Sasi Stephen

Tracking traces of transition metals present in concrete mixtures by inductively-coupled plasma mass spectrometry studies

Transition metals can have a significant impact in research related to the dosage optimization of superplasticizers. It is known that the presence of transition metals can influence such doses, and the application of a contemporary instrumental method to obtain the profiles of subsisting transition elements in concrete mixtures would be useful. In this work, inductively-coupled plasma mass spectrometry (ICP-MS) is investigated as a possible tool to track traces of transition metals in concrete mixtures. Depth profiling using ICP-MS on proofed and unproofed concrete shows the presence of Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu and Zn at trace intensities in the bulk of the samples under investigation. The study demonstrates that the transition metals present in the concrete sample are largely a part of the cement composition and, to a minor degree, a result of exposure to the seawater after curing. The coated concrete samples have a metal distribution pattern similar to the uncoated samples, but slight differences in intensity bear testimony to the very low levels that originate from the exposure to seawater. While X-ray diffraction fails to detect these traces of metals, ICP-MS is successful in detecting ultra-trace intensities to parts per trillion. This method is not only a useful application to track traces of transition metals in concrete, but also provides information to estimate the pore size distribution in a given sample by very simple means.

Rapid evaluation of the extent in micro-degradation of protective coatings using laser-ablation inductively coupled plasma mass spectrometry (LA-ICP-MS)

The durability of coatings used to protect base materials can be affected by environmental factors and degradation mechanisms including thermal decomposition, catalytic decomposition, bio-disintegration, chemical corrosion and mechanical scission. LA-ICP-MS is often used for the analysis of the trace elements to understand the degradation mechanism. This article extends the use of the LA-ICP-MS for the determination of the extent of coating degradation. The method is particularly useful for the rapid evaluation of conventional overlay metal-coatings at micron and sub-micron levels in applications such as pipelines commonly found in the oil and gas industry.