Sedat Nizamoglu

White light generation using CdSe/ZnS core?shell nanocrystals hybridized with InGaN/GaN light emitting diodes

We introduce white light generation using CdSe/ZnS core?shell nanocrystals of single, dual, triple and quadruple combinations hybridized with InGaN/GaN LEDs. Such hybridization of different nanocrystal combinations provides the ability to conveniently adjust white light parameters including the tristimulus coordinates (x,y), correlated colour temperature (Tc) and colour rending index (Ra). We present the design, growth, fabrication and characterization of our white hybrid nanocrystal-LEDs that incorporate combinations of (1) yellow nanocrystals (?PL = 580?nm) on a blue LED (?EL = 440?nm) with (x,y) = (0.37,0.25), Tc = 2692?K and Ra = 14.69; (2) cyan and red nanocrystals (?PL = 500 and 620?nm) on a blue LED (?EL = 440?nm) with (x,y) = (0.37,0.28), Tc = 3246?K and Ra = 19.65; (3) green, yellow and red nanocrystals (?PL = 540, 580 and 620?nm) on a blue LED (?EL = 452?nm) with (x,y) = (0.30,0.28), Tc = 7521?K and Ra = 40.95; and (4) cyan, green, yellow and red nanocrystals (?PL = 500, 540, 580 and 620?nm) on a blue LED (?EL = 452?nm) with (x,y) = (0.24,0.33), Tc = 11?171?K and Ra = 71.07. These hybrid white light sources hold promise for future lighting and display applications with their highly adjustable properties.

Color-converting combinations of nanocrystal emitters for warm-white light generation with high color rendering index

Warm-white light emitting diodes with high color rendering indices are required for the widespread use of solid state lighting especially indoors. To meet these requirements, we propose and demonstrate warm-white hybrid light sources that incorporate the right color-converting combinations of CdSe∕ZnS core-shell nanocrystals hybridized on InGaN∕GaN LEDs for high color rendering index. Three sets of proof-of-concept devices are developed to generate high-quality warm-white light with (1) tristimulus coordinates (x,y)=(0.37,0.30), luminous efficacy (LE)=307lm∕W, color rending index (CR)=82.4, and correlated color temperature (CCT)=3228K; (2) (x,y)=(0.38,0.31), LE=323lm∕W, CRI=81.0, and CCT=3190K; and (3) (x,y)=(0.37,0.30), LE=303lm∕W, CRI=79.6, and CCT=1982K.

A photometric investigation of ultra-efficient LEDs with high color rendering index and high luminous efficacy employing nanocrystal quantum dot luminophores

We report a photometric study of ultra-efficient light emitting diodes (LEDs) that exhibit superior color rendering index (CRI) and luminous efficacy of optical radiation (LER) using semiconductor quantum dot nanocrystal (NC) luminophores. Over 200 million systematically varied NC-LED designs have been simulated to understand feasible performance in terms of CRI vs. LER. We evaluated the effects of design parameters including peak emission wavelength, full-width-at-half-maximum, and relative amplitudes of each NC color component on LED performance. Warm-white LEDs with CRI >90 and LER >380 lm/W at a correlated color temperature of 3000 K are shown to be achieved using nanocrystal luminophores.

Light-guiding hydrogels for cell-based sensing and optogenetic synthesis in vivo

Polymer hydrogels are widely used as cell scaffolds for biomedical applications. While the biochemical and biophysical properties of hydrogels have been extensively investigated, little attention has been paid to their potential photonic functionalities. Here, we report cell-integrated polyethylene glycol-based hydrogels for in-vivo optical sensing and therapy applications. Hydrogel patches containing cells were implanted in awake, freely moving mice for several days and shown to offer long-term transparency, biocompatibility, cell-viability, and light-guiding properties (loss: <1 dB/cm). Using optogenetic, glucagon-like peptide-1 (GLP-1) secreting cells, we conducted light-controlled therapy using the hydrogel in a mouse model with type-2 diabetes and attained improved glucose homeostasis. Furthermore, real-time optical readout of encapsulated heat-shock-protein-coupled fluorescent reporter cells made it possible to measure the nanotoxicity of cadmium-based bare and shelled quantum dots (CdTe; CdSe/ZnS) in vivo.

Warm-white light-emitting diodes integrated with colloidal quantum dots for high luminous efficacy and color rendering

Warm-white LEDs (WLEDs) with high spectral quality and efficiency are required for lighting applications, but current experimental performances are limited. We report on nanocrystal quantum dot (NQD) hybridized WLEDs with high performance that exhibit a high luminous efficacy of optical radiation exceeding 350lm/W(opt) and a high color rendering index close to 90 at a low correlated color temperature <3000K. These spectrally engineered WLEDs are obtained using a combination of CdSe/ZnS core/shell NQD nanophosphors integrated on blue InGaN/GaN LEDs.

Dual-color emitting quantum-dot-quantum-well CdSe-ZnS heteronanocrystals hybridized on InGaN/GaN light emitting diodes for high-quality white light generation

We report white light generation by hybridizing green-red emitting (CdSe)ZnS∕CdSe (core)shell/shell quantum-dot-quantum-well heteronanocrystals on blue InGaN∕GaN light emitting diodes with the photometric properties of tristimulus coordinates (x,y)=(0.36,0.30), luminous efficacy of optical radiation LE=278lm∕W, correlated color temperature CCT=3929K, and color-rendering index CRI=75.1. We present the photometric analysis and the quantum mechanical design of these dual-color emitting heteronanocrystals synthesized to achieve high-quality white light when hybridized on light emitting diodes. Using such multicolor emitting heteronanocrystals facilitates simple device implementation while providing good photometric properties.

Localized plasmon-engineered spontaneous emission of CdSe/ZnS nanocrystals closely-packed in the proximity of Ag nanoisland films for controlling emission linewidth, peak, and intensity.

Using metallic nanoislands, we demonstrate the localized plasmonic control and modification of the spontaneous emission from closely-packed nanocrystal emitters, leading to significant changes in their collective emission characteristics tuned spectrally and spatially by plasmon coupling. Using randomly-distributed silver nanoislands, we show that the emission linewidth of proximal CdSe/ZnS core-shell quantum dots is reduced by 22% and their peak emission wavelength is shifted by 14nm, while their ensemble photoluminescence is enhanced via radiative energy transfer by 21.6 and 15.1 times compared to the control groups of CdSe/ZnS nanocrystals with identical nano-silver but no dielectric spacer and the same nanocrystals alone, respectively.

Anisotropic emission from multilayered plasmon resonator nanocomposites of isotropic semiconductor quantum dots.

We propose and demonstrate a nanocomposite localized surface plasmon resonator embedded into an artificial three-dimensional construction. Colloidal semiconductor quantum dots are assembled between layers of metal nanoparticles to create a highly strong plasmon-exciton interaction in the plasmonic cavity. In such a multilayered plasmonic resonator architecture of isotropic CdTe quantum dots, we observed polarized light emission of 80% in the vertical polarization with an enhancement factor of 4.4, resulting in a steady-state anisotropy value of 0.26 and reaching the highest quantum efficiency level of 30% ever reported for such CdTe quantum dot solids. Our electromagnetic simulation results are in good agreement with the experimental characterization data showing a significant emission enhancement in the vertical polarization, for which their fluorescence decay lifetimes are substantially shortened by consecutive replication of our unit cell architecture design. Such strongly plasmon-exciton coupling nanocomposites hold great promise for future exploitation and development of quantum dot plasmonic biophotonics and quantum dot plasmonic optoelectronics.

All‐Biomaterial Laser Using Vitamin and Biopolymers

Lasers based on biomaterials known as Generally-Recognized-As-Safe (GRAS) substances approved by the U.S. Food and Drug Administration (FDA) are demonstrated. Vitamin B2-doped microdroplet lasers are generated and trapped on a super-hydrophobic poly-L-lactic acid substrate. The spheres support whispering gallery mode lasing at optical pump energies as low as 15 nJ per pulse (≈1 kW/mm2).

White-emitting conjugated polymer nanoparticles with cross-linked shell for mechanical stability and controllable photometric properties in color-conversion LED applications.

We report on the synthesis and characterization of water-dispersible, mechanically stable conjugated polymer nanoparticles (CPNs) in shelled architecture with tunable emission and controllable photometric properties via cross-linking. Using a reprecipitation method, white-emitting polymer nanoparticles are prepared in different sizes by varying the concentration of polymer; the emission kinetics are tuned by controlling the shell formation. For this purpose, polyfluorene derivatives containing azide groups are selected that can be decomposed under UV light to generate very reactive species, which opportunely facilitate the inter- and intra-cross-linking of polymer chains to form shells. Nanoparticles before and after UV treatment are characterized by various techniques. Their size and morphologies are determined by using dynamic light scattering (DLS) measurements and imaging techniques including scanning electron microscopy (SEM) and atomic force microscopy (AFM). For optical characterization, UV-vis and steady-state and time-resolved fluorescent spectroscopies are performed. Solid-state behaviors of these CPNs are also investigated by forming films through drop-casting. Moreover, the photometric calculations are also performed for films and dispersions to determine the color quality. A device has been constructed to show proof-of-principle white light generation from these nanoparticles. Additionally, mechanical stability studies are performed and demonstrated that these nanoparticles are indeed mechanically stable by removing the solvent after cross-linking using a freeze-dryer and redispersing in water and THF. Optical and imaging data confirm that the redispersed particles preserve their shapes and sizes after cross-linking.