Sanjay Vijayaraghavan

New and emerging developments in solar energy

Abstract Solar energy can potentially play a very important role in providing most of the heating, cooling and electricity needs of the world. With the emergence of solar photocatalytic detoxification technology, solar energy also has the potential to solve our environmental problems. However, we do not see widespread commercial use of solar energy. Some of the emerging developments in solar may change that situation. This paper describes some of the new and emerging developments, with special emphasis on: (1) nanoscale antennas for direct conversion of sunlight to electricity with potential conversion efficiencies approaching 80–90%; (2) new thermodynamic cycles for solar thermal power, that have the potential to reduce capital costs by 50%; and (3) solar photocatalytic oxidation for cleanup of industrial wastewater, drinking water, soil and air. The paper describes the fundamentals of each of these developments, their potential, present status and future opportunities for research. (1) Nanoscale antenna solar energy conversion: The current photovoltaic technologies rely on the quantum nature of light and semiconductors which are fundamentally limited by the band-gap energies. A revolutionary new approach suggested by Professor Robert Bailey in 1972 revolves around the wave nature of light. Professor Bailey suggested that broadband rectifying antennas could be used for solar to d.c. conversion. These rectennas would not have the fundamental limitation of semiconductor band-gap limiting their conversion efficiencies. Rectennas for solar conversion would have dimensions of the order of the wavelengths of solar radiation which falls mostly in the sub-micron range. The challenges in actually achieving the objectives are many. This paper describes the challenges and approaches to their solution. (2) New thermodynamic cycles for solar thermal power: It is recognized that the capital costs of solar thermal power will have to be reduced by about 50% in the near future in order to make it competitive with fossil fuels (especially natural gas) based power systems. Potential exists for meeting this goal by reducing the costs and improving the thermodynamic performance of power cycles by hybridization and combined cycle approaches and by employing new and innovative ideas in thermal power cycles. This paper describes the new thermodynamic approaches with an emphasis on an innovative new thermodynamic cycle using ammonia and water mixtures as the working fluids. (3) Solar photocatalytic detoxification and disinfection of water and air: Although the potential of solar radiation for disinfection and environmental mitigation has been known for years, only recently has this technology been scientifically recognized and researched. Solar photocatalytic oxidation has been demonstrated to effectively treat groundwater, drinking water, and industrial wastewater. In some applications such as decoloration and reduction of COD it may be the only effective method of treatment. Treatment of indoor air by the photocatalytic method has been demonstrated as the most effective technology for that application. This paper describes the recent developments and identify challenges and future research opportunities.

A Novel Approach to Enhance the Hydrogen Yield of Biomass Gasification Using CO2 Sorbent

Hydrogen yield of conventional biomass gasification is limited by chemical equilibrium constraints. A novel technique that has the potential to enhance the hydrogen yield by integrating the gasification and absorption reactions has been suggested. The method involves gasification of biomass in presence of a CO 2 sorbent. Ethanol was used as the model biomass compound and CaO was the representative sorbent. Equilibrium modeling was used to determine the product gas composition and hydrogen yield. The analysis was done using ASPEN PLUS software (version 12.1) and the Gibbs energy minimization approach was followed. The effects of temperature, pressure, steam/ethanol ratio, and CaO/ethanol ratio on product yield were investigated. Three case studies were conducted to understand the effect of sorbent addition on the hydrogen yield. Thermodynamic studies showed that the use of sorbents has the potential to enhance the equilibrium hydrogen yield of conventional gasification by ∼ 19% and reduce the equilibrium CO 2 content of product gas by 50.2%. It was also found that the thermodynamic efficiency of sorbent- enhanced gasification (72.1%) was higher than conventional gasification (62.9%). Sorbent-enhanced gasification is a promising technology with a potential to improve the yield and lower the cost of hydrogen production.

On Evaluating Efficiency of a Combined Power and Cooling Cycle

A combined power and cooling cycle is being investigated. The cycle is a combination of the Rankine cycle and an absorption refrigeration cycle. Evaluating the efficiency of this cycle is made difficult by the fact that there are two different simultaneous outputs, namely power and refrigeration. An efficiency expression has to appropriately weigh the cooling component in order to allow comparison of this cycle with other cycles. This paper develops several expressions for the first law, second law and exergy efficiency definitions for the combined cycle based on existing definitions in the literature. Some of the developed equations have been recommended for use over others, depending on the comparison being made. Finally, some of these definitions have been applied to the cycle and the performance of the cycle optimized for maximum efficiency. A Generalized Reduced Gradient (GRG) method was used to perform the optimization. The results of these optimizations are presented and discussed.Copyright

Preparation and Characteristics of Calcium Oxide Pellets for UT-3 Thermochemical Cycle

UT-3 thermochemical cycle for hydrogen production involves four gas-solid reactions. In order to make the cycle feasible, the solid reactant must be chemically reactive and physically stable in cyclic operation. Calcium oxide pellets, with CaO dispersed in the CaTiO3 inert matrix, were prepared and stearic acid, graphite, and corn starch were added as pore forming agents during the process. Experimental studies to improve and evaluate the Ca-pellets through the investigation into thermal decomposition of additives, X-ray diffraction, pore size distribution, conversion and reaction rate were conducted. The pore size distributions of the pellets were found to be strongly influenced by the type of pore forming agents used, and the volume of pores greater than 5μm markedly promoted hydrolysis rate.Copyright

Hydrogen Production From Ethanol: A Thermodynamic Analysis of a Novel Sorbent Enhanced Gasification Process

A novel biomass hydrogen production technique by integrating gasification and absorption reactions has been suggested. The method involves gasification of biomass in presence of a CO2 sorbent. Ethanol was used as the model biomass compound and CaO was the representative sorbent. Equilibrium modeling was used to determine the product gas composition and hydrogen yield. The analysis was done using ASPEN PLUS software (version 12.1) and Gibbs energy minimization approach was followed. The effects of temperature, pressure, steam/ethanol ratio and CaO/ethanol ratio on product yield were investigated. Three case studies were conducted to understand the effect of sorbent addition on hydrogen yield. Finally a simple energy analysis was carried out to determine the energy consumption and efficiency of sorbent enhanced ethanol gasification.Copyright

Organic Working Fluids for a Combined Power and Cooling Cycle

A new thermodynamic cycle has been developed for the simultaneous production of power and cooling from low temperature heat sources. The proposed cycle combines the Rankine and absorption refrigeration cycles, providing power and cooling as useful outputs. Initial studies were performed with an ammonia-water mixture as the working fluid in the cycle. This work extends the application of the cycle to working fluids consisting of organic fluid mixtures. Organic working fluids have been used successfully in geothermal power plants, as working fluids in Rankine cycles. An advantage of using organic working fluids is that the industry has experience with building turbines for these fluids. A commercially available optimization program has been used to maximize the thermodynamic performance of the cycle. The advantages and disadvantages of using organic fluid mixtures as opposed to an ammonia-water mixture are discussed. It is found that thermodynamic efficiencies achievable with organic fluid mixtures, under optimum conditions, are lower than those obtained with ammonia-water mixtures. Further, the refrigeration temperatures achievable using organic fluid mixtures are higher than those using ammonia-water mixtures.Copyright