See Mun Lee

Bis(μ2-N-methyl-N-phenyl­dithio­carbamato)-κ3S,S′:S;κ3S:S,S′-bis­[(N-methyl-N-phenyl­dithio­carbamato-κ2S,S′)cadmium]: crystal structure and Hirshfeld surface analysis

With both chelating and μ2-tridentate dithiocarbamate ligands, the structure of [Cd2(C8H8NS2)4] is a centrosymmetric dimer. The packing features C—H⋯S and C—H⋯π interactions.

Crystal structure of (N-(3-ethoxy-2-oxidobenzylidene)-4-fluorobenzohydrazonato-κ3N,O,O′)-diphenyltin(IV), C28H23FN2O3Sn

Abstract C28H23FN2O3Sn, orthorhombic, Pbca (no. 61), a = 16.0887(2) Å, b = 14.5333(2) Å, c = 20.5550(2) Å, V = 4806.21(10) Å3, Z = 8, Rgt(F) = 0.0199, wRref(F2) = 0.0596, T = 100(2) K.

N′-[1-(5-Bromo-2-hydroxyphenyl)ethylidene]isonicotinohydrazide monohydrate:crystal structure and Hirshfeld surface analysis

The organic molecule is twisted with a near orthogonal relationship between the outer rings [dihedral angle = 71.79 (6)°]. Supramolecular ribbons sustained by hydrogen bonding feature in the molecular packing.

trans-Dichloridobis(dimethyl sulfoxide-κO)bis(4-fluorobenzyl-κC1)tin(IV): crystal structure and Hirshfeld surface analysis

The octahedrally coordinated SnIV atom in [Sn(C7H6F)2Cl2(C2H6OS)2] is located on a centre of inversion so the resulting donor C2Cl2O2 donor set is all-trans. The three-dimensional molecular packing is sustained by C—H⋯F, C—H⋯Cl and C—H⋯π interactions.

Secondary bonding in di­methyl­bis­(morpholine-4-carbodi­thio­ato-κ2S,S′)tin(IV): crystal structure and Hirshfeld surface analysis

In (CH3)2Sn[S2CN(CH2CH2)2O]2, a skew-trapezoidal bipyramidal coordination geometry based on a C2S4 donor set is found. Secondary Sn⋯S interactions lead to centrosymmetric dimeric aggregates in the crystal.

fac-Aceto­nitrile­tricarbon­yl(di­methyl­carbamodi­thio­ato-κ2S,S′)rhenium(I): crystal structure and Hirshfeld surface analysis

An octahedral fac-C3NS2 coordination geometry is found for the ReI atom in the title compound; the dithiocarbamate ligand forms symmetric Re—S bonds. In the crystal, supramolecular layers are formed via weak C—H⋯O interactions.

[N′-(4-Dec­yloxy-2-oxido­benzyl­idene)-3-hy­droxy-2-naphtho­hydrazidato-κ3N,O,O′]di­methyl­tin(IV): crystal structure and Hirshfeld surface analysis

A highly distorted pentacoordinated C2NO2 geometry is observed for the Sn atom owing to a tridentate mode of coordination of the Schiff base ligand and the restricted bite angles it subtends. In the crystal, supramolecular layers sustained by C—H⋯O, π–π, C—H⋯π(arene) and C—H⋯π(chelate ring) interactions are formed.

(Tris{2-[(5-chloro-2-oxido­benzyl­idene-κO)amino-κN]eth­yl}amine-κN)­ytterbium(III): crystal structure and Hirshfeld surface analysis

The title compound features an amine-N-capped octahedral coordination geometry for YbIII defined by an N4O3 donor set. The packing features supramolecular layers sustained by C—H⋯O, C—H⋯π(aryl) and C—Cl⋯π(aryl) interactions.

Zwitterionic 4-bromo-6-meth­oxy-2-{[tris­(hy­droxy­meth­yl)methyl]­iminiumyl­meth­yl}phenolate: crystal structure and Hirshfeld surface analysis

The title compound exists in the keto–amine tautomeric form. In the crystal, supramolecular layers are formed by O—H⋯O hydrogen bonding.