Sebastian Hammerschmidt

Hydrocarbon seepage and its sources at mud volcanoes of the Kumano forearc basin, Nankai Trough subduction zone

Twelve submarine mud volcanoes (MV) in the Kumano forearc basin within the Nankai Trough subduction zone were investigated for hydrocarbon origins and fluid dynamics. Gas hydrates diagnostic for methane concentrations exceeding solubilities were recovered from MVs 2, 4, 5, and 10. Molecular ratios (C1/C2  −40‰ V-PDB) indicate that hydrate-bound hydrocarbons (HCs) at MVs 2, 4, and 10 are derived from thermal cracking of organic matter. Considering thermal gradients at the nearby IODP Sites C0009 and C0002, the likely formation depth of such HCs ranges between 2300 and 4300 m below seafloor (mbsf). With respect to basin sediment thickness and the minimum distance to the top of the plate boundary thrust we propose that the majority of HCs fueling the MVs is derived from sediments of the Cretaceous to Tertiary Shimanto belt below Pliocene/Pleistocene to recent basin sediments. Considering their sizes and appearances hydrates are suggested to be relicts of higher MV activity in the past, although the sporadic presence of vesicomyid clams at MV 2 showed that fluid migration is sufficient to nourish chemosynthesis-based organisms in places. Distributions of dissolved methane at MVs 3, 4, 5, and 8 pointed at fluid supply through one or few MV conduits and effective methane oxidation in the immediate subsurface. The aged nature of the hydrates suggests that the major portion of methane immediately below the top of the methane-containing sediment interval is fueled by current hydrate dissolution rather than active migration from greater depth.

Real-time drilling mud gas monitoring for qualitative evaluation of hydrocarbon gas composition during deep sea drilling in the Nankai Trough Kumano Basin

BackgroundIntegrated Ocean Drilling Program Expedition 338 was the second scientific expedition with D/V Chikyu during which riser drilling was conducted as part of the Nankai Trough Seismogenic Zone Experiment. Riser drilling enabled sampling and real-time monitoring of drilling mud gas with an onboard scientific drilling mud gas monitoring system (“SciGas”). A second, independent system was provided by Geoservices, a commercial mud logging service. Both systems allowed the determination of (non-) hydrocarbon gas, while the SciGas system also monitored the methane carbon isotope ratio (δ13CCH4). The hydrocarbon gas composition was predominated by methane (> 1%), while ethane and propane were up to two orders of magnitude lower. δ13CCH4 values suggested an onset of thermogenic gas not earlier than 1600 meter below seafloor. This study aims on evaluating the onboard data and subsequent geological interpretations by conducting shorebased analyses of drilling mud gas samples.ResultsDuring shipboard monitoring of drilling mud gas the SciGas and Geoservices systems recorded up to 8.64% and 16.4% methane, respectively. Ethane and propane concentrations reached up to 0.03 and 0.013%, respectively, in the SciGas system, but 0.09% and 0.23% in the Geoservices data. Shorebased analyses of discrete samples by gas chromatography showed a gas composition with ~0.01 to 1.04% methane, 2 – 18 ppmv ethane, and 2 – 4 ppmv propane. Quadruple mass spectrometry yielded similar results for methane (0.04 to 4.98%). With δD values between -171‰ and -164‰, the stable hydrogen isotopic composition of methane showed little downhole variability.ConclusionsAlthough the two independent mud gas monitoring systems and shorebased analysis of discrete gas sample yielded different absolute concentrations they all agree well with respect to downhole variations of hydrocarbon gases. The data point to predominantly biogenic methane sources but suggest some contribution from thermogenic sources at depth, probably due to mixing. In situ thermogenic gas production at depths shallower 2000 mbsf is unlikely based on in situ temperature estimations between 81°C and 85°C and a cumulative time-temperature index of 0.23. In conclusion, the onboard SciGas data acquisition helps to provide a preliminary, qualitative evaluation of the gas composition, the in situ temperature and the possibility of gas migration.

Limitation of fluid flow at the Nankai Trough megasplay fault zone

Along the Nankai Trough megasplay fault off SE Japan, the effect of fluid migration on subduction-related seismogenesis and tsunamigenesis remains unresolved. To investigate the existence and role of fluid flow, a SmartPlug borehole observatory was installed at Site C0010 of the Integrated Ocean Drilling Program NanTroSEIZE Kumano transect, where a shallow branch of the fault was intersected and in situ fluid pressure monitored from August 2009 to November 2010. The tidal signal in the formation showed no phase shift relative to seafloor loading. The attenuation of 0.73 reflects the loading efficiency accurately, and enabled calculation of a formation compressibility of 1.0×10–9 Pa–1 and a hydraulic diffusivity (HD) of 1.5×10–5 m2 s–1. A similar HD is predicted by a tidal response model based on SmartPlug pressure data. By contrast, permeability measurements on intact samples from Site C0004 SE along-strike the splay fault and from Site C0006 in the frontal thrust zone were found to be similar and one magnitude smaller respectively, despite having a higher porosity. This is explained by the presence of fractures, which are covered by the larger scale of in situ measurements at Site C0010. Consequently, HD can be set to be at least 10–5 m2 s–1 for the splay fault and 10–6 m2 s–1 for the frontal thrust fault zone. Considering recent publications makes fluid flow at the splay fault unlikely, despite the presence of fractures. If the influence of fractures is limited, then processes leading to fault weakening may be enhanced.