Scott A. Skeen

A Progress Review on Soot Experiments and Modeling in the Engine Combustion Network (ECN)

The following individuals and funding agencies are acknowledged for their support. The authors from DTU acknowledge the Technical University of Denmark, Danish Strategic Research Council, and MAN Diesel & Turbo University of Wisconsin: Financial support provided by the Princeton Combustion Energy Frontier Research Center. ETH Zurich: Financial support from the Swiss Federal Office of Energy (grant no. SI/500818-01) and the Swiss Competence Center for Energy and Mobility (CCEM project “In-cylinder emission reduction”) is gratefully acknowledged. Argonne National Labs: Work was funded by U.S. DOE Office of Vehicle Technologies, Office of Energy Efficiency and Renewable Energy under Contract No. DE-AC02-06CH11357. We also gratefully acknowledge the computing resources provided on Fusion, a computing cluster operated by the Laboratory Computing Resource Center at Argonne National Laboratory. Sandia National Labs, Combustion Research Facility: Work was supported by the U.S. Department of Energy, Office of Vehicle Technologies. Sandia is a multiprogram laboratory operated by Sandia Corporation, a Lockheed Martin Company, for the United States Department of Energy’s National Nuclear Security Administration under contract DEAC04-94AL85000. Chris Carlen and Dave Cicone are gratefully acknowledged for technical assistance. The authors from ANL and SNL also wish to thank Gurpreet Singh and Leo Breton, program managers at U.S. DOE, for their support.

Quantitative Mixing Measurements and Stochastic Variability of a Vaporizing Gasoline Direct-Injection Spray

Spark-ignition direct-injection engines operating in a stratified, lean-burn regime offer improved engine efficiency; however, seemingly random fluctuations in stratified combustion that result in partial-burn or misfire prevent widespread implementation. Eliminating these poor combustion events requires detailed understanding of engine flow, fuel delivery, and ignition, but knowing the dominant cause is difficult because they occur simultaneously in an engine. This study investigated the variability in fuel–air mixture linked to fuel injection hardware in a near-quiescent pressure vessel at high-temperature conditions representative of late, stratified-charge injection. An eight-hole spark-ignition direct-injection spray was interrogated using high-speed schlieren and Mie-scatter imaging from multiple, simultaneous views to acquire the vapor and liquid envelopes of the spray. The mixture fraction of vaporized sections of the spray was then quantified at a plane between plumes using Rayleigh scattering. Probability contours of the line-of-sight vapor envelope showed little variability between injections, whereas probability contours derived from planar, quantitative mixing measurements exhibit greater amounts of variability for lean-combustion-limit charge. The mixture field between plumes was characterized by multi-hole and end-of-injection dynamics that attract the plumes to each other and toward the injection axis, resulting in a liquid-fuel-droplet-dense merged central jet in the planar measurements. Supplemental long-working distance microscopy imaging showed the existence of fuel droplets far downstream in the region of the planar laser measurements.

Onset and progression of soot in high-pressure n-dodecane sprays under diesel engine conditions

Soot onset in n-dodecane sprays is investigated both experimentally, by means of high-speed imaging data from the Sandia spray combustion vessel, and numerically, using the conditional moment closure combustion model and an integrated two-equation soot model in a Reynolds-averaged Navier–Stokes framework. Five operating conditions representative of modern diesel engines are studied at constant density (22.8 kg/m3) with variations in ambient oxygen concentration and temperature. The reference case at 15% O2 and 900 K is compared with measurements in terms of the evolving soot mass distribution and spatiotemporal distributions of formaldehyde and polycyclic aromatic hydrocarbons obtained by 355-nm laser-induced fluorescence (polycyclic aromatic hydrocarbons represented by C2H2 in simulation) and soot optical thickness (KL) signal obtained by diffused back-illumination extinction imaging. All operating points are validated in terms of ignition delay and lift-off length, soot onset time and location, soot mass evolution, and peak location. Measurements show that time lag between ignition and soot onset is considerably increased by a reduction in ambient oxygen or temperature. The trend of this time lag is captured very well by the simulations, as is the evolving axial distribution of soot, despite the simple soot model employed. Building on the good agreement between spatiotemporal distributions in experiment and simulation, further results from the latter are extracted to provide insight into relevant processes. The advancing soot tip lags behind the fuel–vapor spray tip due to soot oxidation. Tracking the Lagrangian time history of notional fluid particles from the soot onset location back to the injector orifice reveals that their trajectories evolve along rich conditions (φ > 1.5) throughout the entire path. Overall, novel insights obtained from experiments with respect to soot and soot precursor evolutions are complemented by simulations using the integrated conditional moment closure/soot modeling approach, showing encouraging results for prediction and understanding of transient soot processes in high-pressure diesel sprays.

Diffuse back-illumination setup for high temporally resolved extinction imaging

This work presents the development of an optical setup for quantitative, high-temporal resolution line-of-sight extinction imaging in harsh optical environments. The application specifically targets measurements of automotive fuel sprays at high ambient temperature and pressure conditions where time scales are short and perceived attenuation by refractive index gradients along the optical path (i.e., beam steering) can be significant. The illumination and collection optics are optimized to abate beam steering, and the design criteria are supported by well-established theoretical relationships. The general effects of refractive steering are explained conceptually using simple ray tracing. Three isolated scenarios are analyzed to establish the lighting characteristics required to render the observed radiant flux unaffected by the steering effect. These criteria are used to optimize light throughput in the optical system, enabling minimal exposure times and high-temporal resolution capabilities. The setup uses a customized engineered diffuser to transmit a constant radiance within a limited angular range such that radiant intensity is maximized while fulfilling the lighting criteria for optimal beam-steering suppression. Methods for complete characterization of the optical system are detailed. Measurements of the liquid-vapor boundary and the soot volume fraction in an automotive spray are presented to demonstrate the resulting improved contrast and reduced uncertainty. The current optical setup reduces attenuation caused by refractive index gradients by an order of magnitude compared to previous high-temporal resolution setups.

Special Issue on Soot Dynamics in Internal Combustion Engines

‘‘Soot’’ has been one of the most frequently studied and enduring topics in the combustion research community. Its formation in engines contributes to component fouling and efficiency losses by radiative heat transfer, while its emission negatively impacts human health and the environment. In the early 1970s, a number of fundamental studies on soot formation and oxidation processes by means of shock-tube and flat flame burner experiments have been reported. The results obtained in these studies are the root of our understanding of the soot processes in internal combustion engines. Minimizing soot emissions from diesel engines has been perpetual target as the level of engine-out soot emission limits the maximum engine torque. In the old days, when fuel injection systems relied on a mechanical pump, the injection pressure depended on the engine speed. This resulted in higher smoke emissions at low engine speed and high torque conditions due to the lower injection pressure and lower swirl velocity. The above problem was solved in the late 1990s by the common-rail fuel injection system, which allows the fuel injection pressure to be decoupled from the engine speed. The advancement provided arbitrary control of both the injection pressure and phasing. Combining the multiple injection strategies enabled by the common-rail system with variable geometry turbocharging, diesel combustion technology attained revolutionary progress. However, internal combustion engines are still subject to increasingly strict demands for reduced carbon dioxide, nitrogen oxides (NOx) and particulate matter (PM) emissions. Indeed, meeting the stringent global emissions standards has required the addition of exhaust after-treatment systems to both gasoline and diesel engines. The diesel particulate filter (DPF) is an effective device to trap soot particles thereby removing more than 99% of the engine-out particle mass. The soot accumulated in the DPF after a certain driving distance must be burned off—a process referred to as regeneration. The regeneration process depends on the exhaust flow rate, oxygen concentration, temperature and soot mass loading on the DPF. Optimization of the regeneration strategy requires a deep understanding of the mechanism by which soot deposited on the filter oxidizes. Although the DPF can remove soot particles in the exhaust with a high-trapping efficiency, strategies to further reduce soot emissions from the cylinder are still warranted as the increased pressure drop in the DPF deteriorates engine performance and frequent regeneration constitutes a significant fuel penalty. This special issue on ‘‘Soot dynamics in internal combustion engines’’ includes 16 technical papers and 1 review. The contents of these papers cover a wide spectrum of topics that can be roughly classified under the following three headlines: (1) in-flame soot processes in diesel DI engines, (2) in-flame soot processes in gasoline DI engines and (3) characterization of soot particles in the engine exhaust.

Inter-plume aerodynamics for gasoline spray collapse

The collapse or merging of individual plumes of direct-injection gasoline injectors is of fundamental importance to engine performance because of its impact on fuel–air mixing. However, the mechanisms of spray collapse are not fully understood and are difficult to predict. The purpose of this work is to study the aerodynamics in the inter-spray region, which can potentially lead to plume collapse. High-speed (100 kHz) particle image velocimetry is applied along a plane between plumes to observe the full temporal evolution of plume interaction and potential collapse, resolved for individual injection events. Supporting information along a line of sight is obtained using simultaneous diffused back illumination and Mie-scatter techniques. Experiments are performed under simulated engine conditions using a symmetric eight-hole injector in a high-temperature, high-pressure vessel at the “Spray G” operating conditions of the engine combustion network. Indicators of plume interaction and collapse include changes in counter-flow recirculation of ambient gas toward the injector along the axis of the injector or in the inter-plume region between plumes. The effect of ambient temperature and gas density on the inter-plume aerodynamics and the subsequent plume collapse are assessed. Increasing ambient temperature or density, with enhanced vaporization and momentum exchange, accelerates the plume interaction. Plume direction progressively shifts toward the injector axis with time, demonstrating that the plume interaction and collapse are inherently transient.

Flame Experiments at the Advanced Light Source: New Insights into Soot Formation Processes

The following experimental protocols and the accompanying video are concerned with the flame experiments that are performed at the Chemical Dynamics Beamline of the Advanced Light Source (ALS) of the Lawrence Berkeley National Laboratory1-4. This video demonstrates how the complex chemical structures of laboratory-based model flames are analyzed using flame-sampling mass spectrometry with tunable synchrotron-generated vacuum-ultraviolet (VUV) radiation. This experimental approach combines isomer-resolving capabilities with high sensitivity and a large dynamic range5,6. The first part of the video describes experiments involving burner-stabilized, reduced-pressure (20-80 mbar) laminar premixed flames. A small hydrocarbon fuel was used for the selected flame to demonstrate the general experimental approach. It is shown how species’ profiles are acquired as a function of distance from the burner surface and how the tunability of the VUV photon energy is used advantageously to identify many combustion intermediates based on their ionization energies. For example, this technique has been used to study gas-phase aspects of the soot-formation processes, and the video shows how the resonance-stabilized radicals, such as C3H3, C3H5, and i-C4H5, are identified as important intermediates7. The work has been focused on soot formation processes, and, from the chemical point of view, this process is very intriguing because chemical structures containing millions of carbon atoms are assembled from a fuel molecule possessing only a few carbon atoms in just milliseconds. The second part of the video highlights a new experiment, in which an opposed-flow diffusion flame and synchrotron-based aerosol mass spectrometry are used to study the chemical composition of the combustion-generated soot particles4. The experimental results indicate that the widely accepted H-abstraction-C2H2-addition (HACA) mechanism is not the sole molecular growth process responsible for the formation of the observed large polycyclic aromatic hydrocarbons (PAHs).