Sébastien Salvador-Blanes

Scale of spatial dependence between chemical properties of topsoil and subsoil over a geologically contrasted area (Massif central, France)

This study investigates scale spatial specific dependence of some major and trace element contents in topsoil horizons and in alterite type horizons (subsoil horizons) over a weakly contaminated area. The study seeks also to compare the spatial distributions of chemical elements at both depths to the spatial variability of the alterite type in order to examine the effect of the parent material. The probability of occurrence of alterite type was estimated using indicator kriging (IK). Factorial kriging analysis (FKA) was used to analyze spatial variability in some soil chemical properties (Ca, Mg, K, Fe, Cr and Co) measured at two depths over a geologically contrasted area of 10 ha in central of France. The coefficients of the coregionalization matrix at different spatial scales reveal the dominant long-range autocorrelation and cross-correlation in all chemical elements in both depths except for trace elements (Co and Cr) where the short-range structure dominates the cross-correlation. The resulting structural correlation coefficients showed strong correlations between variables changing as a function of spatial scale. These relationships between chemical properties at different spatial scales were not revealed by the linear correlation coefficients. A principal component analysis was performed on the coregionalization matrices at each depth to summarize the relationships among the variables at the different spatial scales. Cokriging allowed mapping each spatial component for both depths. These maps were then compared with the probability map of alterite type estimated using indicator kriging. This comparison revealed that the spatial pattern of chemical elements in the subsoil horizons is almost certainly due to the alterite type effect, whereas the alterite type effect on the spatial pattern of chemical properties in the topsoil horizons was partly hidden by human activities and erosion.

Quantifying sediment sources in a lowland agricultural catchment pond using (137)Cs activities and radiogenic (87)Sr/(86)Sr ratios.

Soil erosion often supplies high sediment loads to rivers, degrading water quality and contributing to the siltation of reservoirs and lowland river channels. These impacts are exacerbated in agricultural catchments where modifications in land management and agricultural practices were shown to accelerate sediment supply. In this study, sediment sources were identified with a novel tracing approach combining cesium ((137)Cs) and strontium isotopes ((87)Sr/(86)Sr) in the Louroux pond, at the outlet of a lowland cultivated catchment (24km(2), Loire River basin, France) representative of drained agricultural areas of Northwestern Europe. Surface soil (n=36) and subsurface channel bank (n=17) samples were collected to characterize potential sources. Deposited sediment (n=41) was sampled across the entire surface of the pond to examine spatial variation in sediment deposits. In addition, a 1.10m sediment core was sampled in the middle of the pond to reconstruct source variations throughout time. (137)Cs was used to discriminate between surface and subsurface sources, whereas (87)Sr/(86)Sr ratios discriminated between lithological sources. A distribution modeling approach quantified the relative contribution of these sources to the sampled sediment. Results indicate that surface sources contributed to the majority of pond (μ 82%, σ 1%) and core (μ 88%, σ 2%) sediment with elevated subsurface contributions modeled near specific sites close to the banks of the Louroux pond. Contributions of the lithological sources were well mixed in surface sediment across the pond (i.e., carbonate sediment contribution, μ 48%, σ 1% and non-carbonate sediment contribution, μ 52%, σ 3%) although there were significant variations of these source contributions modeled for the sediment core between 1955 and 2013. These fluctuations reflect both the progressive implementation of land consolidation schemes in the catchment and the eutrophication of the pond. This original sediment fingerprinting study demonstrates the potential of combining radionuclide and strontium isotopic geochemistry measurements to quantify sediment sources in cultivated catchments.

Influence des substrats et des formations de versant sur la variabilité spatiale des teneurs naturelles en chrome de sols issus de roches métamorphiques

Abstract The variability of Cr content is studied along a toposequence of soils developed on amphibolite and gneiss. Amphibolites are Ca-rich, gneiss are K- and Cr-rich. A mineralogical study shows that biotite is the main bearer of Cr, and explains the relationship between K and Cr in the alterites. This relation still exists in pedological horizons. The nature of the parent material and the erosion are the main factors explaining the variability of Cr along the toposequence.

Investigating the temporal dynamics of suspended sediment during flood events with 7 Be and 210 Pb xs measurements in a drained lowland catchment

Soil erosion is recognized as one of the main processes of land degradation in agricultural areas. High suspended sediment loads, often generated from eroding agricultural landscapes, are known to degrade downstream environments. Accordingly, there is a need to understand soil erosion dynamics during flood events. Suspended sediment was therefore sampled in the river network and at tile drain outlets during five flood events in a lowland drained catchment in France. Source and sediment fallout radionuclide concentrations (7Be, 210Pbxs) were measured to quantify both the fraction of recently eroded particles transported during flood events and their residence time. Results indicate that the mean fraction of recently eroded sediment, estimated for the entire Louroux catchment, increased from 45 ± 20% to 80 ± 20% between December 2013 and February 2014, and from 65 ± 20% to 80 ± 20% in January 2016. These results demonstrate an initial flush of sediment previously accumulated in the river channel before the increasing supply of sediment recently eroded from the hillslopes during subsequent events. This research highlights the utility of coupling continuous river monitoring and fallout radionuclide measurements to increase our understanding of sediment dynamics and improve the management of soil and water resources in agricultural catchments.

One-, Two- and Three-Dimensional Pedogenetic Models

Various methods have been used to measure or estimate pedogenic processes that are responsible for the differentiation of a soil profile. In this chapter, the modelling and quantification of these processes will be reviewed and discussed.