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Dive into the research topics where Sangyun Lim is active.

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Featured researches published by Sangyun Lim.


ACS Nano | 2007

Low-defect, purified, narrowly (n,m)-dispersed single-walled carbon nanotubes grown from cobalt-incorporated MCM-41.

Yuan Chen; Li Wei; Bo Wang; Sangyun Lim; Dragos Ciuparu; Ming Zheng; Jia Chen; Codruta Zoican; Yanhui Yang; Gary L. Haller; Lisa D. Pfefferle

A mild, four-step purification procedure using NaOH reflux, HCl wash, and oxidation by 4 mol % molecular oxygen at 500 degrees C was developed to purify single-walled carbon nanotubes (SWCNTs) with narrow semiconducting (n,m) distribution produced from cobalt-incorporated MCM-41 (Co-MCM-41) in order to obtain bulk low-defect-density nanotubes. Three key features of Co-MCM-41 allow this mild purification technique: (1) ultrathin silica walls versus dense silica or other crystalline oxide supports are soluble in dilute NaOH aqueous solution, which avoids the damage to SWCNTs usually caused by using HF treatment to remove catalytic supports; (2) the small metallic particles are easily dissolved in HCl, a significantly milder chemical treatment compared to HF or HNO(3); (3) the high selectivity to SWCNTs with negligible multiwalled carbon nanotubes or graphite, which facilitates the removal of undesired carbon species by selective oxidation. The effectiveness of this purification procedure was evaluated by high-resolution transmission electron microscopy, scanning electron microscopy, Raman, UV-vis-NIR, and fluorescence spectroscopy, solution redox chemistry on fractionated (6,5) tubes, and SWCNT-based field effect transistor device performance. The results demonstrate that Co-MCM-41 catalyst not only provides tubes with narrow semiconducting (n,m) distribution but also allows a mild purification procedure and, therefore, produces SWCNTs with fewer defects.


Microporous and Mesoporous Materials | 2001

Synthesis and characterization of Pt/MCM-41 catalysts

Naisheng Yao; Carla Pinckney; Sangyun Lim; Chanho Pak; Gary L. Haller

Abstract The preparation of Pt/MCM-41 catalysts was studied. Three different precursors were used: platinum acetyl acetonate Pt(AcAc) 2 , tetraamine platinum (II) nitrate Pt(NH 3 ) 4 (NO 3 ) 2 , and hydrogen hexachloroplatinate (IV) hydrate H 2 PtCl 6 . With these precursors, the catalysts were prepared by three different methods: equilibrium adsorption, ion exchange, and a new method, which we call vacuum evaporation impregnation (VEI). Through the characterizations by XRD, physisorption, chemisorption, XAFS, and XANES-TPR, it was demonstrated that a structured, high loading (0.5–2 wt.%) and high dispersion (>1.0 calculated from CO and/or H 2 chemisorption) Pt/MCM-41 catalysts was obtained by the new preparation method VEI.


Studies in Surface Science and Catalysis | 2000

Preparation of highly structured V-MCM-41 and determination of its acidic properties

Sangyun Lim; Gary L. Haller

Vanadium substituted mesoporous molecular sieves (MCM-41) were prepared and the effects of water: Si ratio and anti-foaming agent addition to synthesis solution were investigated. The anti-foaming agent was very effective in improving the reproductibility of sample structure. The amount of V substitution into the silica framework was increased with increasing water amount and surfactant chain length. All of the incorporated V was tetrahedrally coordinated in the silica framework. The density of Lewis acid sites was constant for all samples but exceeds that in a pure silica sample.


Journal of Catalysis | 2007

Methanation of carbon dioxide on Ni-incorporated MCM-41 catalysts: The influence of catalyst pretreatment and study of steady-state reaction

Guoan Du; Sangyun Lim; Yanhui Yang; Chuan Wang; Lisa D. Pfefferle; Gary L. Haller


Journal of Physical Chemistry B | 2003

Synthesis and Characterization of Highly Ordered Co−MCM-41 for Production of Aligned Single Walled Carbon Nanotubes (SWNT)

Sangyun Lim; Dragos Ciuparu; Chanho Pak; Frank Dobek; Yuan Chen; David Harding; Lisa D. Pfefferle; Gary L. Haller


Journal of Physical Chemistry B | 2004

Uniform-diameter single-walled carbon nanotubes catalytically grown in cobalt-incorporated MCM-41

Dragos Ciuparu; Yuan Chen; Sangyun Lim; Gary L. Haller; Lisa D. Pfefferle


Journal of Catalysis | 2008

Synthesis, characterization, and catalytic performance of highly dispersed vanadium grafted SBA-15 catalyst

Guoan Du; Sangyun Lim; Mathieu Pinault; Chuan Wang; Fang Fang; Lisa D. Pfefferle; Gary L. Haller


Journal of Catalysis | 2004

Synthesis of uniform diameter single-wall carbon nanotubes in Co-MCM-41: effects of the catalyst prereduction and nanotube growth temperatures

Yuan Chen; Dragos Ciuparu; Sangyun Lim; Yanhui Yang; Gary L. Haller; Lisa D. Pfefferle


Journal of Physical Chemistry B | 2005

Synthesis and characterization of highly ordered Ni-MCM-41 mesoporous molecular sieves.

Yanhui Yang; Sangyun Lim; Guoan Du; Yuan Chen; Dragos Ciuparu; Gary L. Haller


Applied Catalysis A-general | 1999

Gas phase methanol oxidation on V-MCM-41

Sangyun Lim; Gary L. Haller

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Yanhui Yang

Nanyang Technological University

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Bo Wang

Nanyang Technological University

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