Satadru Bhattacharya

Jarosite occurrence in the Deccan Volcanic Province of Kachchh, western India: Spectroscopic studies on a Martian analog locality

The sulfate mineral jarosite is considered a key indicator of hydrous, acidic, and oxidizing conditions on the surface of early Mars. Here we report an analog terrestrial locality hosting jarosite from Matanumadh, Kachchh, western India, using detailed spectroscopic studies on weathered basalts of the Deccan Volcanic Province and overlying tuffaceous shales and sandstones of the Matanumadh Formation. Hyperspectral data in the visible/near-infrared (350–2500 nm) to midinfrared (4000–400 cm−1) region of the electromagnetic spectrum and X-ray diffraction patterns have been acquired on samples collected from the field to detect and characterize the hydrous sulfate and phyllosilicate phases present at the studied site. Hydrous sulfates occur in association with Al-rich phyllosilicates (kaolinite) that overlie a zone of Fe/Mg smectites in altered basalts. Jarosite is found within both saprolitic clay horizons altered from the basalt and within variegated sandstone and shale/clay units overlying the saprolite; it mostly occurs as secondary veins with or without gypsum. Jarosite is also seen as coatings on kaolinite clasts of varying shapes and sizes within the tuffaceous variegated sandstone unit. We argue that the overall geological setting of the Matanumadh area, with this unusual mineral assemblage developing within altered basalts and in the overlying sedimentary sequence, mimics the geological environment of many of the identified jarosite localities on Mars and can be considered as a Martian analog from this perspective.

Alteration and submergence of basalts in Kachchh, Gujarat, India: implications for the role of the Deccan Traps in the India–Seychelles break-up

Abstract The Deccan Trap flood basalt volcanism has commonly been considered to have initiated the break-up of India from the Seychelles (c. 62.5 Ma). In Kachchh, Gujarat, western India, the sedimentary succession in the Paleocene Matanomadh Formation was deposited on highly weathered Deccan Trap basalts that were altered to kaolinite before basin formation. This contrasts with the weathering pattern on flat-topped hills of the Deccan Traps outside the Cenozoic rift basins in the Kachchh region and other parts of India, where basalt is dominantly altered to smectitic minerals. As basalts that are altered to smectite and kaolinite occur just across the faults that bound the Matanomadh Basin, the differential weathering cannot be attributed to climate. Geochemical modelling shows that kaolinite stabilizes in preference to smectite if CO2- and O2-buffered rainwater interacts with well-drained basaltic rock at high water:rock ratios. Such conditions can be accomplished by rainfall on a slope created by Cenozoic rifting that exposes the graben flank and basin floor basalts to continuously flowing water, the composition of which is buffered by equilibration with the atmosphere. As the rift post-dates both the eruption of the basalts and subsequent smectite formation, the associated extensional tectonics must be unrelated to flood basalt volcanism, and is most likely to correspond to the India–Seychelles break-up.

Astrobiological implications of dim light phototrophy in deep-sea red clays

Red clays of Central Indian Basin (CIB) under influence of trace of Rodriguez Triple Junction exhibited chemoautotrophy, low temperature hydrothermal alterations and photoautotrophic potential. Seamount flank TVBC-08, hosting such signatures revealed dominance of aerobic anoxygenic phototroph Erythrobacter, with 93% of total 454 pyrosequencing tags. Subsequently, enrichments for both aerobic (Erythrobacter) and anaerobic anoxygenic phototrophs (green and purple sulphur bacteria) under red and white LED light illumination, with average irradiance 30.66Wm-2, were attempted for three red-clay sediment cores. Successful enrichments were obtained after incubation for c.a. 120 days at 4°± 2°C and 25°± 2°C, representing ambient psychrophilic and low temperature hydrothermal alteration conditions respectively. During hydrothermal cooling, a microbial succession from anaerobic chemolithotrophy to oxygenic photoautotrophy through anaerobic/aerobic anoxygenic phototrophic microbes is indicated. Spectral absorbance patterns of the methanol extracted cell pellets showed peaks corresponding to metal sulphide precipitations, the Soret band of chlorosome absorbance by photosystem II and absence of peaks at Qy transition band. Dendritic nano-structures of metal sulphides are common in these sediments and are comparable with other sulphidic paleo-marine Martian analogues. Significant blue and redshifts have been observed for the experimental samples relative to the un-inoculated medium. These observations indicate the propensity of metal-sulphide deposits contributing to chemiluminiscence supporting the growth of phototrophs at least partially, in the otherwise dark abyss. The effects of other geothermal heat and light sources are also under further consideration. The potential of phototrophic microbial cells to exhibit Doppler shift in absorbance patterns is significant towards understanding planetary microbial habitability. Planetary desiccation could considerably influence Doppler effects and consequently spectral detection techniques exo-planetary microbial life.