, which is the surrounding ambient environment in most cases. The loop was also operated in an induction-heated, watercooled configuration that allows for measurements of physical parameters that are difficult to isolate in the air-cooled configuration. Analysis included the development of two computational fluid dynamics models. Future work is anticipated to answer questions that were not covered in this project. UNCLASSIFIED UNLIMITED RELEASE 4 UNCLASSIFIED UNLIMITED RELEASE This page intentionally left blank. UNCLASSIFIED UNLIMITED RELEASE 5 UNCLASSIFIED UNLIMITED RELEASE

Z-inertial fusion energy: power plant final report FY 2006.

This report summarizes the work conducted for the Z-inertial fusion energy (Z-IFE) late start Laboratory Directed Research Project. A major area of focus was on creating a roadmap to a z-pinch driven fusion power plant. The roadmap ties ZIFE into the Global Nuclear Energy Partnership (GNEP) initiative through the use of high energy fusion neutrons to burn the actinides of spent fuel waste. Transmutation presents a near term use for Z-IFE technology and will aid in paving the path to fusion energy. The work this year continued to develop the science and engineering needed to support the Z-IFE roadmap. This included plant system and driver cost estimates, recyclable transmission line studies, flibe characterization, reaction chamber design, and shock mitigation techniques.